Geochemical surveillance of active volcanoes: data on the fumaroles of Vulcano (Aeolian Islands,Italy)

Temperature and chemical composition of condensates of higher temperature fumaroles, located on the rim of the crater of Vulcano, were studied over a period of one year. Maximum temperature changed from 216°C (June 1977) to 291°C (May 1978). HCl is the main constituent of condensates which, in comparison with data from fumaroles of other volcanoes, contain also noteworthy quantities of boron and bromine. Since these chemical characteristics suggested the possible inflow of water of marine origin into the volcanic conduit, experimental data on seawater-rock reactions at high temperatures and pressures were taken into account. A model is drafted for the volcanic system, in which the occurrence of an aquifer interposed between the magma chamber and the surface is considered. The vaporization of this aquifer would feed the fumaroles giving rise, through different mixing processes with surface waters, to the observed differences in temperature and chemical composition. However, data available at present are not sufficient to support the proposed model, which must be mainly considered as a working hypothesis.     

The relation between geomagnetic pulsations and an increase in the fluxes of geosynchronous relativistic electrons during geomagnetic storms

The dynamics of the Pc5 and Pi1 pulsation characteristics and relativistic electron fluxes at geostationary orbit were comparatively analyzed for three nine-day intervals, including quiet periods and periods of geomagnetic storms. It was shown that relativistic electron fluxes increase considerably when the power of global Pc5 pulsations and the index of midlatitude irregular Pi1 pulsations increase simultaneously. The correlation between the characteristics of Pi1 and Pc5 geomagnetic pulsations and the level of the relativistic electron flux at geostationary orbit during the magnetic storm recovery phase were studied. It was shown that the correlation coefficient of the relativistic electron maximal fluxes during the magnetic storm recovery phase with the parameter of midlatitude Pi1 pulsations is slightly higher than such a correlation coefficient with the solar wind velocity.     

Enhanced geochemical gradients in a marine shallow-water hydrothermal system: Unusual arsenic speciation in horizontal and vertical pore water profiles

The shallow marine hydrothermal vents near Ambitle Island in eastern Papua New Guinea discharge hot, slightly acidic, As-rich, chemically reduced fluid into cool, slightly alkaline, oxygenated seawater. Gradients in temperature, pH, and total As (As^T), among others, are established as the two aqueous phases mix. The hydrothermal fluid contained 900 μg/L As^T, almost exclusively present as the reduced As^III, while local seawater measured between 1.2 and 2.4 μg/L As, with approximately equal levels of As^III and As^V. Of particular interest in this study was As speciation and abundance in pore waters as a function of sediment depth and as a function of distance from the area of focused venting. With increasing distance, As^T concentration in the pore water decreased rapidly, but remained elevated up to 300 m from the area of focused venting when compared to a non-hydrothermal control site. As a function of depth (to 100 cm) As^T concentration in the pore water profiles was elevated and generally increased with depth. Surprisingly, aqueous As^V far exceeded aqueous As^III at almost all distances and depths investigated, while at the control site the As^III concentration exceeded that of As^V. In the Tutum Bay hydrothermal system, chemical disequilibria among As species provide potential metabolic energy for arsenite oxidizing microorganisms where hydrothermal fluid mixes with seawater near the vent orifice, and for arsenate reducing microorganisms with increasing distance and depth from the hydrothermal point source.     

Spatial and seasonal variability of sediment accumulation potential through controlled flooding of the beels located in the polders of the Ganges-Brahmaputra-Meghna delta of Southwest Bangladesh

The Ganges-Brahmaputra-Meghna (GBM) delta plain within Bangladesh is one of the most vulnerable to relative sea level rise (RSLR) in the world especially under current anthropogenically modified (i.e., embanked) conditions. Tidal river management (TRM) as practiced in coastal regions of Bangladesh may provide an opportunity to combat RSLR by raising the land level through controlled sedimentation inside beels (depression within embanked polders) with re-opening of polders. To date, TRM has been applied to tide-dominated coastal regions, but the potential applicability of TRM for the beels within the polders of river-dominated and mixed flow (MF) regimes remains to be assessed. We apply a calibrated 2D numerical hydromorphodynamic model to quantify sediment deposition in a beel flooded through breaching of the polder dike under conditions of river-dominated, tide-dominated and MF regimes for different seasons and applying different regulation schemes for the flow into the beel. Simulation results show considerable seasonality in sediment deposition with largest deposition during the monsoon season. The potential of controlled flooding is highest in the tide-dominated region, where sediment accumulation can be up to 28 times higher than in the river-dominated region. Regulating flow into a beel increases trapping efficiency, but results in slightly lower total deposition than without regulation. We conclude that re-establishing flooding of the beel within the polder without regulating the flow into the beel through breaching of the polder dike is a promising strategy for the mixed and tide-dominated flow regions in the delta as the sediment accumulation can raise the land surface at a higher rate than RSLR and effective SLR (ESLR). In the more upstream river-dominated section of the delta, accumulation rates would be much lower, but the pressure of sea level rise on these areas is lower as well. Owing to the abundant availability of sediment, application of controlled flooding like TRM therefore provides an opportunity to counteract the impact of RSLR and ESLR by means of land raising, particularly along the tidal river reaches in the GBM delta.     

In situ uptake of mercury by the intertidal mussel,Mytilus californianus

The in situ uptake of mercury in tissues of Mytilus californianus was studied by exposing control specimens to waters at four depths near a submarine wastewater discharge for a period of 24 weeks. The response patterns observed for digestive gland, adductor muscle and gonadal tissues were strikingly different. Digestive gland concentrations increased rapidly to the heightened levels found for indigenous specimens. On the other hand, changes in the mercury content of adductor muscle were not statistically significant, and gonadal tissues generally exhibited a low rate of increase. No correlation with depth was observed.     

Formation of a local atmospheric electric field

We have estimated the variations in the atmospheric electrostatic field (AEF, E _Z(0)) strength in the surface layer caused by variations in conductivity due to radon influences, cosmic ray intensity, changes in the balance of light and heavy ions during sunset and sunrise, and under the effect of the ionospheric electric current potential on the AEF potential. It is shown that the air conductivity varies due to ionization under the effect of radon emanations and is determined by the radon exhalation and turbulent diffusion of the surface air layer, while the cosmic ray intensity affects the surface air conductivity through changes in the ion recombination conditions. A decrease in the air conductivity due to a decrease in the cosmic ray intensity (Forbush decrease) also decreases E _Z(0), while a decrease in radon fluxes results in an increase in E _Z(0). We have estimated the effect of illumination conditions on the AEF due to variations in the relative concentration of heavy and light ions under the influence of photodetachment and photoattachment processes. The work has been done on the basis of data received from the Paratunka observatory (Kamchatka).     

Dynamical downscaling approach for wintertime seasonal-scale simulation over the Western Himalayas

The performance of RegCM4 for seasonal-scale simulation of winter circulation and associated precipitation over the Western Himalayas (WH) is examined. The model simulates the circulation features and precipitation in three distinct precipitation years reasonably well. It is found that the RMSE decreases and correlation coefficient increases in the precipitation simulations with the increase of model horizontal resolutions. The ETS and POD for the simulated precipitation also indicate that the performance of model is better at 30 km resolution than at 60 and 90 km resolutions. This improvement comes due to better representation of orography in the high-resolution model in which sharp orography gradient in the domain plays an important role in wintertime precipitation processes. A comparison of model-simulated precipitation with observed precipitation at 17 station locations has been carried out. Overall, the results suggest that 30 km model produced better skill in simulating the precipitation over the WH and this model is a useful tool for further regional downscaling studies.