Vertical distribution of the macrobenthic community and its relationships to trace metals and natural sediment characteristics in the lower Douro estuary, Portugal

Vertical distribution (0–15 cm) of the macrobenthic community and its relationships to natural sediment characteristics and trace metal contents and bioavailability were studied at five locations in the lower Douro estuary, Portugal. An analysis of vertical metal distribution, for the interpretation of anthropogenic impact on the estuarine sediments, was also investigated. Sediment characterisation included organic matter, grain size, metals (Al, Fe, Cu, Pb, Cr, Ni, Cd, Zn and Mn), acid volatile sulphide (AVS) and simultaneously extracted metals (SEM). The macrobenthic community had low diversity (14 species), was dominated by small size opportunists and seemed to be controlled mainly by natural factors such as grain size distribution, Al and Fe contents and sediment depth. The vertically heterogeneous distribution of macrobenthic community appears to affect redox status of the sediments and consequently metal bioavailability. Despite anthropogenic contamination in terms of Zn, Cu, Pb, Cr and Ni having already been detected in the north bank, the analysis of vertical distribution was essential for the identification of current anthropogenic contamination in terms of Zn, Pb and Cd in the south bank.     

Assessment of the impact of the planetary scale on the decay of blocking and the use of phase diagrams and enstrophy as a diagnostic

It was shown that abrupt changes in the large-scale structure of atmospheric flows may lead to the rapid decay of blocking. Analysis of phase diagrams made it possible to identify when sharp changes occurred in the dynamics of the system. The connection of these changes to the decay of blocking was estimated for three blocking events in the Southern Hemisphere. In addition to phase diagrams, enstrophy was used as a diagnostic tool for the analysis of blocking events. From the results of this analysis, four scenarios for the decay mechanisms were determined: (i) decay with a lack of synoptic-scale support, (ii) decay with an active role for synoptic processes, and (iii–iv) either of these mechanisms in the interaction with an abrupt change in the character of the planetary-scale flow.     

Analysis of seabed instability using element free Galerkin method

Wave-induced seabed instability, either momentary liquefaction or shear failure, is an important topic in ocean and coastal engineering. Many factors, such as seabed properties and wave parameters, affect the seabed instability. A non-dimensional parameter is proposed in this paper to evaluate the occurrence of momentary liquefaction. This parameter includes the properties of the soil and the wave. The determination of the wave-induced liquefaction depth is also suggested based on this non-dimensional parameter. As an example, a two-dimensional seabed with finite thickness is numerically treated with the EFGM meshless method developed early for wave-induced seabed responses. Parametric study is carried out to investigate the effect of wavelength, compressibility of pore fluid, permeability and stiffness of porous media, and variable stiffness with depth on the seabed response with three criteria for liquefaction. It is found that this non-dimensional parameter is a good index for identifying the momentary liquefaction qualitatively, and the criterion of liquefaction with seepage force can be used to predict the deepest liquefaction depth.     

Computations of the almost highest short-crested waves in deep water

The highest short-crested waves have been studied analytically and numerically by several workers, but without a conclusive view. An efficient numerical scheme is proposed in this paper which retains the water-surface elevations in an implicit form in the governing equations, rather than using a series approximation, thus improving the accuracy of the numerical results. Convergence of the numerical scheme is verified. The almost highest short-crested waves in deep water are then evaluated, which are defined for the condition with the largest wave energies. It is found that the critical angle for wave frequency reversal also demarcates the wave characteristics near breaking, for either kinematic or dynamic prominence. The known results available for the limiting two-dimensional cases of standing and progressive waves are compared favourably.     

Geodynamic Evolution of the Eastern Segment of the Azores-Gibraltar Zone: The Gorringe Bank and the Gulf of Cadiz Region

Detailed structural interpretation of the recently acquired deep seismic multichannel profiles along the Iberian Atlantic Margins (IAM Project) provides new results on the geodynamic evolution of the eastern part of the Azores-Gibraltar plate boundary. Thrusting and folding of the oceanic basement and of Mesozoic and Cenozoic sedimentary cover of the Gorringe Bank region are consistent with the N–S convergence of Iberia and Africa. Compressive structures in the Gorringe Bank region are spread over a wide area. Deformation under compression took place mainly in Tertiary times, as is evidenced by a basal unconformity and several discontinuities in Tertiary sediments, although some deformation has also been recorded in Quaternary sediments. The compressive structures in the Gulf of Cadiz are E–W oriented thrusts, folds and related diapiric structures. N–S oriented transpressive deformation is likely to occur in the western Portuguese platform. There is no continuity of structures from the oceanic to the continental domain, suggesting that deformation transfers from one side to the other through a transcurrent fault zone. The fault contact between the two domains is located in the ocean-continent transition zone.     

Wave climate in a groin field

Wave records at seven different locations within a groin field have been analysed by both statistical and spectral approaches to study the general wave climate. The wave heights and periods from the wave records were obtained by both upcross and downcross methods for the statistical approach. The variation of different wave height and wave period parameters with respect to the time of measurement at a particular location and its variation at different locations within the groin field at a particular instant of time are presented and discussed in detail in this paper. It is generally found that the wave heights follow the Weibull distribution.     

The role of organic coatings in the enrichment of marine particles with selenium. The fixation of selenite on an adsorbed amino acid

The enrichment of marine particles with selenium cannot be explained as that with metals present in cationic form by complexation with anionic functional groups of adsorbed organic matter. Physicochemical data obtained using a model system are reported. The surface of the particles is modelized by a mercury electrode whose surface charge density can be easily changed, covered by a layer of adsorbed polymers. Studies with different kinds of macromolecules and salts show a specific interaction between adsorbed polyalanine and selenite. The results can be explained by the concordance of the distances between two oxygen atoms in this oxyanion and between two amine groups of the adsorbed polypeptide. A similar mechanism could occur in marine aggregates whatever their nature, as long as they contain amine groups at their surface which result in this concordance. Some prospects derived from the results are discussed.     

Relationship between the seismicity and geologic structure of the Blanco Transform Fault Zone

Morphologic studies of an oceanic transform, the Blanco Transform Fault Zone (BTFZ), have shown it to consist of a series of extensional basins that offset the major strike-slip faults. The largest of the extensional basins, the Cascadia Depression, effectively divides the transform into a northwest segment, composed of several relatively short strike-slip faults, and a southeast segment dominated by fewer, longer faults. The regional seismicity distribution (m _b 4.0) and frequency-magnitude relationships (b-values) of the BTFZ show that the largest magnitude events are located on the southeast segment. Furthermore, estimates of the cumulative seismic moment release and seismic moment release rate along the southeast segment are significantly greater than that of the northwest segment. These observations suggest that slip along the southeast segment is accommodated by a greater number of large magnitude earthquakes. Comparison of the seismic moment rate, derived from empirical estimates, with the seismic moment rate determined from plate motion constraints suggests a difference in the seismic coupling strength between the segments. This difference in coupling may partially explain the disparity in earthquake size distribution. However, the results appear to confirm the relation between earthquake size and fault length, observed along continental strike-slip faults, for this oceanic transform.     

Butyltins in marine waters of The Netherlands in 1988 and 1989; Concentrations and effects

Specific effects of tributyltin (TBT) on Crassostrea gigas—valve thickening, and Nucella lapillus—imposex, were measured on local populations, relatively clean unaffected species from England were transferred to the Netherlands and exposed during six weeks to ambient TBT concentrations. Near marinas 50% of the exposed species were sterile after six weeks. In general, no dissolved butyltins were detected in the Rhine and Scheldt estuaries. In 1988 TBT concentrations in marinas ranged from 120 to 4000 ng litre⁻¹. In sediments (fraction <60 μm) and suspended particulate matter TBT concentrations reached up to 1200 ng g⁻¹. TBT concentrations in mussel tissue ranged from <1 to 2300 ng g⁻¹ based on a dry weight. In 1989 concentrations of dissolved TBT ranged from <0·1 to 7200 ng litre⁻¹. In 1989 a seasonal study in the marina of Colijnsplaat showed that dissolved butyltins increased from April to the end of May due to the launching of freshly painted boats, and decreased afterwards.