Studies on the determination of inorganic iodine in seawater

Existing methods for the determination of the various forms of iodine present in seawater are laborious or unwieldy in use. This paper describes modified forms of the iodate and total iodine methods described by Barkley and Thompson (1960), a spectrophotometric procedure for iodate determination derived from Johannesson's (1958) work, and an automatic method for total iodine determination. Procedures for iodate and total-iodine determination which are suitable for use aboard ship, are recommended. Both procedures for iodate determination returned a standard deviation close to 0.5 μg/l when several replicate samples of a seawater containing approximately 30 μg/l of iodate-iodine were analysed. The automatic method for total iodine determination yielded a standard deviation of 0.8 μg/l by the repeated analysis of a seawater containing a total of approximately 50 μg/l of iodine. Suitable methods for the filtration and storage of seawater are also described.     

The Reproductive Cycle of Ophioderma brevispinum (Echinodermata: Ophiuroidea)

Abstract. .The reproductive cycle of the brittlestar Ophioderma brevispinum is described using histological and organ index data for a population in Massachusetts, U.S.A. The cycle consists of a one month mid-summer spawning phase followed by gametogenesis and gradual gonadal growth during the winter, and greatly accelerated gonadal growth from May to June. At the end of the spawning season, oogonia proliferate near the base of the ovary, and a continuous layer of spermatogonia lines the testis. As oocytes grow to a maximum diameter of 350 um, yolk granules accumulate and the cytoplasm becomes less basophilic. Prior to spawning, the testis becomes branched and sulcate, and a whorl of spermatozoa produced by columns of spermatids accumulates in the lumen. Comparisons between the reproductive cycles of different populations of O. brevispinum and its congeners support the hypothesis that temperature may be a critical exogenous factor, but definitely not the only factor, in the initiation and duration of the growth and spawning phases of the ophiuroid reproductive cycle.     

Kinetic studies of the rate of dissolution of silica and diatom tests in sea water

Kinetic studies have been carried out on the dissolution of 10μm beads of silica and of the siliceous tests of two species of diatoms (Thalassiosira fluviatus andSkeletonema costatum) in sea water at 10–50°C and over the pH range 6–9. At all temperatures dissolution of the biogenous silica occurred most rapidly at pH 8 and most slowly at pH 6. First order kinetics were closely followed when the silica was present in a considerable excess over that required for saturation, the rate being proportional to the area of the silica. Apparent deviation from this type of kinetics occurred when there was insufficient silica to bring about saturation. This was undoubtedly due to the progressive decrease in the surface area which takes place as the particle dissolves. Application of the rather simplistic model developed by Kamataniet al. (1980), which makes allowance for this decrease, gave a close correspondence with the data until ∼ 90% of the silica had dissolved.     

Gravity anomalies over inactive fracture zones in the central North Atlantic

The basement topography and the free-air gravity along two profiles in the central North Atlantic between 16° and 25° N, crossing a number of fracture zones, were divided in three wavelength intervals. Two-dimensional modelling shows that the short wavelength (>50 km) gravity is well explained by uncompensated topography (mainly spreading topography). For the long wavelengths (>200 km) there is no correlation of topography and gravity. In principle this topography is compensated. Residual anomalies comprise the Ridge effect as well as regional anomalies related to depth anomalies. The 50 to 200km band-pass filtered topography and gravity contain relevant information on fracture zones. Models require a base of the crust that parallels the topography rather than a form of regional compensation. For an explanation of this crustal model that has the appearance of frozen in normal faults we have to consider the typical morphology as created in the transform domain. The geophysical processes that cause this morphology are still an object of study.     

A locking-compass for in situ sample orientation

A mechanically-actuated locking-compass was designed for mounting on corers to record equipment orientation during the sampling process, thereby providing magnetic orientation data on the recovered deep-sea core. Locking occurs upon impact by the corer with the sea-floor; after retrieval, the device is easily unlocked and reset for another station. Compass construction makes use of commercially available parts, requires no welding and little machining, and thus allows inexpensive and easy assembly at sea.     

Ocean bottom refraction seismograph (OBRS)

This paper describes a pop-up ocean bottom seismograph designed primarily for refraction surveys both on the continental shelf and in deep sea. Its development is the extension of our system based on seismic detectors located on the sea floor with radio transmission of seismic signals and used for seismic refraction studies on the continental shelf. The seismic detectors (vertical geophone or hydrophone and two orthogonally mounted horizontal geophones) are located outside of the pressure vessel on the main frame. Optionally, the seismic sensors may be decoupled from the main frame assembly. This decoupling is performed by a mobile arm positioning the separate three component sensor package on the sea floor.Contribution No. 455 of the Département Scientifique, Centre Océanologique de Bretagne.     

Improved in situ gamma-ray transmission densitometer for marine sediments

The first-generation University of Illinois gamma-ray transmission densitometer, designed for the in situ measurement of sediment bulk density, was modified by incorporating in the detector probe (1) an Americium-241 alpha particle pulser and an anti-walk gain stabilization control to maintain better temperature stability and (2) a small power supply and a IC preamplifier to eliminate the need for a high-voltage coaxial cable between the detector and external signal conditioning electronics package. This second-generation Lehigh University system has been successfully deployed since 1971 in routine use from ships and submersibles in the Atlantic and Pacific Oceans and the Gulf of Mexico. Results are presented of system operations to (1) measure bulk density over the range of 1.2–1.8 Mg/m³ in the Hudson Canyon, (2) penetrate 1.9 m into the seafloor in the San Diego trough and, (3) be lowered to a water depth of 3.6 km in the Gulf of Mexico.     

Paleomagnetic events in the brunhes and Matuyama epochs identified from magnetic profiles reduced to the pole

Eleven oceanic magnetic profiles associated with the paleomagnetic time scale younger than the beginning of the Matuyama epoch (2.43 my) have been reduced to the pole, altered to conform to a 3 cm yr^-1 spreading rate, and then all halves added and averaged to obtain a representative symmetric magnetic profile. This final stacked profile emphasizes the subtle anomalies associated with minor paleomagnetic events and minimizes randomly occurring anomalies. The axial anomaly of the stacked profile shows no evidence of the Laschamp event (centered at 0.025 my); however, a minimum at 0.15 my may correspond to the Blake event. A physical model of the stacked magnetic profile consists of a thin, highly magnetized layer with a 40% magnetization decrease at 10 km from the profile center. Magnetization values were modified from Irving and Talwani and the Blake event included. The stacked profile shows two minor anomalies centered at 1.97 my and 2.17 my. The younger anomaly corresponds with the younger Olduvai event (centered at 1.965 my) on the Cox time scale and the W anomaly (centered at 1.99 my) of Emilia and Heinrichs. The older anomaly lies between the older Olduvai event (2.12 my) of Cox and the X anomaly of Heirtzler, and Emilia and Heinrichs; additional work is required to assess the significance of this older event.This material was presented at the Fall Annual Meeting of the American Geophysical Union, December 8, 1971.     

Kirsch problem and the lower natural frequencies of a clamped square-plate

A clamped square-plate is subjected to a uniform state of stress in the x-direction. The present study deals with the basic question of determining the variation of the lower natural frequencies of transverse vibration of a plate as a small diameter, central hole is made in it, introducing a stress concentration field.