Studies on the determination of inorganic iodine in seawater

Existing methods for the determination of the various forms of iodine present in seawater are laborious or unwieldy in use. This paper describes modified forms of the iodate and total iodine methods described by Barkley and Thompson (1960), a spectrophotometric procedure for iodate determination derived from Johannesson's (1958) work, and an automatic method for total iodine determination. Procedures for iodate and total-iodine determination which are suitable for use aboard ship, are recommended. Both procedures for iodate determination returned a standard deviation close to 0.5 μg/l when several replicate samples of a seawater containing approximately 30 μg/l of iodate-iodine were analysed. The automatic method for total iodine determination yielded a standard deviation of 0.8 μg/l by the repeated analysis of a seawater containing a total of approximately 50 μg/l of iodine. Suitable methods for the filtration and storage of seawater are also described.     

Plate boundaries and evolution of the Solomon Sea region

The Solomon Sea Plate was widely developed during late Oligocene, separating the proto-West Melanesian Arc from the proto-Trobriand Arc. Spreading in the Bismarck Sea and in the Woodlark Basin resulted from interaction between the Pacific and Australian Plates, specifically from the collision of the proto-West Melanesian Arc with north New Guinea, which occurred after arc reversal. This model explains the extensive Miocene, Pliocene, and Quaternary volcanism of the Papua New Guinea mainland as it related to southward subduction of the Trobriand Trough. Our interpreted plate motions are concordant with the geological evidence onshore and also with complex tectonic features in the Solomon Sea Basin Region.     

Benthic Metabolism and Standing Stock in the Central and Northern Deep Red Sea

Abstract. Benthic metabolism and standing stocks were investigated in the deep Red Sea between 21^o and 27^oN, Activity was assessed by the determination of respiration rates with a shipboard method and by calculating oxygen consumption from the activity in the electron transport system. We attempted to compare results from different latitudes within the warm Red Sea and with data from cold Atlantic environments. Our investigations were part of an environmental risk assessment to evaluate future mining of metalliferous sediments from the Atlantis II Deep.     

The Reproductive Cycle of Ophioderma brevispinum (Echinodermata: Ophiuroidea)

Abstract. .The reproductive cycle of the brittlestar Ophioderma brevispinum is described using histological and organ index data for a population in Massachusetts, U.S.A. The cycle consists of a one month mid-summer spawning phase followed by gametogenesis and gradual gonadal growth during the winter, and greatly accelerated gonadal growth from May to June. At the end of the spawning season, oogonia proliferate near the base of the ovary, and a continuous layer of spermatogonia lines the testis. As oocytes grow to a maximum diameter of 350 um, yolk granules accumulate and the cytoplasm becomes less basophilic. Prior to spawning, the testis becomes branched and sulcate, and a whorl of spermatozoa produced by columns of spermatids accumulates in the lumen. Comparisons between the reproductive cycles of different populations of O. brevispinum and its congeners support the hypothesis that temperature may be a critical exogenous factor, but definitely not the only factor, in the initiation and duration of the growth and spawning phases of the ophiuroid reproductive cycle.     

Kinetic studies of the rate of dissolution of silica and diatom tests in sea water

Kinetic studies have been carried out on the dissolution of 10μm beads of silica and of the siliceous tests of two species of diatoms (Thalassiosira fluviatus andSkeletonema costatum) in sea water at 10–50°C and over the pH range 6–9. At all temperatures dissolution of the biogenous silica occurred most rapidly at pH 8 and most slowly at pH 6. First order kinetics were closely followed when the silica was present in a considerable excess over that required for saturation, the rate being proportional to the area of the silica. Apparent deviation from this type of kinetics occurred when there was insufficient silica to bring about saturation. This was undoubtedly due to the progressive decrease in the surface area which takes place as the particle dissolves. Application of the rather simplistic model developed by Kamataniet al. (1980), which makes allowance for this decrease, gave a close correspondence with the data until ∼ 90% of the silica had dissolved.     

Optimum design of a servo-controlled breathing regulator for underwater divers

This article deals with the analysis, synthesis and performance evaluation of the flow and dynamic characteristics of the new class of servo-controlled breathing regulators for underwater divers.Emphasis on such a class of regulators has been stimulated by their tremendous potential in extending the dive depth and duration because they reduce the diver breathing effort to a great extent. This would eliminate the unnecessary exhaustion of the diver under such extreme diving conditions and accordingly improve his work efficiency underwater.The study aims at developing rational design procedures and guides that would enable the regulator designers to select the optimal design parameters of this class of regulators. Such design guides are based on the analysis of the flow and dynamic characteristics of the servo-controlled regulator as well as the basic principle of the theory of optimum control.The study presents also experimental evaluation techniques of the dynamic characteristics of this class of regulators in order to provide common quantitative means for comparison with the conventional regulator designs.The presented results emphasize the merits and the potential of the servo-controlled regulators as essential tools of supporting the life of divers underwater.     

Petroleum hydrocarbons in sediments of Southampton water estuary

The sediments of Southampton Water were analysed for petroleum hydrocarbons to determine the fate of petrochemical refinery waste in the estuary. Much of the petroleum hydrocarbons appears to be removed by adsorption onto estuarine sediments close to source. Surface sediment concentrations range from 3·1mg/g dry weight near a refinery to 0·5 mg/g dry weight at locations distant from the refinery.The absence of any change with depth in total hydrocarbon concentrations from some sediment cores and the presence of distinct ‘oil’ horizons in others suggests that mixing of sediments in the area is very random. Sedimentation rates in areas where a distinct oil horizon was observed ranged from 1 to 3cm a year.     

Optimization of an ocean thermal energy conversion system

The optimum performance of a simple Rankine cycle ocean thermal energy conversion plant is investigated analytically. It is shown that the ratio of maximum net power output to heat exchanger surface area varies as H(Δt − t₀)² where H describes the overall heat transfer properties of the evaporator and condenser, Δt is the temperature difference between the warm and cold sea water supplies, and t₀ is a parameter depending primarily upon the pressure drops across the warm and cold sea water pumping systems. The model is relatively insensitive to the choice of working fluid, although ammonia is used as the illustrative example.