Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.     

Opening angles, Lorentz factors and confinement of X-ray binary jets

We present a collation of the available data on the opening angles of jets in X-ray binaries, which in most cases are small (≲10°). Under the assumption of no confinement, we calculate the Lorentz factors required to produce such small opening angles via the transverse relativistic Doppler effect. The derived Lorentz factors, which are in most cases lower limits, are found to be large, with a mean >10, comparable to those estimated for active galactic nuclei (AGN) and much higher than the commonly assumed values for X-ray binaries of 2–5. Jet power constraints do not, in most cases, rule out such high Lorentz factors. The upper limits on the opening angles show no evidence for smaller Lorentz factors in the steady jets of Cygnus X-1 and GRS 1915+105. In those sources in which deceleration has been observed (notably  XTE J1550−564  and Cygnus X-3), some confinement of the jets must be occurring, and we briefly discuss possible confinement mechanisms. It is however possible that all the jets could be confined, in which case the requirement for high bulk Lorentz factors can be relaxed.     

Radiation exposure and Mission Strategies for Interplanetary Manned Missions (REMSIM)

Cosmic radiation is an important problem for human interplanetary missions. The “Radiation Exposure and Mission Strategies for Interplanetary Manned Missions–REMSIM” study is summarised here. They are related to current strategies and countermeasures to ensure the protection of astronauts from radiation during interplanetary missions, with specific reference to: radiation environment and its variability; radiation effects on the crew; transfer trajectories and associated fluences; vehicle and surface habitat concepts; passive and active shielding concepts; space weather monitoring and warning systems.     

On The Concept Of Periapsis In Hill’s Problem

The concept of closest approach is analyzed in Hill’s problem, resulting in a partitioning of the position space. The different behavior between the direct and retrograde motion is explained analytically, resulting in a simple estimate of the variation of Hill’s periodic and quasi-circular orbits as a function of the Jacobi constant. The local behavior of the orbits on the zero velocity surfaces and an analytical definition of local escape and capture in Hill’s problem are also given.     

Chemical alteration of tephra in the depositional environment: theoretical stability modelling

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.