Thermodynamic characterization of the partitioning of iron between soluble and colloidal species in the Atlantic Ocean

Recent electrochemical measurements have shown that iron (Fe) speciation in seawater is dominated by complexation with strong organic ligands throughout the water column and have provided important thermodynamic information about these compounds. Independent work has shown that iron exists in both soluble and colloidal fractions in the Atlantic Ocean. Here we have combined these approaches in samples collected from a variety of regimes within the Atlantic Ocean. We measured the partitioning of Fe between soluble (< 0.02 μm) and colloidal (0.02 to 0.4 μm) size classes and characterized the concentrations and conditional stability constants of Fe ligands within these size classes. Results suggest that equilibrium partitioning of Fe between soluble and colloidal ligands is partially responsible for the distribution of Fe between soluble and colloidal size classes. However, a significant fraction of the colloidal Fe was inert to ligand exchange as soluble Fe concentrations were generally lower than values predicted by a simple equilibrium partitioning model.In surface waters, strong ligands with conditional stability constants of 10¹³ relative to total inorganic Fe appeared to dominate speciation in both the soluble and colloidal fractions. In deep waters these ligands were absent, and instead we found ligands with stability constants 12–15 fold smaller that were predominantly in the soluble pool. Nevertheless, significant levels of colloidal Fe were found in these samples, which we inferred must be inert to coordination exchange.     

Water vapor in the atmosphere over the northern Tien Shan

Refined data of systematic measurements of total water vapor in the atmosphere from May 1980 to April 2005 are presented. The data were obtained at the Issyk Kul atmospheric-monitoring station by the method of solar molecular-absorption spectroscopy. Over 25 years, the annual mean water-vapor content in the atmosphere increased by 4.5% at a mean rate of increase of 0.18% per year. However, the water-vapor content decreased in the last five years. The results of statistical processing of experimental data (general statistical characteristics, correlation coefficients, composite oscillations) are described. A refined model is proposed for forecasts of temporal variations in the monthly mean and annual mean water-vapor contents for the coming years. The model includes a linear trend and the sum of oscillations with periods close to the periods of a number of well-known geophysical phenomena. Regression equations are proposed to relate the water-vapor content in the atmospheric column to the surface temperature and absolute humidity.     

Methods of fitting the Fisher-Tippett type 1 extreme value distribution

Methods are described for estimating the parameters of the Fisher-Tippet Type 1 extreme value distribution and associated return values from measured extremes, such as maximum wave height. A comparison of these methods, with simulated data, shows that those using Gumbel's plotting position are least satifactory. Maximum likelihood methods give the smallest mean square errors, but the very much simpler method of moments is nearly as good.     

A literature review of the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on OTEC heat exchangers

An investigation has been made of available data on the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on Ocean Thermal Energy Conversion (OTEC) heat exchangers. Pertinent oceanographic data is lacking at or near potential OTEC sites for the calculation of the degree of saturation of seawater with respect to calcium carbonate. Consequently, only “extrapolated” saturation values can be used. These indicate that near surface seawater is probably supersaturated, with respect to the calcium carbonate phases calcite and aragonite, at all potential OTEC sites. The deep seawater that would be brought to the surface at the potential Atlantic Ocean sites is also likely to be supersaturated with respect to calcium carbonate. The deep seawater at the potential Pacific Ocean sites may be slightly undersaturated.The fact that OTEC heat exchangers will be operating in seawater, which is supersaturated with respect to calcium carbonate, means that if nucleation of calcite or aragonite occurs on the heat exchanger surfaces, significant growth rates of calcium carbonate scale may be expected. The potential for calcium carbonate nucleation is highest at cathodic metal surface locations, which are produced as the result of aluminum corrosion in seawater. Consequently, corrosion and scale formation may be closely related. What the possible effects of biofouling may be on this process are not known.     

Modelling of the spectral characteristics of the wind wave envelope

A method applied for the determination of the statistical characteristics of the wind wave envelope is considered. It is shown that the correlation function envelope for a normal random process defines the basic properties of the process envelope and it can be expressed through the spectrum width. No limitations are imposed on the form or the width of the spectrum. The model is effective for a developing and steady sea disturbance when the attenuation of the temporal correlation function can be approximated by an exponent. Numerical computations and experimental results for typical cases of sea disturbance are compared.Translated by Mikhail M. Trufanov.     

Relationship between the anomalies of temperature and air pressure over the ocean

This paper considers the relationship between multi-year air temperature and pressure fluctuations over the ocean, based on an approximate solution of the problem on the determination of large-scale seawater temperature anomalies from the conditions predominating at the sea surface. The dependence derived is numerically analysed using observations made in the North Atlantic. It is shown that the variability of annual mean air temperature anomalies is largely controlled by the air pressure field which has taken place during the preceding long-term period. The dependence derived may be applied to generate long-term forecasts of the ocean's hydrometeorological regime.Translated by Vladimir A. Puchkin.     

Some General Properties of Transverse Motions of the Geostrophic Front

Within the framework of the reduced-gravity model of the ocean taking into account the effect of friction in the Rayleigh form, we study the two-dimensional problem of nonlinear motions of a subsurface front of finite width. We consider the conservation laws and the character of motion of the center-of-mass of the cross section of the front and their variations caused by the losses of energy. For fields with special structure, the problem is reduced to the solution of a system of nonlinear ordinary differential equations. It is shown that the initially geostrophic frontal current decays with time according to a power law. The deviations of the initial state of the front from the state of geostrophic balance result in the generation of superinertial oscillations of the hydrodynamic fields.