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391.
J.A. Saunders M.-K. Lee M. Shamsudduha P. Dhakal A. Uddin M.T. Chowdury K.M. Ahmed 《Applied Geochemistry》2008
Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO4 to stimulate metabolism of indigenous SO4-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO4, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO4 reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS2. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO4 reduction commenced but increased to pre-experiment level once SO4 reduction ended. In the ongoing experiment, both SO4 and Fe(II) were amended to groundwater to evaluate if FeS/FeS2 formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions. 相似文献
392.
393.
David P. Bacon Nash’at N. Ahmad Thomas J. Dunn Michael C. Monteith Ananthakrishna Sarma 《Natural Hazards》2008,44(3):317-327
By definition, a crisis is a situation that requires assistance to be managed. Hence, response to a crisis involves the merging
of local and non-local emergency response personnel. In this situation, it is critical that each participant: (1) know the
roles and responsibilities of each of the other participants; (2) know the capabilities of each of the participants; and (3)
have a common basis for action. For many types of natural disasters, this entails having a common operational picture of the unfolding events, including detailed information on the weather, both current and forecasted, that may impact on either
the emergency itself or on response activities. The Consequences Assessment Tool Set (CATS) is a comprehensive package of
hazard prediction models and casualty and damage assessment tools that provides a linkage between a modeled or observed effect
and the attendant consequences for populations, infrastructure, and resources, and, hence, provides the common operational
picture for emergency response. The Operational Multiscale Environment model with Grid Adaptivity (OMEGA) is an atmospheric
simulation system that links the latest methods in computational fluid dynamics and high-resolution gridding technologies
with numerical weather prediction to provide specific weather analysis and forecast capability that can be merged into the
geographic information system framework of CATS. This paper documents the problem of emergency response as an end-to-end system
and presents the integrated CATS–OMEGA system as a prototype of such a system that has been used successfully in a number
of different situations. 相似文献
394.
Gregory P. Marchildon Suren Kulshreshtha Elaine Wheaton Dave Sauchyn 《Natural Hazards》2008,45(3):391-411
Agriculture in the southern Great Plains of Canada has been particularly vulnerable to prolonged episodes of drought. Using
climate data and a precipitation minus potential evapotranspiration index, the extent of the region’s exposure to drought
is examined. Between 1914 and 1917, the Dry Belt was particularly vulnerable to drought, whereas after 1928, a much larger
region known as the Palliser Triangle covering most of southern Alberta and Saskatchewan was much more exposed to drought.
These droughts provoked major institutional adaptation, in particular the establishment of the Special Areas Board by the
Government of Alberta, and the creation of the Prairie Farm Rehabilitation Administration by the Government of Canada. Both
organizations have proved to be relatively permanent public adaptations to the natural hazard of drought in the region. Moreover,
these earlier experiences with prolonged drought as well as institution-building may be of value in helping the residents
of the Palliser Triangle adapt to predicted climate changes in the future as well as anticipate some of the barriers to effective
institutional adaptation. 相似文献
395.
Gravitational spreading of mountain ridges displays primary disequilibrium of flysch mountain areas of the Czech Carpathians.
The progression of various types of mass movements is a product of long-term ridge disintegration and is predisposed by the
geological structure of the area and the upper Tertiary-Quaternary morphogenesis of the mountain area. Deep-seated slope deformations
are spatially interconnected by the occurrence of some other types of slope deformations (e.g. debris flows, debris slides,
slumps, rock avalanches, etc.), which pose a considerable risk for the existence of human society. An important causative
factor in these dynamically developing hazardous processes is, among other factors, the way in which land has been used in
the last three centuries. Therefore, the occurrence of various types of slope deformations is studied in terms of their relation
to deep-seated gravitational deformations and in terms of other limiting factors (structural geological, morphological and
climatic factors, manmade impacts, etc.). The paper presents several case studies of slope deformations (Velká Čantoryje Mt,
Lysá hora Mt, Ropice Mt and Smrk Mt) in the area of the Outer Carpathians within the territory of the Czech Republic and also
adverts to some consequences in terms of the socioeconomic structure of the landscape. 相似文献
396.
A.M.D. van Rotterdam-Los S.P. Vriend M.J. van Bergen P.F.M. van Gaans 《Journal of Geochemical Exploration》2008,96(1):53-68
Acid water from the Banyuputih river (pH 3.5) is used for the irrigation of agricultural land in the Asembagus coastal area (East Java, Indonesia), with harmful consequences for rice yields. The river water has an unusual composition which is caused by seepage from the acidic Kawah Ijen crater lake into the river. This unique irrigation setting allows the study of soil acidification in situ. This paper assesses the effects of volcanogenically contaminated irrigation water on the chemical properties of the agricultural soils.The changes in soil properties were evaluated by comparing samples taken from the topsoil and sub-soil (1–3 m depth) from areas irrigated with acid water and areas irrigated with neutral water. The field survey thus resulted in four soil categories. Bulk soil composition, organic matter content, moisture content and particle size distribution were determined. Reactive phases were quantified with the selective extractions 1 M KCl, 0.1 M Na-pyrophosphate and 0.2 M acid ammonium oxalate (AAO).By comparing the four soil categories it is shown that the use of the naturally polluted irrigation water has had a large influence on the chemical composition of the topsoil. The composition of the soil solution has changed over the entire investigated soil profile. Furthermore the acid irrigation water has strongly modified the composition of the reactive phases, extracted as KCl, pyrophosphate, and AAO extractable elements, and also the bulk soil composition has been significantly modified. Overall this has resulted in the net dissolution of some elements and the net precipitation of others. The changes in the reactive phases and bulk soil composition are only apparent in the topsoil (0–20 cm) but not in the deeper soil. 相似文献
397.
A.R. Salgueiro P. Freire vila H. Garcia Pereira J.M. Santos Oliveira 《Journal of Geochemical Exploration》2008,98(1-2):15
Based on an environmental geochemistry case study carried out in the neighbourhood of a W–Sn abandoned mine, the pollution in stream sediments was modelled through a Global Contamination Index. Such an index permits one to summarize the combination of deleterious elements in a single variable, obtained by the projection of samples onto the first axis of a PCASD (Principal Components Analysis of Standardized Data) applied to the entire n × p matrix containing the available concentrations of p = 16 elements in the set of n = 220 collected samples.In order to provide a sound basis for a coherent planning of the remediation process which will be put in operation in the affected area, it is necessary to balance the costs of reclaiming with the probabilities of exceeding the upper limits accepted for concentrations of environmentally harmful elements in sediments. Given these limits, they are back-transformed in the index values, providing a practical threshold between ‘clean’ and ‘contaminated’ samples. On the other hand, the minimum dimension of the cell to be reclaimed is restrained by the selected remediation process to be applied in the affected area. Hence, to meet the constraints of such a remediation process, it is required to estimate the probabilities of exceeding the index threshold in technologically meaningful sub-areas. For this end, the Indicator Block Kriging technique was applied, producing a series of maps where sub-areas to be reclaimed can be spotted for different probability levels. These maps, on which the decision making remediation agency can rely for its cost-benefit analysis, take into account both the spatial structure of ‘clean’ vs. ‘contaminated’ samples and the constraints of the reclaiming process. 相似文献
398.
Mineralogy and geochemistry of El Dorado epithermal gold deposit, El Sauce district, central-northern Chile 总被引:1,自引:0,他引:1
J. Carrillo-Rosúa S. Morales-Ruano D. Morata A. J. Boyce M. Belmar A. E. Fallick P. Fenoll Hach-Alí 《Mineralogy and Petrology》2008,92(3-4):341-360
Summary The El Dorado Au-Cu deposit is located in an extensive intra-caldera zone of hydrothermal alteration affecting Upper Cretaceous
andesites of the Los Elquinos Formation at La Serena (≈ 29°47′S Lat., 70°43′W Long., Chile). Quartz-sulfide veins of economic potential are hosted by N25W and N20E
fault structures associated with quartz-illite alteration (+supergene kaolinite). The main ore minerals in the deposit are
pyrite, chalcopyrite ± fahlore (As/(As + Sb): 0.06−0.98), with electrum, sphalerite, galena, bournonite-seligmanite (As/(As
+ Sb): 0.21−0.31), marcasite, pyrrhotite being accessory phases. Electrum, with an Ag content between 32 and 37 at.%, occurs
interstitial to pyrite aggregates or along pyrite fractures. Pyrite commonly exhibits chemical zonation with some zones up
to 1.96 at.% As. Electron probe microanalyses of pyrite indicate that As-rich zones do not exhibit detectable Au values. Fluid
inclusion microthermometry shows homogenization temperatures between 130 and 352 °C and salinities between 1.6 and 6.9 wt.%
NaCl eq. Isotope data for quartz, ankerite and phyllosilicates and estimated temperatures show that δ18O and δD for the hydrothermal fluids were between 3 and 10‰ and between −95 and −75‰, respectively. These results suggest
the mineralizing fluids were a mixture of meteoric and magmatic waters. An epithermal intermediate-sulfidation model is proposed
for the formation of the El Dorado deposit.
Author’s present address: J. Carrillo-Rosúa, Dpto. de Didáctica de las Ciencias Experimentales, Universidad de Granada, Campus de Cartuja, 18071, Granada, Spain 相似文献
399.
M. Mejías J. Garcia-Orellana J. L. Plata M. Marina E. Garcia-Solsona B. Ballesteros P. Masqué J. López C. Fernández-Arrojo 《Environmental Geology》2008,54(3):521-536
A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic
aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a
previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated
combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics
and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural
analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and
groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were
applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium
isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (18O, 2H and 3H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system.
Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics
of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater
uses in the area of study. 相似文献
400.
T. G. Sitharam Pijush Samui P. Anbazhagan 《Geotechnical and Geological Engineering》2008,26(5):503-517
Geospatial technology is increasing in demand for many applications in geosciences. Spatial variability of the bed/hard rock
is vital for many applications in geotechnical and earthquake engineering problems such as design of deep foundations, site
amplification, ground response studies, liquefaction, microzonation etc. In this paper, reduced level of rock at Bangalore,
India is arrived from the 652 boreholes data in the area covering 220 km2. In the context of prediction of reduced level of rock in the subsurface of Bangalore and to study the spatial variability
of the rock depth, Geostatistical model based on Ordinary Kriging technique, Artificial Neural Network (ANN) and Support Vector
Machine (SVM) models have been developed. In Ordinary Kriging, the knowledge of the semi-variogram of the reduced level of
rock from 652 points in Bangalore is used to predict the reduced level of rock at any point in the subsurface of the Bangalore,
where field measurements are not available. A new type of cross-validation analysis developed proves the robustness of the
Ordinary Kriging model. ANN model based on multi layer perceptrons (MLPs) that are trained with Levenberg–Marquardt backpropagation
algorithm has been adopted to train the model with 90% of the data available. The SVM is a novel type of learning machine
based on statistical learning theory, uses regression technique by introducing loss function has been used to predict the
reduced level of rock from a large set of data. In this study, a comparative study of three numerical models to predict reduced
level of rock has been presented and discussed. 相似文献