Distribution of hydrate on Europa: Further evidence for sulfuric acid hydrate

Sulfuric acid hydrate has been proposed as an important species on Europa's surface, the acid being produced by radiolysis of surficial sulfur compounds. We investigated the spectral properties of disordered and crystalline forms of sulfuric acid and suggest that the hydration properties of Europa's hypothesized sulfuric acid lie between two end members: liquid sulfuric acid and its higher crystalline hydrates. The spectra of these end members are similar except for spectral shifts at the band edges. We measured the optical constants of sulfuric acid octahydrate and used these with simple radiative transfer calculations to fit Europa spectra obtained by Galileo's Near Infrared Mapping Spectrometer (NIMS). The global distribution of the hydrate that we associate here with hydrated sulfuric acid shows a strong trailing-side enhancement with a maximum fractional hydrate abundance of 90% by volume, corresponding to a sulfur atom to water molecule ratio of 10%. The hydrate concentration spatially correlates with the ultraviolet and visible absorption of the surface and with the sulfur dioxide concentration. The asymmetric global distribution is consistent with Iogenic plasma ion implantation as the source of the sulfur, possibly modified by electron irradiation and sputtering effects. The variegated distribution also correlates with geologic forms. A high spatial resolution image shows resolved lineae with less hydrate appearing within the lineae than in nearby crustal material. The low concentration of hydrated material in these lineae argues against their conveying sulfurous material to the surface from the putative ocean.     

Postglacial history of a cedar swamp in southeastern Connecticut

Stratigraphic and palynologic analyses of sediment cores from a large mire, combined with geologic and hydrologic studies of its watershed, provide a late Quaternary record of environmental change at Cedar Swamp in southeastern Connecticut. Since deglaciation of the area, the basin has evolved from an open lake characterized by the rapid accumulation of allochthonous inorganic sediments to an ombrotrophic mire with peat accumulation keeping pace with the gradual rise in the water table. Lithostratigraphic, pollen, and chronologic evidence suggest that the long-term trend of basin infilling and paludification was interrupted by two intervals (14 000–13 000 and 8000–4700 yr B.P.) when the water table elevation dropped at least 1 m.     

Precession of the orbital nodes of Jupiter and Saturn triggered by the mutual perturbation: A model of two rings

The problem of the precession of the orbital planes of Jupiter and Saturn under the influence of mutual gravitational perturbations was formulated and solved using a simple dynamical model. Using the Gauss method, the planetary orbits are modeled by material circular rings, intersecting along the diameter at a small angle α. The planet masses, semimajor axes and inclination angles of orbits correspond to the rings. What is new is that each ring has an angular momentum equal to the orbital angular momentum of the planet. Contrary to popular belief, it was proved that the orbital resonance 5: 2 does not preclude the use of the ring model. Moreover, the period of averaging of the disturbing force (T ≈ 1332 yr) proves to be appreciably greater than a conventionally used period (≈900 yr). The mutual potential energy of rings and the torque of gravitational forces between the rings were calculated. We compiled and solved the system of differential equations for the spatial motion of rings. It was established that a perturbing torque causes the precession and simultaneous rotation of the orbital planes of Jupiter and Saturn. Moreover, the opposite orbit nodes on the Laplace plane coincide and perform a secular movement in retrograde direction with the same velocity of 25.6″/yr and the period T _J = T _S ≈ 50687 yr. These results are close to those obtained in the general theory (25.93″/yr), which confirms the adequacy of the developed model. It was found that the vectors of the angular velocity of orbital rings move counterclockwise over circular cones and describe circles on the celestial sphere with radii β₁ ≈ 0.8403504° (Saturn) and β₂ ≈ 0.3409296° (Jupiter) around the point which is located at an angular distance of 1.647607° from the ecliptic pole.     

The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

A new algorithm to estimate sky condition based on 5 minutes-averaged values of clearness index and relative optical air mass

Summary This work describes a new algorithm to characterize sky condition in intervals of 5 min using four categories of sun exposition: apparent sun with cloud reflection effects; apparent sun without cloud effects; sun partially concealed by clouds; and sun totally concealed by clouds. The algorithm can also be applied to estimate hourly and daily sky condition in terms of the traditional three categories: clear, partially cloudy and cloudy day. It identifies sky conditions within a confidence interval of 95% by minimizing local climate and measurement effects. This is accomplished by using a logistic cumulative probability function to characterize clear sky and Weibull cumulative probability function to represent cloudy sky. Both probability functions are derived from frequency distributions of clearness index, based on 5 minutes-averaged values of global solar irradiance observed at the surface during a period of 6 years in Botucatu, Southeastern of Brazil. The relative sunshine estimated from the new algorithm is statistically comparable to the one derived from Campbell-Stocks sunshine recorder for both daily and monthly values. The new method indicates that the highest frequency of clear sky days occurs in Botucatu during winter (66%) and the lowest during the summer (38%). Partially cloudy condition is the dominant feature during all months of the year.     

Sources of the Late Mesozoic magmatic associations in the northeastern part of the Amurian microcontinent

Based on generalization of available geochronological data, Late Mesozoic magmatic associations in the northeastern part of the Amurian microcontinent are divided into three groups: 142–125, 124–115, and <110 Ma. The age of these associations decreases with approaching the Pacific margin of Asia. In the same direction, they show a change in sources of their parental melts: continental crust (142–125 Ma) → continental crust + PREMA (DM) (124–115 Ma) → continental crust + PREMA (DM) + EMII (<110 Ma). Isotope-geochemical (Sr-Nd) study indicates that intrusive and volcanic rocks of the Late Mesozoic magmatic associations in the northeastern part of the Amurian microcontinent were originated in geodynamic settings that provided access of enriched mantle sources to magma formation. The most probable of these settings are as follows: (1) plate sliding accompanying by the formation of slab window beneath continental margin; (2) passage of the Asian margin over the East Asian mantle hot field in the Late Mesozoic; (3) asthenospheric upwelling due to delamination of the lower crust during closure of the Mongolian-Okhotsk ocean caused by collision between the Amurian microcontinent, Dzhugdzhur-Stanovoy, and Selenga-Stanovoy superterranes in the Central Asian fold belt.     

Statistical Modeling of Monthly Anomalies of Atmospheric Precipitations for the Region of the Ukraine and Black Sea

The data array accumulated for the period 1946–1995 is used to select the most significant predictor of monthly anomalies of precipitation in the region of the Ukraine and Black Sea, namely, a large-scale circulation in a sector covering the North Atlantic and Europe. Three large-scale predictors (geopotential at a level of 500GPa, sea-level pressure, and the difference between the geopotentials at levels of 500 and 1000GPa) give almost identical results: their correlation with anomalies of precipitation is equal to 0.7–0.8 in winter and 0.4–0.5 in summer. The predominant mechanism of the influence of circulation on precipitations at low frequencies is the response of the trajectories of European cyclones to changes in the upper-tropospheric jet currents in the Atlantic-European sector described as the superposition of the North-Atlantic oscillation and the Eurasian mode. The decomposition of the fields of precipitations and circulation in the eigenmodes of the canonical correlation analysis opens a possibility of direct computation of the monthly average fields of precipitations for the entire territory of the Ukraine and Black Sea region according to the large-scale geopotential fields.     

Observed intra-seasonal to interannual variability of the upper ocean thermal structure in the southeastern Arabian Sea during 2002–2008

The southeastern Arabian Sea (SEAS), located in the Indian Ocean warm pool, is a key-region of the regional climate system. It is suspected to play an important role in the dynamics of the Asian summer monsoon system. The present study reports the salient features derived from a newly harvested observational dataset consisting of repeated fortnightly XBT transects in the SEAS over the period 2002–2008. The fortnightly resolution of such a multi-year record duration is unprecedented in this part of the world ocean and provides a unique opportunity to examine the observed variability of the near-surface thermal structure over a wide spectrum, from intra-seasonal to interannual timescales. We find that most of the variability is trapped in the thermocline, taking the form of upwelling and downwelling motions of the thermal stratification. The seasonal variations are consistent with past studies and confirm the role of the monsoonal wind forcing through linear baroclinic waves (coastally-trapped Kelvin and planetary Rossby waves). Sub-seasonal variability takes the form of anomalous events lasting a few weeks to a few months and occurs at two preferred timescales: in the 30–110 day band, within the frequency domain of the Madden–Julian oscillation and in the 120–180 day band. While this sub-seasonal variability appears fairly barotropic in the offshore region, the sign of the anomaly in the upper thermocline is opposite to that in its lower part on many occasions along the coast. Our dataset also reveals relatively large interannual temperature variations of about 1 °C from 50 to 200 m depth that reflect a considerable year-to-year variability of the magnitude of both upwelling and downwelling events. This study clearly demonstrates the necessity for sustained long-term temperature measurements in the SEAS.     

Gamma-Hadron Separation using Čerenkov Photon Density Fluctuations

In the atmospheric Čerenkov technique γ-rays are detected against the abundant background produced by hadronic showers. In order to improve the signal to noise ratio of theexperiment, it is necessary to reject a significant fraction of hadronic showers. Traditional background rejection methods based on image shape parameters have been extensively used for the data from imaging telescopes. However, non-imaging Čerenkov telescopes have to develop very different means of statistically identifying and removing cosmic ray events. Some of the parameters, which could be potentially important for non-imaging arrays, are the temporal and spectral differences, the lateral distributions and density fluctuations of Čerenkov photons generated by γ-ray and hadron primaries. Here we study the differences in fluctuations of Čerenkov photon density in the light pool at the observation level from showers initiated by photons and those initiated by protons or heavier nuclei. The database of simulated events for the PACT array has been used to evaluate the efficiency of the new technique. Various types of density fluctuations like the short range and medium range fluctuations as well as flatness parameter are studied. The estimated quality factors reflect the efficiencies with which the hadrons can be rejected from the data. Since some of these parameters are independent, the cuts may be applied in tandem and we demonstrate that the proton rejection efficiency of ∼90% can be achieved. Use of density fluctuations is particularly suited for wavefront sampling observations and it seems to be a good technique to improve the signal to noise ratio. This revised version was published online in July 2006 with corrections to the Cover Date.     

Slump debris flows in the Akovolwo Mountains area of Benue State,Nigeria

In September 1979, rain-induced complex landslides occurred in two separate localities along the slopes of the Akovolwo Mountains near Jato-Aka in the Kwande Local Government area of Benue State, Nigeria.The two movements developed on bedrock slopes covered by a veneer of colluvium and (or) residuum no more than 1.5 to 2m deep. Each started as a slump and graduated into a debris flow. The slump, extending downhill a short distance away from the head scarp, had been reconstituted into a debris flow as the initial movement (sliding movement) of the soil mass caused remoulding of the saturated moving mass into viscous debris-laden mud. The resulting mass moved partly along a pre-existing mountain stream channel and partly along a fresh channel it cleared in the savanna forest. At the break of slope, the mass of boulders was dumped and a trail of smaller fragments littered the channels towards the Katsina-Ala River.