On the sampling of airborne measurements of radiative properties of cloud fields: Results from International Cirrus Experiment (ICE), 1987

Summary During the first pilot phase of the International Cirrus Experiment (ICE) in September/October 1987 radiation measurements were carried out above and below broken cloud fields over the German Bight. Analyses of the measurements of 25.9.1987 (broken cumulus cloud field) showed an unexpected high absorption of solar radiation but not those of 28.9.1987 (stratocumulus/stratus cloud field). This might be explained by a partial negligence of cloud side factor under the viewing geometry of the pyranometer and other reasons. The light guide effect (leakage) within holes can account for the depletion of cloud reflectance and the enhancement of cloud transmittance at large cloud cover, as observed during the measurements on 28.9.1987. The fluctuation of the irradiances, which can be characterized by the intermittency parameter, has been related to the corresponding cloud cover by a regression equation. On the condition of similarity, this scaling parameter derived from sample measurements could be extrapolated to that of the whole cloud field. Thus, the estimation of the irradiance spectrum for the whole cloud field may be possible, from samples taken with aircraft and imaging data.With 5 Figures     

Correlation methods in fingerprint detection studies

This investigation addresses two general issues regarding the role of pattern similarity statistics in greenhouse warming detection studies: normalization, and the relative merits of centered versus uncentered statistics. A pattern correlation statistic is used to search for the greenhouse warming signals predicted by five different models in the observed records of land and ocean surface temperature changes. Two forms of this statistic were computed: R (t), which makes use of nonnormalized data, and (t), which employs point-wise normalized data in order to focus the search on regions where the signal-to-noise ratio is large. While there are no trends in the R (t) time series, the time series of (t) show large positive trends. However, it is not possible to infer from the (t) results that the observed pattern of temperature change is, in fact, becoming increasingly similar to the model-predicted signal. This is because point-wise normalization of the observed and simulated mean change fields by a single common field introduces a common factor effect, which means that the quantities being compared should show some similarity a priori. This does not necessarily make normalization inapplicable, because the detection test involves seeking a trend in the similarity statistic. We show, however, that trends in (t) must arise almost completely from the observed data, and cannot be an indicator of increasing observed data/signal similarity. We also compare the information provided by centered statistics such as R(t) and the uncentered C(t) statistic introduced by Barnett. We show that C(t) may be expressed as the weighted sum of two terms, one proportional to R(t) and the other proportional to the observed spatial mean. For near-surface temperatures, the spatial average term dominates over the R(t) term. In this case the use of C(t) is equivalent to the use of spatial-mean temperature. We conclude that at present, the most informative pattern correlation statistic for detection purposes is R(t), the standard product-moment correlation coefficient between the observed and model fields. Our failure to find meaningful trends in R(t) may be due to the fact that the signal is being obscured by the background noise of natural variability, and/or because of incorrect model signals or sensitivities.     

Coupling an ocean wave model to an atmospheric general circulation model

A coupled model, consisting of an ocean wave model and an atmospheric general circulation model (AGCM), is integrated under permanent July conditions. The wave model is forced by the AGCM wind stress, whereas the wind waves modify the AGCM surface fluxes of momentum, sensible and latent heat. We investigate the following aspects of the coupled model: how realistic are the wave fields, how strong is the coupling, and how sensitive is the atmospheric circulation to the spatially and temporally varying wave field. The wave climatology of the coupled model compares favorably with observational data. The interaction between the two models is largest (although weak) in the storm track in the Southern Hemisphere. Young windsea, which is associated with enhanced surface fluxes is generated mostly in the equatorward frontal area of an individual cyclone. However, the enhancement of the surface fluxes is too small to significantly modify the climatological mean atmospheric circulation.This paper was presented at the Second International Conference on Modelling of Global Climate Variability, held in Hamburg 7–11 September 1992 under the auspices of the Max Planck Institute for Meteorology. Guest Editor for these papers is L. Dümenil     

Experimental investigation and application of the equilibrium rutile + orthopyroxene = quartz + ilmenite

Equilibria in the Sirf (Silica-Ilmenite-Rutile-Ferrosilite) system: $${\text{SiO}}_{\text{2}} + ({\text{Mg,Fe}}){\text{TiO}}_{\text{3}} {\text{ + (Mg,Fe)SiO}}_{\text{3}} $$ have been calibrated in the range 800–1100° C and 12–26 kbar using a piston-cylinder apparatus to assess the potential of the equilibria for geobarometry in granulite facies assemblages that lack garnet. Thermodynamic calculations indicate that the two end-member equilibria involving quartz + geikielite = rutile + enstatite, and quartz + ilmenite = rutile + ferrosilite, are metastable. We therefore reversed equilibria over the compositional range Fs_40–70, using Ag₈₀Pd₂₀ capsules with \(f_{{\text{O}}_{\text{2}} } \) buffered at or near iron-wüstite. Ilmenite compositions coexisting with orthopyroxene are \(X_{{\text{MgTiO}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.06 to 0.15 and \(X_{{\text{Fe}}_{\text{2}} {\text{O}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.00 to 0.01, corresponding toK _D values of 13.3, 10.2, 9.0 and 8.0 (±0.5) at 800, 900, 1000 and 1100° C, respectively, whereK _D =(XMg/XFe)^Opx/(XMg/XFe)^Ilm. Pressures have been calculated using equilibria in the Sirf system for granulites from the Grenville Province of Ontario and for granulite facies xenoliths from central Mexico. Pressures are consistent with other well-calibrated geobarometers for orthopyroxeneilmenite pairs from two Mexican samples in which oxide textures appear to represent equilibrium. Geologically unreasonable pressures are obtained, however, where oxide textures are complex. Application of data from this study on the equilibrium distribution of iron and magnesium between ilmenite and orthopyroxene suggests that some ilmenite in deep crustal xenoliths is not equilibrated with coexisting pyroxene, while assemblages from exposed granulite terranes have reequilibrated during retrogression. The Sirf equilibria are sensitive to small changes in composition and may be used for determination of activity/composition (a/X) relations of orthopyroxene if an ilmenite model is specified. A symmetric regular solution model has been used for orthopyroxene in conjunction with activity models for ilmenite available from the literature to calculatea/X relations in orthopyroxene of intermediate composition. Data from this study indicate that FeSiO₃?MgSiO₃ orthopyroxene exhibits small, positive deviations from ideality over the range 800–1100°C.     

Stratiform and vein U,Mo and Cu mineralization in the Novoveská Huta area,CSFR

U-Mo and Cu mineralization occurs in horizons as well as in veins in the Permian formations near Novoveská Huta. Ore mineralization is represented by uraninite, U-Ti oxides, coffinite, molybdenite, chalcopyrite, tennantite and pyrite. The isotopic composition of S and C displays a larger variability in the stratiform ores (³⁴S from –32.7 to +2.7 and ¹³C from –27.1 to — 0.5) These data suggest mixing of meteoric solutions with fluids of volcanic origin and a complex history. There is a narrower range of ³⁴S from –18.8 to –4.6 and ¹³C from –6.3 to –2.5% in quartz-carbonate veins with Cu mineralization suggesting a deep source of ore-bearing solutions. The Permian volcanics were a significant source of ore elements.Their contents of U, Mo, Cu and Y are from two to eight times higher than in sedimentary rocks. Accumulations of ore elements in the horizons were formed by the reduction and adsorption processes 240 ± 30 Ma ago according to U-Pb isotopic dating. Due to Alpine tectonism, these low-grade ores (U<0.1 wt%) were remobilized and higher-grade U-Mo ores (U>0.1 wt%) were formed 130 ± 20 Ma ago at temperatures ranging from 110 to 120° C, according to fluid inclusions. Younger veins with Cu mineralization were formed 115 ± 10 Ma according to the model age of Pb at temperatures ranging from 95 to 190°C.     

Recreation on public lands in New Zealand — past,present and future

Since the turn of the century, recreation has grown as a motivating force in public land administration. Today, the Department of Conservation manages approximately one third of New Zealand's outdoor recreation resources and has the mandate to foster the use of natural and historic resources for recreation, and to allow their use for tourism (Conservation Act 1987:8). This paper traces the emergence of a recreation perspective within public land administration and examines the development of a recreation philosophy and policy within the Department of Conservation. It suggests future directions for outdoor recreation management in New Zealand.     

Cu 2p absorption spectroscopy as a probe for the site occupancy of (ZnxCu1−x)WO4 solid solution

The solid solution sanmartinite (ZnWO₄)—cuproscheelite (CuWO₄) has been studied using Cu 2p X-ray absorption spectroscopy. While a single L₃ absorption peak is observed for CuWO₄, two distinct L₃ absorption peaks with a separation of ～0.8 eV are observed for the intermediate samples in the solid solution. The two peaks represent distinct Cu sites: one with all CuO₆ next nearest neighbours in the (Cu,Zn)O₆ chains, another having at least one ZnO₆ next nearest neighbour. Both sites show a linear increase in covalency as a function of increasing Cu-content. The relative intensities of the two absorption peaks is dependent upon the Cu-content and has been used to model the site occupancies. The results reveal that the local structural effects can be associated with a composition-dependent structural phase transition from P2/c (ZnWO₄) to P $\bar 1$ (CuWO₄). Deviations from a single-site model are explained in terms of the local environments, and evidence for site preferences and local clustering are explored.     

The emplacement of intermediate volume ignimbrites: A case study from Roccamonfina Volcano,Southern Italy

A model is presented for the emplacement of intermediate volume ignimbrites based on a study of two 6 km³ volume ignimbrites on Roccamonfina Volcano, Italy. The model considers that the flows were slow moving, and quickly deflated from turbulent to non-turbulent conditions. Yield strength and density increased whereas fluidisation decreased with time and runout of the pyroclastic flows. In proximal locations, on the caldera rim, heterogeneous exposures including discontinuous lithic breccias, stratified and cross-stratified units interbedded with massive ignimbrite suggest deposition from turbulent flows. In medial locations thick, massive ignimbrite occurs associated with three types of co-ignimbrite lithic breccia which we interpret as being emplaced by non-turbulent flows. Multiple grading of different breccia/lithic concentration types within single flow units indicates that internal shear occurred producing overriding or overlapping of the rear of the flow onto the slower-moving front part. This overriding of different parts of non-turbulent pyroclastic flows could be caused by at least two different mechanisms: (1) changes in flow regime, such as hydraulic jumps that may occur at breaks in slope; and (2) periods of increased discharge rate, possibly associated with caldera collapse, producing fresh pulses of lithic-rich material that sheared onto the slower-moving part of the flow in front.We propose that ground surge deposits enriched in pumice compared with their associated ignimbrite probably formed by a flow separation mechanism from the top and front of the pyroclastic flow. These turbulent clouds moved ahead of the non-turbulent lower part of the flow to form stratified pumice-rich deposits. In distal regions well-developed coarse, often clast-supported, pumice concentrations zones and coarse intra-flow-unit lithic concentrations occur within the massive ignimbrite. We suggest that the flows were non-turbulent, possessed a relatively high yield strength and may have moved by plug flow prior to emplacement.     

Automatic equipment to monitor groundwater radon

Prototype instrumentation, able to automatically measure groundwater radon content variations, is presented. The equipment is made of stainless steel and has spherical valves with automatic and pneumatic control. The deemanation of the gases from the water is obtained by evacuating a suitable expansion chamber. The instrumentation can make discrete sampling ranging from 1 per hour to 1 per 99 hours. The equipment was tested in the laboratory: the efficiency was measured by means of a²⁶⁶Ra solution. A mean value of (0.65±0.07) count/s/Bq was obtained. A calibration test was carried out by comparing countings from the automatic equipment with those obtained by the standard laboratory cell. Results of an operational check over a period of approximately one year indicate that variations in radon at the calibration site are attributable more to meteorological than to tectonic causes.     

Isotope and trace element evidence for three component mixing in the genesis of the North Luzon arc lavas (Philippines)

Post-3Ma volcanics from the N Luzon arc exhibit systematic variations in ⁸⁷Sr/⁸⁶Sr (0.70327–0.70610), ¹⁴³Nd/¹⁴⁴Nd (0.51302–0.51229) and ²⁰⁸Pb^*/²⁰⁶Pb^* (0.981–1.035) along the arc over a distance of about 500 km. Sediments from the South China Sea west of the Manila Trench also exhibit striking latitudinal variations in radiogenic isotope ratios, and much of the isotopic range in the volcanics is attributed to variations in the sediment added to the mantle wedge during subduction. However, Pb-Pb isotope plots reveal that prior to subduction, the mantle end-member had high 8/4, and to a lesser extent high 7/4, similar to that in MORB from the Indian Ocean and the Philippine Sea Plate. Th isotope data on selected Holocene lavas indicate a source with unusually high Th/U ratios (4.5–5.5). Combined trace element and isotope data require that three end-members were implicated in the genesis of the N Luzon lavas: (1) a mantle wedge end-member with a Dupal-type Pb isotope signature, (2) a high LIL/HFS subduction component interpreted to be a slab-derived hydrous fluid, and (3) an isotopically enriched end-member which reflects bulk addition (<5%) of subducted S China Sea terrigenous sediment. The ⁸⁷Sr/⁸⁶Sr ratios in the volcanics show a restricted range compared with that in the sediments, and this contrasts with ¹⁴³Nd/¹⁴⁴Nd and ²⁰⁸Pb^*/²⁰⁶Pb^*, both of which have similar ranges in the volcanics and sediments. Such differences imply that whereas the isotope ratios of Nd, Pb and Th are dominated by the component from subducted sediment, those of Sr reflect a larger relative contribution from the slab-derived fluid.