Transport of three herbicides in ground water at Twin Lake test site,Chalk River,Ontario, Canada

A field tracer test performed under natural flow conditions at the Twin Lake test site, Chalk River Laboratories of the Atomic Energy of Canada Ltd. in Chalk River, Ontario, Canada, using tritium and three herbicides (Chlortoluron, Terbuthylazine, and Pendimethalin) was interpreted using the dispersion equation with a combined reaction model. The reaction model couples an instantaneous equilibrium reaction governed by a linear adsorption isotherm with a reversible or irreversible kinetic reaction of the first order, and decay. An improved interpretation method consists of a simultaneous fitting of theoretical concentration and mass-recovery curves to the experimental data, which leads to a more reliable determining of reaction models and improves the accuracy of fitting. Tritium served as the reference tracer to determine the flow velocity, dispersivity, and the recovery of the herbicides. Chlortoluron was slightly delayed by equilibrium exchange with strongly reduced concentration due to an irreversible kinetic reaction and/or decay. Terbuthilazine was slightly delayed by equilibrium exchange, with strongly reduced concentration due to a reversible kinetic reaction with some influence of decay. A strong equilibrium reaction and a strong reversible kinetic reaction without degradation governed the transport of Pendimethalin, reducing considerably its concentration. The results obtained show that simulations based only on Kd and decay constant, especially if these parameters are found in the laboratory, may considerably differ from those performed with reaction parameters determined in properly performed field tests. The dominant reaction types, and the values of parameters found in the study, supply useful information on the transport of the investigated herbicides in sandy aquifers under natural flow conditions.     

Petrogenesis of voluminous mid-Tertiary ignimbrites of the Sierra Madre Occidental,Chihuahua, Mexico

The mid-Tertiary ignimbrites of the Sierra Madre Occidental of western Mexico constitute the largest continuous rhyolitic province in the world. The rhyolites appear to represent part of a continental magmatic arc that was emplaced when an eastward-dipping subduction zone was located beneath western Mexico.In the Batopilas region of the northern Sierra Madre Occidental the mid-Tertiary Upper Volcanic sequence is composed predominantly of rhyolitic ignimbrites, but volumetrically minor lava flows as mafic as basaltic andesite are also present. The basaltic andesite to rhyolite series is calc-alkalic and contains 1% K₂O at 60% SiO₂. Trace element abundances of a typical ignimbrite with 73% SiO₂ are Sr 225 ppm, Rb 130 ppm, Y 32 ppm, Th 12 ppm, Zr 200 ppm, and Nb 15 ppm. The entire series plots as coherent and continuous trends on variation diagrams involving major and trace elements, and the trends are distinct from those of geographicallyassociated rocks of other suites. We interpret these and other geochemical variations to indicate that the rocks are comagmatic. Mineral chemistry, Sr isotopic data, and REE modelling support this interpretation.Least squares calculations show that the major element variations are consistent with formation of the basaltic andesite to rhyolite series by crystal fractionation of observed phenocryst phases in approximate modal proportions. In addition, calculations modelling the behavior of Sr with the incompatible trace element Th favor a fractional crystallization origin over a crustal anatexis origin for the rock series. The fractionating minerals included plagioclase (> 50%), and lesser amounts of Fe-Ti oxides, pyroxenes, and/or hornblende. The voluminous ignimbrites represent no more than 20% of the original mass of a mantle-derived mafic parental magma.     

Steady state hodographs in a baroclinic boundary layer

If the steady-state geostrophic wind vector varies exponentially with height in the planetary boundary layer, calculated hodographs of the 24-hour mean wind resemble the classic Ekman spiral distorted by thermal effects. For such an assumed distribution, Lettau's (1967) conclusion that the effects of thermal influence on the steady-state boundary-layer winds can be linearly superimposed on the effects of internal friction is justified.The minimum value of the cross-isobar angle of the surface wind for a given magnitude of the thermal wind vector occurs when that vector points about 345° to the right of the surface geostrophic wind vector and the maximum value occurs when it points at an azimuth of about 120° relative to the surface geostrophic wind vector. The range of values of the cross-isobar angle is almost directly proportional to the magnitude of the thermal wind vector.Hodographs resulting from the assumed variation of the geostrophic wind have approximately the same shape as 24-hour mean hodographs at two locations over the Great Plains.This work is part of a thesis submitted to the University of Wisconsin in partial fulfillment of the requirements for the Ph.D. Degree, written under the supervision of Professor H. Lettau, Department of Meteorology.     

Sedimentology and kinematics of a large, retrogressive growth-fault system in Upper Carboniferous deltaic sediments, western Ireland

Growth faulting is a common feature of many deltaic environments and is vital in determining local sediment dispersal and accumulation, and hence in controlling the resultant sedimentary facies distribution and architecture. Growth faults occur on a range of scales, from a few centimetres to hundreds of metres, with the largest growth faults frequently being under‐represented in outcrops that are often smaller than the scale of feature under investigation. This paper presents data from the exceptionally large outcrops of the Cliffs of Moher, western Ireland, where a growth‐fault complex affects strata up to 60 m in thickness and extends laterally for ≈ 3 km. Study of this Namurian (Upper Carboniferous) growth‐fault system enables the relationship between growth faulting and sedimentation to be detailed and permits reconstruction of the kinematic history of faulting. Growth faulting was initiated with the onset of sandstone deposition on a succession of silty mudstones that overlie a thin, marine shale. The decollement horizon developed at the top of the marine shale contact for the first nine faults, by which time aggradation in the hangingwall exceeded 60 m in thickness. After this time, failure planes developed at higher stratigraphic levels and were associated with smaller scale faults. The fault complex shows a dominantly landward retrogressive movement, in which only one fault was largely active at any one time. There is no evidence of compressional features at the base of the growth faults, thus suggesting open‐ended slides, and the faults display both disintegrative and non‐disintegrative structure. Thin‐bedded, distal mouth bar facies dominate the hangingwall stratigraphy and, in the final stages of growth‐fault movement, erosion of the crests of rollover structures resulted in the highest strata being restricted to the proximity of the fault. These upper erosion surfaces on the fault scarp developed erosive chutes that were cut parallel to flow and are downlapped by the distal hangingwall strata of younger growth faults.     

Trace element distributions in aquatic sediments of Danang – Hoian area, Vietnam

 Distribution of the trace elements Cr, Cu, Ni, Pb and Zn in surficial sediments of the river/sea environment in Danang – Hoian area (Vietnam) was investigated to examine the degree of metal pollution caused by anthropogenic activities. Point sources from domestic and industrial wastes are identified as dominant contributors of trace element accumulation. Surficial sediments of Hoian River show extremely high total concentrations of Cu (Average Concentration 295 μg/g), Ni (AC 112 μg/g), Pb (AC 396 μg/g) and Zn (AC 429 μg/g) that exceed assigned safety levels ER-M. Similarly, the sediments of Han River show high Pb (AC 188 μg/g) and Zn (AC 282 μg/g) contents. In marine sediments of Thanhbinh beach Pb is also enriched (138 μg/g) above guideline levels. In contrast the sediments of the Cude River are dominated by trace element concentrations close to background values. Received: 17 December 1998 · Accepted: 6 May 1999     

Ice flow direction during late Paleozoic glaciation in western Paraná Basin, Brazil

The recent discovery of ice-striated surfaces associated with the late Paleozoic Aquidauana Formation suggests that glaciers coming from southwest Africa reached westernmost parts of the Paraná Basin in central Brazil. Abrasion features were developed by glaciers moving from SSE towards NNW, mainly on an unconsolidated bed. These records expand to about 1,050,000 km², the coverage of the late Paleozoic glaciation in the region of the Paraná Basin in Western Gondwana.

Resumen

A recente descoberta de superfícies estriadas associadas à Formação Aquidauana, de idade permocarbonífera, sugere que as geleiras provenientes do sudoeste da África alcançaram as porções ocidentais da Bacia do Paraná, na região central do Brasil. As feições de abrasão foram geradas pelo deslocamento de geleiras de SSE para NNW, principalmente sobre substrato inconsolidado. Estes novos registros evidenciam que a glaciação neopaleozóica cobriu uma área de pelo menos de 1.050.000 km² na região ocupada pela Bacia do Paraná no Gondwana Ocidental.     

Selenium concentration in food and blood of residents of Abeokuta Metropolis,Southwestern Nigeria

Selenium like any other element can both be essential and toxic depending upon the concentration at which it occurs in human diet. This paper assessed the level of this trace element in twenty different (20) types of locally produced food items around Abeokuta town and the blood obtained from the antecubital fossa vein of eighty-eight (88) healthy adults resident in Abeokuta.     

Thermodynamics of minerals of variable composition: Andradite-grossularite and pistacite-clinozoisite solid solutions

Exchange-mineral equilibria with Al and Fe³⁺ aqueous chloride solutions (aq.), Andr + AlCl _aq ³ = FeCl _aq ³ + Gros, (1) Psc + AlCl _aq ³ = FeCl _aq ³ + Czo, (2) were studied under the following experimental conditions: 500°;C and 580°;C and 1 and 2 kbar, respectively, with an overall concentration of metals in the aqueous solutions of about 0.5 M and pH 3. The mixing functions of the components in garnet and epidote were calculated from the experimental data. Thermodynamic treatment of experimental evidence for reaction (1) led to the conclusion that, within the accuracy of experiment, garnet in the andradite-grossularite series was an ideal solid solution. However, epidote solid solution markedly departed from the ideal, as was shown by concentration and pressure-temperature (PT) dependencies of Gibbs's molar excess energies and by mixing-volume concentration dependence.