Mineralogy and geochemistry of El Dorado epithermal gold deposit, El Sauce district, central-northern Chile

Summary The El Dorado Au-Cu deposit is located in an extensive intra-caldera zone of hydrothermal alteration affecting Upper Cretaceous andesites of the Los Elquinos Formation at La Serena (≈ 29°47′S Lat., 70°43′W Long., Chile). Quartz-sulfide veins of economic potential are hosted by N25W and N20E fault structures associated with quartz-illite alteration (+supergene kaolinite). The main ore minerals in the deposit are pyrite, chalcopyrite ± fahlore (As/(As + Sb): 0.06−0.98), with electrum, sphalerite, galena, bournonite-seligmanite (As/(As + Sb): 0.21−0.31), marcasite, pyrrhotite being accessory phases. Electrum, with an Ag content between 32 and 37 at.%, occurs interstitial to pyrite aggregates or along pyrite fractures. Pyrite commonly exhibits chemical zonation with some zones up to 1.96 at.% As. Electron probe microanalyses of pyrite indicate that As-rich zones do not exhibit detectable Au values. Fluid inclusion microthermometry shows homogenization temperatures between 130 and 352 °C and salinities between 1.6 and 6.9 wt.% NaCl eq. Isotope data for quartz, ankerite and phyllosilicates and estimated temperatures show that δ¹⁸O and δD for the hydrothermal fluids were between 3 and 10‰ and between −95 and −75‰, respectively. These results suggest the mineralizing fluids were a mixture of meteoric and magmatic waters. An epithermal intermediate-sulfidation model is proposed for the formation of the El Dorado deposit. Author’s present address: J. Carrillo-Rosúa, Dpto. de Didáctica de las Ciencias Experimentales, Universidad de Granada, Campus de Cartuja, 18071, Granada, Spain     

Mineralogy and geochemistry of platinum-group elements in the Aguablanca Ni-Cu deposit (SW Spain)

Summary The Aguablanca Ni-Cu-(PGE) magmatic sulphide deposit is associated with a magmatic breccia located in the northern part of the Aguablanca gabbro (SW, Iberia). Three types of ores are present: semi-massive, disseminated, and chalcopyrite-rich veined ore. The principal ore minerals are pyrrhotite, pentlandite and chalcopyrite. A relatively abundant platinum-group mineral (PGM) assemblage is present and includes merenskyite, melonite, michenerite, moncheite and sperrylite. Moreover, concentrations of base and precious metals and micro-PIXE analyses were obtained for the three ore-types. The mineralogy and the mantle-normalised chalcophile element profiles strongly suggest that semi-massive ore represents mss crystallisation, whereas the disseminated ore represents an unfractionated sulphide liquid and the chalcopyrite-rich veined ore a Cu-rich sulphide liquid. Palladium-bearing minerals occur commonly enclosed within sulphides, indicating a magmatic origin rather than hydrothermal. The occurrences and the composition of these minerals suggest that Pd was initially dissolved in the sulphides and subsequently exsolved at low temperatures to form bismutotellurides. Negative Pt and Au anomalies in the mantle-normalised chalcophile element profiles, a lack of Cu-S correlation and textural observations (such as sperrylite losing its euhedral shape when in contact with altered minerals) suggest partial remobilisation of Pt, Au and Cu by postmagmatic hydrothermal fluids after the sulphide crystallisation. Authors’ addresses: R. Pi?a, L. Ortega, R. Lunar, Departamento de Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense de Madrid, ES-28040 Madrid, Spain; F. Gervilla, Facultad de Ciencias, Instituto Andaluz de Ciencias de la Tierra, Universidad de Granada-CSIC, Avda. Fuentenueva, s/n, ES-18002 Granada, Spain     

Methodology of hydrogeological characterization of deep carbonate aquifers as potential reservoirs of groundwater. Case of study: the Jurassic aquifer of <Emphasis Type="Italic">El Maestrazgo</Emphasis> (Castellón,Spain)

A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (¹⁸O, ²H and ³H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.     

High‐pressure metamorphism in Taiwan: from oceanic subduction to arc‐continent collision?

Abstract The Taiwan orogen has been the focus of a number of models of mountain building processes, but little attention has been paid to high‐pressure (HP) metamorphic rocks that are found as exotic blocks intermingled within the deepest units of the mountain belt. In this study, we re‐appraise from updated petrological and thermodynamic databases the physical conditions of HP metamorphism in Taiwan, and we combine our findings with available geochronological data to estimate the thermal history of these rocks. Our results indicate that peak metamorphic conditions of ～550 °C and 10–12 kbar have been followed by a rapid isothermal decompression, with exhumation possibly as rapid as burial. These units have subsequently been stored at a pressure of ～3 kbar for ～4–5 Myr, before their final exhumation, probably facilitated by the accretion of passive margin sequences during the Late Cenozoic collision. Therefore, HP units in Taiwan maintain a record of processes at depth from the early stages of oceanic subduction to the present arc‐continent collision.     

Spatial Variability of Rock Depth in Bangalore Using Geostatistical, Neural Network and Support Vector Machine Models

Geospatial technology is increasing in demand for many applications in geosciences. Spatial variability of the bed/hard rock is vital for many applications in geotechnical and earthquake engineering problems such as design of deep foundations, site amplification, ground response studies, liquefaction, microzonation etc. In this paper, reduced level of rock at Bangalore, India is arrived from the 652 boreholes data in the area covering 220 km². In the context of prediction of reduced level of rock in the subsurface of Bangalore and to study the spatial variability of the rock depth, Geostatistical model based on Ordinary Kriging technique, Artificial Neural Network (ANN) and Support Vector Machine (SVM) models have been developed. In Ordinary Kriging, the knowledge of the semi-variogram of the reduced level of rock from 652 points in Bangalore is used to predict the reduced level of rock at any point in the subsurface of the Bangalore, where field measurements are not available. A new type of cross-validation analysis developed proves the robustness of the Ordinary Kriging model. ANN model based on multi layer perceptrons (MLPs) that are trained with Levenberg–Marquardt backpropagation algorithm has been adopted to train the model with 90% of the data available. The SVM is a novel type of learning machine based on statistical learning theory, uses regression technique by introducing loss function has been used to predict the reduced level of rock from a large set of data. In this study, a comparative study of three numerical models to predict reduced level of rock has been presented and discussed.     

饱和粉砂不稳定性的试验研究

通过对净砂和级配良好粉砂(含10 %粉土)进行一系列三轴固结不排水试验（CU）,研究了粉土、孔隙比和围压对饱和粉砂不稳定性的影响。试验结果表明,净砂与粉砂在不排水剪切条件下均会出现应变软化现象（即不稳定性）。同一围压下脆性指数(IB)随孔隙比增加,但不稳定线的应力比随孔隙比增加而减小。引用等效粒间孔隙比(ege)后,净砂和粉砂在ege-ln p?平面上拥有基本相同的临界状态线。在临界状态理论及等效粒间孔隙比的基础上,提出在同一修正状态参数(?ge)下净砂和级配良好粉砂有相似的不稳定性。     

SOME EXPERIMENTS CONCERNING THE PRIMARY SEISMIC PULSE*

Recordings were made with three types of detector of the primary compressional (P) and shear (S) wave pulses generated by explosions in boreholes. Charge weights varied from 0.08 kg to 9.5 kg and detector distances varied from about 3 m to about 80 m. Scaling by the simple factor W^1/3 where W is the charge weight, enabled observations from different sized charges to be fitted to a single expression. Experiments were carried out in the Bunter sandstone and the London clay and both fluid and solid tamping were used. This variation in tamping had no significant effect on the P-waves but it may have affected the generation of SV-waves. In both media the P-wave energy carried at 30 m from the shot by frequencies less than 100 Hz decreased rapidly with depth and was usually 1–2 % of the available chemical energy for a shot depth of 15 m. The S-wave energy was much less than this, but was highly directional. The P-wave pulse had the appearance of a damped sinusoid in very good agreement with the predictions of the ‘equivalent radiator’ hypothesis. However, the surface of this radiator should be identified not with the blown cavity but with the surface at which the tensile stresses associated with the stress wave become less than the tensile strength of the rock. The predominant frequency for a 1 kg charge at a depth of 15 m was 24 Hz in the clay and 52 Hz in the sandstone. In these and similar media, therefore, an effort should be made to keep individual charges less than 1 kg in reflection shooting and less than 10 kg in refraction shooting. The value of Q was about 50 in clay and about 25 in the sandstone. These estimates are rather uncertain because of the small distances over which the pulses were observed. The Z-transforms of the sampled pulses indicated that they were all of minimum phase, or very near to it.     

THE ELECTRICAL CURRENT PATTERN INDUCED BY AN OSCILLATING MAGNETIC DIPOLE IN A SEMI INFINITE CONDUCTIVE THIN PLATE*

In a paper by Koefoed and Kegge (1968), which was based on previous work of Wesley (1958), the electrical current pattern has been derived that is induced by an oscillating magnetic dipole in a semi-infinite thin plate of infinitesimal resistivity. In the present paper, the range of validity of the assumptions, on which the work of Wesley is based, is subjected to a theoretical analysis. It is found that the decisive factor for the validity of Wesley's derivation is the quotient of the square of the penetration depth of the electrical current over the product of the thickness of the plate and a distance that is indicative of the size of the current loops in the plate. Wesley's derivation is shown to be valid only when this factor is negligible. It is also shown that in this condition the imaginary component of the anomaly must be negligible. Model experiments are described in which the electrical current pattern is studied also in the range in which the derivation of Wesley is not valid. The procedure used in these model experiments was to measure the tangential component of the magnetic field strength very close to the metal plate that simulated the conductive dyke. In order to express the results of the measurements in terms of the imaginary to real ratio, these results are compared with an interpretation graph for field measurements that was published by Hedström and Parasnis (1958). It is found that the current pattern in the plate is essentially the same as that which follows from Wesley's derivation, provided that the imaginary to real ratio is less than one third. The measurements do not permit to draw conclusions regarding the current pattern in the plate in conditions that correspond to larger values of the imaginary to real ratio.