Theoretical emission line strengths for Ov compared to EUV solar observations

RecentR-matrix calculations of electron impact excitation rates in Ov are used to derive the emission line intensity ratios (in energy units) $$\begin{gathered} R_1 = I(2s2p^{ 3} P - 2p^{2 3} P)/I(2s^{2 1} S_0 - 2s2p^{ 1} P_1 ) = I(761.1\mathop A\limits^ \circ )/I(629.7\mathop A\limits^ \circ ), \hfill \\ R_2 = I(2s^{2 1} S_0 - 2s2p^{ 3} P_1 )/I(2s^{2 1} S_0 - 2s2p^{ 1} P_1 ) = I(1218.4\mathop A\limits^ \circ )/I(629.7\mathop A\limits^ \circ ), \hfill \\ \end{gathered} $$ and $$R_3 = I(2s2p^{ 1} P_1 - 2p^{2 1} S_0 )/I(2s^{2 1} S_0 - 2s2p^{ 1} P_1 ) = I(774.5\mathop A\limits^ \circ )/I(629.7\mathop A\limits^ \circ )$$ as a function of electron temperature (T _e) and density (N _e). These results are presented as plots ofR ₁ vsR ₂, andR ₁ vsR ₃, which should allowboth N _e andT _e to be deduced for the Ov line emitting region of a plasma. Electron densities derived from the (R ₁,R ₂) and (R ₁,R ₃) diagrams in conjunction with observational data for several solar features obtained with the Harvard S-055 spectrometer on boardSkylab are found to be compatible, and in good agreement with values ofN _e estimated from line ratios in species formed at similar electron temperatures to Ov. In addition, values ofT _e determined from (R ₁,R ₂) and (R ₁,R ₃) are generally close to that expected theoretically. These results provide experimental support for the accuracy of the diagnostic calculations presented in this paper, and hence the atomic data used in their derivation.     

Sub-arcsec 10 μm imaging of β pictoris and other star disk candidates

We have used the ESO 10 m camera, TIMMI, to image with a very high angular resolution (PFoV: 0.3; FWHM:0.9) several main-sequence star disk candidates. Information on the -Pictoris dust disk has been obtained in a region largely inaccessible to previous observations: 0–80 AU, with a resolution of about 5 AU after deconvolution. Another promising target for 10 m imaging, 51 Ophiuchi, appears point-like.based on data collected at the European Southern Observatory (ESO), La Silla, Chile     

On the sampling of airborne measurements of radiative properties of cloud fields: Results from International Cirrus Experiment (ICE), 1987

Summary During the first pilot phase of the International Cirrus Experiment (ICE) in September/October 1987 radiation measurements were carried out above and below broken cloud fields over the German Bight. Analyses of the measurements of 25.9.1987 (broken cumulus cloud field) showed an unexpected high absorption of solar radiation but not those of 28.9.1987 (stratocumulus/stratus cloud field). This might be explained by a partial negligence of cloud side factor under the viewing geometry of the pyranometer and other reasons. The light guide effect (leakage) within holes can account for the depletion of cloud reflectance and the enhancement of cloud transmittance at large cloud cover, as observed during the measurements on 28.9.1987. The fluctuation of the irradiances, which can be characterized by the intermittency parameter, has been related to the corresponding cloud cover by a regression equation. On the condition of similarity, this scaling parameter derived from sample measurements could be extrapolated to that of the whole cloud field. Thus, the estimation of the irradiance spectrum for the whole cloud field may be possible, from samples taken with aircraft and imaging data.With 5 Figures     

Correlation methods in fingerprint detection studies

This investigation addresses two general issues regarding the role of pattern similarity statistics in greenhouse warming detection studies: normalization, and the relative merits of centered versus uncentered statistics. A pattern correlation statistic is used to search for the greenhouse warming signals predicted by five different models in the observed records of land and ocean surface temperature changes. Two forms of this statistic were computed: R (t), which makes use of nonnormalized data, and (t), which employs point-wise normalized data in order to focus the search on regions where the signal-to-noise ratio is large. While there are no trends in the R (t) time series, the time series of (t) show large positive trends. However, it is not possible to infer from the (t) results that the observed pattern of temperature change is, in fact, becoming increasingly similar to the model-predicted signal. This is because point-wise normalization of the observed and simulated mean change fields by a single common field introduces a common factor effect, which means that the quantities being compared should show some similarity a priori. This does not necessarily make normalization inapplicable, because the detection test involves seeking a trend in the similarity statistic. We show, however, that trends in (t) must arise almost completely from the observed data, and cannot be an indicator of increasing observed data/signal similarity. We also compare the information provided by centered statistics such as R(t) and the uncentered C(t) statistic introduced by Barnett. We show that C(t) may be expressed as the weighted sum of two terms, one proportional to R(t) and the other proportional to the observed spatial mean. For near-surface temperatures, the spatial average term dominates over the R(t) term. In this case the use of C(t) is equivalent to the use of spatial-mean temperature. We conclude that at present, the most informative pattern correlation statistic for detection purposes is R(t), the standard product-moment correlation coefficient between the observed and model fields. Our failure to find meaningful trends in R(t) may be due to the fact that the signal is being obscured by the background noise of natural variability, and/or because of incorrect model signals or sensitivities.     

Cu 2p absorption spectroscopy as a probe for the site occupancy of (ZnxCu1−x)WO4 solid solution

The solid solution sanmartinite (ZnWO₄)—cuproscheelite (CuWO₄) has been studied using Cu 2p X-ray absorption spectroscopy. While a single L₃ absorption peak is observed for CuWO₄, two distinct L₃ absorption peaks with a separation of ～0.8 eV are observed for the intermediate samples in the solid solution. The two peaks represent distinct Cu sites: one with all CuO₆ next nearest neighbours in the (Cu,Zn)O₆ chains, another having at least one ZnO₆ next nearest neighbour. Both sites show a linear increase in covalency as a function of increasing Cu-content. The relative intensities of the two absorption peaks is dependent upon the Cu-content and has been used to model the site occupancies. The results reveal that the local structural effects can be associated with a composition-dependent structural phase transition from P2/c (ZnWO₄) to P $\bar 1$ (CuWO₄). Deviations from a single-site model are explained in terms of the local environments, and evidence for site preferences and local clustering are explored.     

The effect of orchard crop structure on the integral length-scale of turbulence

The integral length-scalesL for the three orthogonal components of diffusivityK=L are derived from spectral analysis of velocity time series measurements. A 3-D sonic anemometer was used to make these velocity measurements at heights in the range 0.7–7.0 m in and above a 2 m orchard canopy with near-neutral atmospheric boundary-layer stability conditions. The integral length-scale is compared with another length-scale of diffusionL obtained by fitting an exponential model to the auto-correlation spectrumR _E (t) in the region 0.95<R _E (t)<0.5 for smallt. This length-scale is appropriate to a high frequency region of the energy spectrum where turbulent momentum transport becomes diffusion-like and the turbulent energy varies with the inverse square of frequence. This region has been shown by others to determine the magnitude of the dissipation rate of turbulent energy by the action of viscosity even though the dominant dynamics are inviscid. Within the crop, the ratio of the length-scalesL/L were found to be smaller than the values measured above the crop for vertical turbulence. This was attributed to the enhanced decay rate of turbulent energy due to the effect of the airflow interaction with the crop. It is unclear whether similar effects are present in the horizontal plane because of greater scatter in the data, resulting from the more variable nature of the wind direction in the horizontal plane.     

The emplacement of intermediate volume ignimbrites: A case study from Roccamonfina Volcano,Southern Italy

A model is presented for the emplacement of intermediate volume ignimbrites based on a study of two 6 km³ volume ignimbrites on Roccamonfina Volcano, Italy. The model considers that the flows were slow moving, and quickly deflated from turbulent to non-turbulent conditions. Yield strength and density increased whereas fluidisation decreased with time and runout of the pyroclastic flows. In proximal locations, on the caldera rim, heterogeneous exposures including discontinuous lithic breccias, stratified and cross-stratified units interbedded with massive ignimbrite suggest deposition from turbulent flows. In medial locations thick, massive ignimbrite occurs associated with three types of co-ignimbrite lithic breccia which we interpret as being emplaced by non-turbulent flows. Multiple grading of different breccia/lithic concentration types within single flow units indicates that internal shear occurred producing overriding or overlapping of the rear of the flow onto the slower-moving front part. This overriding of different parts of non-turbulent pyroclastic flows could be caused by at least two different mechanisms: (1) changes in flow regime, such as hydraulic jumps that may occur at breaks in slope; and (2) periods of increased discharge rate, possibly associated with caldera collapse, producing fresh pulses of lithic-rich material that sheared onto the slower-moving part of the flow in front.We propose that ground surge deposits enriched in pumice compared with their associated ignimbrite probably formed by a flow separation mechanism from the top and front of the pyroclastic flow. These turbulent clouds moved ahead of the non-turbulent lower part of the flow to form stratified pumice-rich deposits. In distal regions well-developed coarse, often clast-supported, pumice concentrations zones and coarse intra-flow-unit lithic concentrations occur within the massive ignimbrite. We suggest that the flows were non-turbulent, possessed a relatively high yield strength and may have moved by plug flow prior to emplacement.     

Automatic equipment to monitor groundwater radon

Prototype instrumentation, able to automatically measure groundwater radon content variations, is presented. The equipment is made of stainless steel and has spherical valves with automatic and pneumatic control. The deemanation of the gases from the water is obtained by evacuating a suitable expansion chamber. The instrumentation can make discrete sampling ranging from 1 per hour to 1 per 99 hours. The equipment was tested in the laboratory: the efficiency was measured by means of a²⁶⁶Ra solution. A mean value of (0.65±0.07) count/s/Bq was obtained. A calibration test was carried out by comparing countings from the automatic equipment with those obtained by the standard laboratory cell. Results of an operational check over a period of approximately one year indicate that variations in radon at the calibration site are attributable more to meteorological than to tectonic causes.     

Alkaline and ultramafic carbonate lamprophyres in Central Bohemian carboniferous basins,Czech Republic

Summary Dykes of alkaline and ultramafic carbonate lamprophyres (monchiquite-ouachitite and aillikite) intrude the Carboniferous sediments of Central Bohemia. Their characteristic feature is the presence of substantial amounts of a sodalite group mineral (presumably haüyne), carbonate and barite. Isotopic compositions of ¹³C (–3.4 to –6.2) and ¹⁸O ( + 13.5 to + 15.9) indicate that the carbonate is of primary magmatic origin and that fluids were formed at temperatures of 500 to 350°C. High contents of CO₂ (3.6 to 17.6 wt.%) and incompatible elements, high LREE/HREE ratios (30.0 to 57.7), and low Rb/Sr (0.025 to 0.078) and⁸⁷Sr/⁸⁶Sr (0.7038 to 0.7042) ratios suggest the ultramafic lamprophyres are related to deep-seated carbonated magmas of mantle origin. Low degree of partial melting ( < 1%) of the mantle peridotite is envisaged, with additional transport of fluids rich in incompatible elements into the crustal chamber. Alkaline lamprophyres are fractionated derivatives which originated from the same source. Magma intrusion from different levels of a magma chamber into fracture zones under horizontal tension without a central intrusion could result in variability in lamprophyre composition (cumulates or evolved derivatives).

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Alkalische und ultramafische Karbonat-Lamprophyre der zentralen böhmischen Karbonbecken, Tschische Republik

Zusammenfassung Alkalische und ultramafische Karbonat-Lamprophyrgänge (Monchiquit-Ouachitit und Aillikit) intrudieren in karbonische Sedimente Zentralböhmens. Sie sind charakterisiert durch das Auftreten von beträchtlichen Mengen an Mineralen der Sodalith-Gruppe (v.a. Haüyn), Karbonaten und Baryt. Ihre Isotopenzusammensetzung von ¹³C (–3.4 bis –6.2) und ¹⁸O (13.5 bis 15.9) zeigt, daß die Karbonate primär magmatischen Ursprungs sind und daß assoziierte Fluide in einem Temperaturbereich von 350 bis 500°C gebildet wurden. Hohe Gehalte an CO₂ (3.6 bis 17.6 Gew. %), inkompatiblen Elementen, hohe LREE/HREE-Verhältnisse (30.0 bis 57.7), sowie niedrige Rb/Sr—(0.025 bis 0.078) und⁸⁷Sr/⁸⁶Sr-(0.7038 bis 0.7042) Verhältnisse lassen vermuten, daß die ultramafischen Lamprophyre mit karbonatischen Magmen des Mantels in Beziehung stehen. Eine niedrige Aufschmelzungsrate ( < 1%) von Mantelperidotit mit zusätzlichem Transport von, an inkompatiblen Elementen angereicherten Fluiden, in die krustale Magmenkammer wird diskutiert. Alkalische Lamprophyre sind als stärker fraktionierte Magmen, die derselben Quelle entstammen, zu verstehen. Die Intrusion der aus verschiedenen Bereichen der Magmenkammer stammenden Magmen in durch horizontale Dehnung verursachte Störungszonen könnte das Fehlen eines zentralen Intrusionskörpers und die unterschiedliche Zusammensetzung der Lamprophyre (Kumulate oder entwickelte Derivate) erklären.

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With 8 Figures     

Cesstibtantite—a geologic introduction to the inverse pyrochlores

Summary The crystal structure of cesstibtantite has been solved from diffractometer data collected on samples from Leshaia, Russia and the Tanco pegmatite, Manitoba. Cesstibtantite from the Leshaia pegmatite (type locality) hasa 10.515(2) Å, space groupFd3m, composition Cs_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_O.91(Ta_1.88Nb_0.12)₂(O_5.69[OH, F]_0.31)₆(OH, F)_0.69, Z 8; its structure was refined toR 3.8,wR 4.3% using 96 observed (F > 3[F]) reflections (MoK). Cesstibtantite from the Tanco pegmatite hasa 10.496(1) Å, space groupFd3m, composition (Cs_0.22K_0.01)_0.23(Na_0.45Sb_0.39Pb_0.14· Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78[OH,F]_0.22)₆(OH,F)_0.55,Z 8; its structure was refined toR 3.9w R 3.7% using 104 observed reflections. Cesstibtantite differs from the normal pyrochlores in that it contains significant amounts of very large cations such as Cs. As these cations are too large (^VIII[r] > 1.60 Å) for the conventional [8]-coordinated A site, they occupy the [18]-coordinated site, which normally contains monovalent anions. Natural cesstibtantite samples are non-ideal in that both Cs and monovalent anions occur at the site; thus cesstibtantite is intermediate to thenormal pyrochlores (with only monovalent anions at the site) and theinverse pyrochlores (with only large cations at the site).

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Cesstibtantit—eine geologische Einfiihrung in die inversen Pyrochlore

Zusammenfassung Die Kristallstruktur von Cesstibtantit wurde auf der Basis von Diffraktometerdaten von Proben von Leshaia, Russland and dem Tanco Pegmatit, Manitoba, gelöst. Cesstibtantit aus dem Leshaia Pegmatit (Typlokalität) hat a 10.515(2) Å, RaumgruppeFd3m, die Zusammensetzung CS_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_0.91(Ta_1.88Nb_0.12)₂· (O_5.69OH, F_0.31)₆(OH, F)_0.69 Z 8; die Struktur wurde aufR 3.8,wR 4.3% verfeinert unter Benützung von 96 beobachteten Reflexen. Cesstibtantit vom Tanco Pegmatit hat a 10.496(1) Å, RaumgruppeFd3m, die Zusammensetzung (Cs_0.22K_0.01)_0.23(Na_0.45· Sb_0.39Pb_0.14Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78OH,F_0.22)₆(OH,F)_0.55,Z 8; seine Struktur wurde aufR 3.9wR 3.7% auf der Basis von 104 beobachteten Rettexen verfeinert. Cesstibtantit unterscheidet sich von normalen Pyrochloren insofern, als er signifikante Mengen von sehr großen Kationen, wie z.B. Cs enthält. Da these Kationen zu groß sind (^VIII r 1.60 Å) für eine konventionelle [8]-koordinierteA Stelle, nehmen she die [18]-koordinierten Positionen ein, welche normalerweise monovalente Anionen enthalten. Natürliche Cesstibtantitproben sind nicht ideal insofern als sowohl Cs als auch monovalente Anionen in der Position vorkommen. Somit ist Cesstibtantit intermediär zu den normalen Pyrochloren (mit nur monovalenten Anionen auf der Position) and den inversen Pyrochloren (mit ausschließlichen großen Kationen an der Position).