Authigenic carbonate mineral formation in the Pagassitikos palaeolake during the latest Pleistocene, central Greece

The Pagassitikos Gulf in Greece is a semi-enclosed bay with a maximum depth of 102 m. According to the present-day bathymetric configuration and the sea level during the latest Pleistocene, the gulf would have been isolated from the open sea, forming a palaeolake since ~32 cal. ka b.p. Sediment core B-4 was recovered from the deepest sector of the gulf and revealed evidence of a totally different depositional environment in the lowest part of the core: this contained light grey-coloured sediments, contrasting strongly with overlying olive grey muds. Multi-proxy analyses showed the predominance of carbonate minerals (aragonite, dolomite and calcite) and gypsum in the lowest part of the core. Carbonate mineral deposition can be attributed to autochthonous precipitation that took place in a saline palaeolake with high evaporation rates during the last glacial–early deglacial period; the lowest core sample to be AMS ¹⁴C dated provided an age of 19.53 cal. ka b.p. The palaeolake was presumably reconnected to the open sea at ~13.2 cal. ka b.p. during the last sea-level rise, marking the commencement of marine sedimentation characterised by the predominance of terrigenous aluminosilicates and fairly constant depositional conditions lasting up to the present day.     

Lagrangian analysis of mixing and transport of water masses in the marine bays

The Lagrangian approach to studying the mixing and transport of a passive admixture in marine bays and gulfs based on the methods of a theory of dynamic systems is developed. This approach is employed to investigate the lateral mixing and transport of waters in the Peter the Great Bay, Japan Sea, using a velocity field of the predictive numerical hydrodynamic circulation model of a synoptic scale. It is shown that the Lagrangian characteristics, such as the maximum accumulated Lyapunov exponent, the time of particle stay in the bay, particle relative displacements, and the number of cyclonic and anticyclonic rotations, allow us to describe the movement of water masses, the character of mixing, and chaos in the Bay. In integrating the advection equations forward and backward in time, maps showing a number of particle arrivals to different regions of the Bay make it possible to establish corridors through which particles leave and enter the Bay.     

A control-volume finite-element method for three-dimensional multiphase basin modeling

In this paper we describe a 3D control-volume finite-element method to solve numerically the coupled partial differential equations (PDEs) governing geological processes involved in the evolution of sedimentary basins. These processes include sediment deposition and deformation, hydrocarbon generation, multiphase fluid flow, and heat transfer in deforming porous media.     

Dynamics of structural and functional characteristics of zooplankton in the Northern Sea of Okhotsk in the “Warm” and “Cold” years

An analysis of the structural and functional characteristics of zooplankton community and their coupling with the synoptic situation was carried out for the spring period in the northern Sea of Okhotsk. The years of 2000 and 2001 may be referred to as “cold” type due to the significant extent of the ice-covered area. Based on the ice cover extent, the years of 2004 and 2005 may be referred to as “warm” years due to the decreased extent of the ice-covered area. The “cold” and “warm” years did not significantly differ from each other in terms of the total zooplankton biomass. In the northeast Sea of Okhotsk, the zooplankton abundance increased during the “cold” years, while, in its northwestern part, the zooplankton abundance increased during the “warm” years. The different types of years significantly differ in the species structure of the macrozooplankton community. The abundance of copepods was higher in the “warm” years, whereas the chaetognath abundance increased in the “cold” ones. These features of the dynamics and distribution of zooplankton in the northern part of the Sea of Okhotsk also affected its productivity. The higher production of the elements of the zooplankton community that was revealed in the “warm” years was caused by the increase in the seasonal P/B ratio of both nonpredatory and predatory species. In the “warm” years, the production of nonpredatory zooplankton was higher in the northwest, while, in the “cold” years, it was higher in the northeast of the area.     

Pteropods in Southern Ocean ecosystems

To date, little research has been carried out on pelagic gastropod molluscs (pteropods) in Southern Ocean ecosystems. However, recent predictions are that, due to acidification resulting from a business as usual approach to CO₂ emissions (IS92a), Southern Ocean surface waters may begin to become uninhabitable for aragonite shelled thecosome pteropods by 2050. To gain insight into the potential impact that this would have on Southern Ocean ecosystems, we have here synthesized available data on pteropod distributions and densities, assessed current knowledge of pteropod ecology, and highlighted knowledge gaps and directions for future research on this zooplankton group.Six species of pteropod are typical of the Southern Ocean south of the Sub-Tropical Convergence, including the four Thecosomes Limacina helicina antarctica, Limacina retroversa australis, Clio pyramidata, and Clio piatkowskii, and two Gymnosomes Clione limacina antarctica and Spongiobranchaea australis. Limacina retroversa australis dominated pteropod densities north of the Polar Front (PF), averaging 60 ind m⁻³ (max = 800 ind m⁻³) and 11% of total zooplankton at the Prince Edward Islands. South of the PF L. helicina antarctica predominated, averaging 165 ind m⁻³ (max = 2681 ind m⁻³) and up to >35% of total zooplankton at South Georgia, and up to 1397 ind m⁻³ and 63% of total zooplankton in the Ross Sea. Combined pteropods contributed <5% to total zooplankton in the Lazarev Sea, but 15% (max = 93%) to macrozooplankton in the East Antarctic. In addition to regional density distributions we have synthesized data on vertical distributions, seasonal cycles, and inter-annual density variation.Trophically, gymnosome are specialist predators on thecosomes, while thecosomes are considered predominantly herbivorous, capturing food with a mucous web. The ingestion rates of L. retroversa australis are in the upper range for sub-Antarctic mesozooplankton (31.2-4196.9 ng pig ind⁻¹ d⁻¹), while those of L. helicina antarctica and C. pyramidata are in the upper range for all Southern Ocean zooplankton, in the latter species reaching 27,757 ng pig ind⁻¹ d⁻¹ and >40% of community grazing impact. Further research is required to quantify diet selectivity, the effect of phytoplankton composition on growth and reproductive success, and the role of carnivory in thecosomes.Life histories are a significant knowledge gap for Southern Ocean pteropods, a single study having been completed for L. retroversa australis, making population studies a priority for this group. Pteropods appear to be important in biogeochemical cycling, thecosome shells contributing >50% to carbonate flux in the deep ocean south of the PF. Pteropods may also contribute significantly to organic carbon flux through the production of fast sinking faecal pellets and mucous flocs, and rapid sinking of dead animals ballasted by their aragonite shells. Quantification of these contributions requires data on mucous web production rates, egestion rates, assimilation efficiencies, metabolic rates, and faecal pellet morphology for application to sediment trap studies.Based on the available data, pteropods are regionally significant components of the Southern Ocean pelagic ecosystem. However, there is an urgent need for focused research on this group in order to quantify how a decline in pteropod densities may impact on Southern Ocean ecosystems.     

Response of Nereis diversicolor population (Polychaeta,Nereididae) to the pollution impact – Authie and Seine estuaries (France)

A survey within the French National Programme of Ecotoxicology was carried out in 2002, 2003 and 2004 to study the response of Nereis diversicolor populations (Polychaeta, Nereididae) to the impact of pollution in the Authie estuary (non-contaminated site) and in the Seine estuary (contaminated site). In the period studied, the density varied from 672 ind. m⁻² to 3584 ind. m⁻² in the Authie estuary and from 80 ind. m⁻² to 920 ind. m⁻² in the Seine estuary. Biomass varied from 3.94 g m⁻² (dry weight) in February 2004 to 38.0 g m⁻² in August 2003 in the Authie estuary and from 3.4 g m⁻² in February 2002 to 0.6 g m⁻² in February 2004 in the Seine estuary. Density and biomass of the populations of N. diversicolor were consistently lower in the Seine estuary than in the Authie estuary. Size frequency histograms permit the analysis of the cohorts as well as the elaboration of the growth curves. For the individuals from the Authie estuary, the relation between dry weight (DW) and length L3 (prostomium, peristomium and chaetiger 1) was DW = 4.2205 L3^2.9832. For those from the Seine estuary, the relation between dry weight and L3 was DW = 0.4697e^1.7209L3. The individuals of N. diversicolor should belong to eight cohorts in Authie estuary (two cohorts each year) instead of six cohorts for those from the Seine estuary. These differences can be attributed to the effect of pollution on the population of N. diversicolor.     

A comparison of economic performance in the fisheries sector: A short- and long-term perspective

Indicators of the economic performance of fishing vessels are frequently computed in various countries. In this paper, we use different types of information to assess capital value and the economic performance of fishing vessels. On the one hand, field surveys provide technical and financial information on the main components of fishing capital. On the other hand, book values are given in bookkeeping databases. We use both sources of information on fishing capital are used for the same set of vessels, namely the commercial fishing fleet of the French region of Brittany. Based on these two sources, measures of economic performance can be produced for the short term using gross surplus; and for the long term including the cost of capital. The measures of performance obtained are presented and the differences between them are then discussed.     

Fundamental study for morphodynamic modelling: Sand mounds in oscillatory flows

Experiments on sand mounds in oscillatory flow, undertaken in controlled, large-scale laboratory conditions, have produced well-defined data sets for model comparison. Three bathymetries with different levels of submergence, including a surface-piercing case, were tested. The maximum slope was about 1:5.5. Sediment transport is due to bed load with ripple formation. The principal time-dependent bulk parameters are the vertical distance of the centre of gravity above the base and the volume of the mound. A semi-implicit finite-volume depth-averaged hydrodynamic model is used to drive morphodynamics, using van Rijn's sediment flux model generalized to take account of bed slope, and some justification is given for depth-averaged modeling in these conditions. Starting the model runs with the conditions at the end of the first cycle avoided initial atypical physical behaviour. In general good predictions were obtained with an angle of repose reduced from the standard value of about 30° for stationary beds to 15°. For these situations, morphodynamics was largely unaffected by a hydrodynamic roughness height in the range 2.5D₅₀ to 51D₅₀, with larger values accounting for ripple roughness. The reduced angle of repose may be physically expected with mobile beds but this specific value is only expected to be suited to this form of bed motion. In one case an exaggerated ripple formed near the top of the mound reducing agreement with experiment. For the submerged case with normal ripple structure excellent predictions were obtained. For the initially surface-piercing mound, the time of submergence was better predicted with a 30° angle of repose, presumably due to the prominent influence of the near stationary bed near the wet/dry interface, although long term predictions were better predicted with 15°. The occurrence of vortex shedding in the first cycle modeled was in agreement with experimental observation.     

On the energy dissipation of jacket type offshore platforms with different pile–leg interactions

In recent years, considerable amount of effort has been made to design earthquake resistant offshore structures in seismic active areas. In order to achieve this objective, all components of a typical structure should function properly to dissipate seismically-induced energy within the members. Among components of an offshore installation, braces are of significant importance as they contribute substantially to total energy dissipation of the structure. Buckling in compression and yielding in tension assist the process of energy absorption. Nevertheless, the functionality of braces is dependent upon their joints where joint-cans are included to avoid any brittle fracture and unpredicted failure mechanisms.In this paper, special attention is being paid to energy dissipation of jacket type offshore platforms with two different pile–leg interactions. A case study representing an offshore platform is studied both analytically and experimentally. Analytical models are validated step by step based on available experimental tests and observations on individual members. Several parameters such as cyclic behavior, maximum bearing load and most importantly energy dissipation of two different 2D frames are investigated. Results provide promising insights into design and fabrication of fixed platforms with different pile–leg interactions.     

Methylmercury production in sediments of Chesapeake Bay and the mid-Atlantic continental margin

Methylmercury (MeHg) concentration and production rates were studied in bottom sediments along the mainstem of Chesapeake Bay and on the adjoining continental shelf and slope. Our objectives were to 1) observe spatial and temporal changes in total mercury (HgT) and MeHg concentrations in the mid-Atlantic coastal region, 2) investigate biogeochemical factors that affect MeHg production, and 3) examine the potential of these sediments as sources of MeHg to coastal and open waters. Estuarine, shelf and slope sediments contained on average 0.5 to 1.5% Hg as MeHg (% MeHg), which increased significantly with salinity across our study site, with weak seasonal trends. Methylation rate constants (k_meth), estimated using enriched stable mercury isotope spikes to intact cores, showed a similar, but weaker, salinity trend, but strong seasonality, and was highly correlated with % MeHg. Together, these patterns suggest that some fraction of MeHg is preserved thru seasons, as found by others [Orihel, D.M., Paterson, M.J., Blanchfield, P.J., Bodaly, R.A., Gilmour, C.C., Hintelmann, H., 2008. Temporal changes in the distribution, methylation, and bioaccumulation of newly deposited mercury in an aquatic ecosystem. Environmental Pollution 154, 77] Similar to other ecosystems, methylation was most favored in sediment depth horizons where sulfate was available, but sulfide concentrations were low (between 0.1 and 10 μM). MeHg production was maximal at the sediment surface in the organic sediments of the upper and mid Bay where oxygen penetration was small, but was found at increasingly deeper depths, and across a wider vertical range, as salinity increased, where oxygen penetration was deeper. Vertical trends in MeHg production mirrored the deeper, vertically expanded redox boundary layers in these offshore sediments. The organic content of the sediments had a strong impact on the sediment:water partitioning of Hg, and therefore, on methylation rates. However, the HgT distribution coefficient (K_D) normalized to organic matter varied by more than an order of magnitude across the study area, suggesting an important role of organic matter quality in Hg sequestration. We hypothesize that the lower sulfur content organic matter of shelf and slope sediments has a lower binding capacity for Hg resulting in higher MeHg production, relative to sediments in the estuary. Substantially higher MeHg concentrations in pore water relative to the water column indicate all sites are sources of MeHg to the water column throughout the seasons studied. Calculated diffusional fluxes for MeHg averaged  1 pmol m^− 2 day^− 1. It is likely that the total MeHg flux in sediments of the lower Bay and continental margin are significantly higher than their estimated diffusive fluxes due to enhanced MeHg mobilization by biological and/or physical processes. Our flux estimates across the full salinity gradient of Chesapeake Bay and its adjacent slope and shelf strongly suggest that the flux from coastal sediments is of the same order as other sources and contributes substantially to the coastal MeHg budget.