Bartonian orthophragminids from the Fulra Limestone (Kutch,W India) and coeval units in Sulaiman Range,Pakistan: a synthesis of shallow benthic zone (SBZ) 17 for the Indian Subcontinent

Orthophragminids from the Bartonian Fulra Limestone in Kutch, India and the coeval units in Sulaiman Range in Pakistan suggest the establishment of a significant number of endemic species in the Indian subcontinent (Eastern Tethys). Among a total of fifteen species of Discocyclina, Orbitoclypeus and Asterocyclina, six of them appear to be confined to Indian subcontinent while seven species are common both to the peri-Mediterranean/Europe region (Western Tethys) and Indian subcontinent. Two species, Asterocyclina sireli, a four-ribbed species of possibly Indo-Pacific origin, and Orbitoclypeus haynesi that form large populations in Fulra Limestone, appear to have spread into North Africa and Turkey but not into European platforms as a response to Middle Eocene Climatic Optimum (MECO). The lack of Lutetian and Priabonian fauna in the studied sections, either due to a hiatus or unsuitable depositional environments, hampers the establishment of the actual stratigraphic ranges of the identified taxa. Our record provides us to characterize the orthophragminids in shallow benthic zone (SBZ) 17 for Eastern Tethys in detail by comparing the data from the above localities with those from the North Africa, Europe and Turkey, showing the change in diversity.     

Optical and near-infrared photometric study of NGC 6724

BVRI CCD photometry of the poorly studied open cluster NGC 6724 has been carried out down to a limiting magnitude of V ～20 mag. The stars of the cluster have been observed using the Newtonian focus(f/4.84) of the 74-inch telescope at Kottamia Astronomical Observatory in Egypt.Also, the 2 MASS-JHK system is used to confirm the results we obtained. The main photometric parameters have been estimated for the present object; the diameter is found to be 6 arcmin, the distance is 1530±60 pc from the Sun and the age is 900±50 Myr. The optical reddening E(B-V) = 0.65 mag,while the infrared reddening is E(J-H) = 0.20 mag. The slope of the mass function distribution and the relaxation time estimations indicate that cluster NGC 6724 is dynamically relaxed.     

Geochemistry and Zircon U-Pb Dates of Felsic-Intermediate Members of the Late Cretaceous Yüksekova Arc Basin: Constraints on the Evolution of the Bitlis–Zagros Branch of Neotethys (Elazığ, E Turkey)

During the Late Cretaceous in the Eastern Mediterranean, the northern branch of the southern Neotethys was closed by multiple northward subductions. Of these, the most northerly located subduction created the Baskil continental arc at around 82–84 Ma. The more southerly and intra-oceanic subduction, on the other hand, produced an arc-basin system,the Yüksekova Complex, as early as the late Cenomanian–early Turonian. The abundant and relatively well-studied basaltic rocks of this complex were intruded by dykes, sills and small stocks of felsic–intermediate rocks, not previously studied in detail. The intrusives collected from five different localities in the Elaz?? region of eastern Turkey are all subalkaline, with low Nb/Y values. Most of them have been chemically classified as rhyodacites/dacites, whereas a small number appear to be andesites. In normal mid-ocean-ridge basalt(N-MORB)-normalised plots, the intrusives are characterised by relative enrichments in Th and La over Nb, Zr, Hf, Ti and high field strength elements(HREEs), indicating their derivation from a subduction-modified source. While their relatively high, positive εN d(i) values(+6.4 and +7.2) might suggest a depleted mantle source for their ultimate origin, somewhat radiogenic Pb values indicate a sedimentary contribution to the source of the rocks. The overall geochemical characteristics indicate their generation in an oceanic arc setting. The zircon U-Pb Laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS) data obtained from five felsic-intermediate rock samples yielded intrusion dates of 80–88 Ma. This suggests that the Elaz?? oceanic arc-related intrusives are slightly younger than those of the Yüksekova arc-basin system, but coeval with the Baskil continental arc. However, the felsic–intermediate intrusives show different geochemical characteristics(oceanic arc-type, with a lack of crustal contamination)to those of the Baskil continental arc. This indicates that these two igneous systems are unrelated and likely developed in different tectonic settings. This, in turn, supports a geodynamic model in which the northern strand of the southern Neotethys was consumed by multiple northward subductions.     

Rate of seawater intrusion estimated by geophysical methods in an arid area: Al Khabourah, Oman

Seawater intrusion and its spreading rate are the challenging problems in over-pumped coastal aquifers of arid zones like the Batinah region of Oman. The study delineates the saline plume, identifies saline/freshwater zones, and estimates the migration rate of the plume in the Al Khabourah area of the Batinah coast. Time domain electromagnetic surveys, aided by vertical electrical sounding surveys, and seismic refraction methods have defined the locus of the saline/freshwater interface in the area. The current (2007) interface position, when compared with that determined during 2002, indicates a prominent recession in the saline plume and suggests an average annual recession rate of 120 m. This recession may be attributed mainly to the recharging dam of Wadi Al Hawasinah, constructed in 1995, and the enforcement of new water resources legislation. This study reveals the shielding role of the recharging dam to counter advancing saline intrusion.     

Cyanide from gold mining and its effect on groundwater in arid areas,Yanqul mine of Oman

The use of cyanide (CN), which is characterized by volatility, toxicity and high odor, in gold mining is scarcely addressed in the literature and remain controversial. Environmentalists oppose CN usage as it potentially poses serious environmental threats, whereas economic and mining geologists are in favor of its usage for its extracting capacity and economic feasibility. The present study investigates the possible dispersion of CN into groundwater resources caused by a gold mine (ca. 15 years old) located in the arid area of Yanqul, North Oman. The gold is hosted in gossan deposits associated with ophiolitic rocks and sulfide deposits. Sodium cyanide is mixed with 0.5 m³ of water and then added to a tonne of crushed ore rock to extract 6 g of gold mineral. The final residues are dumped in engineered, lined and uncovered tailing dams. Subsequent to rainfall water draining the mine plateau flows along the wadies and percolates into the shallow Quaternary alluvium aquifer. Hence, groundwater samples were collected from 16 piezometers adjacent to and around the mine. The samples were analyzed for CN using the revised phenolphthalin method and they all show CN concentration below the detection limit (5 ppb). The samples were also analyzed for heavy metals to investigate the potential of CN complexation. Most of heavy metals indicated very trace concentration. The absence of CN in groundwater is attributed to volatilization of CN (converted to HCN), lined dam structure, high evapotranspiration rate and deeper water table. This finding is consistent with the historical CN analysis in the groundwater and solid wastes. It can be pointed out that within few years of operation well engineered tailing dams can provide safe structure preventing CN-groundwater pollution in arid areas. Potential threats to the air and soil are not addressed in this article.     

The Sha’it–Nugrus shear zone separating Central and South Eastern Deserts,Egypt: A post-arc collision low-angle normal ductile shear zone

The northerly dipping Sha’it–Nugrus shear zone (SNSZ) is the boundary separating the Central Eastern Desert from the South Eastern Desert of Egypt. The hangingwall of this shear zone is composed of low-grade metavolcanics and ophiolitic nappes of the Central Eastern Desert, while the footwall consists of South Eastern Desert high-grade metapsammitic gneisses (Migif-Hafafit gneissic complex). The SNSZ is about 700 m thick and represents the shear foliated lower parts of the hangingwall and upper parts of the footwall. A significant part of the SNSZ has been truncated by a later normal fault along Wadi Sha’it, however the SNSZ is well-preserved along Wadi Nugrus. Features of the SNSZ include shear-related schistosity (termed Ss), mylonite zones, sheared syn-kinematic granitoid intrusions, diverse metasomatism and metamorphic effects (higher T overprinting of hangingwall lithologies and retrogression of footwall lithologies). Shear-sense indicators clearly show top-to-N or NW displacement sense. SNSZ structures overprint arc collision related nappe structures (～680 Ma) and are therefore post-arc collision. SNSZ syn-kinematic intrusives have been dated at ～600 Ma. The SNSZ is deformed (regionally and locally folded and thrust dissected) during later NE–SW compressive tectonism. The SNSZ had an originally approximately E–W strike, low-angle N-dip and a normal shear sense, making this an example of a low-angle normal ductile shear (LANF) or detachment fault. The steep NE dip of Ss foliations and low-pitching slip lineations along Wadi Nugrus are due to NW–SE folding of the SNSZ, and do not indicate a sinistral strike-slip shear zone. The normal shear sense activity is responsible for juxtaposing the low-grade Central Eastern Desert lithologies against South Eastern Desert gneisses. A displacement of 15–30 km is estimated on the SNSZ, which is comparable to LANF displacements in the Basin and Range province of the western USA. Frictional resistance along this shear was probably reduced by high magmatic fluid pressure and hydrothermal fluid pressure. The vastness and diversity of the hydrothermal activity along this shear zone is a characteristic of other LANFs in the Eastern Desert, e.g. at Gabal El-Sibai, and may be Gabal Meatiq. The SNSZ formed during the Neoproterozoic extensional tectonic phase of Eastern Desert that began ～600 Ma, and followed arc collision and NW-ward ejection of nappes.     

Purification of diatomite powder by acid leaching for use in fabrication of porous ceramics

This study presents an investigation of the purification of a raw diatomite by acid leaching conducted in hot solution (75 °C and 5 M HCl) for long periods up to 240 h, evaluates the use of these purified powders in the fabrication of porous materials, and examines their porosities. The treatment for 1 h increased the specific surface area of diatomite from 189 m²/g to 222 m²/g, but the SiO₂ content of 78.66% was still low. Material leached for a relatively short time shows an amorphous phase with quartz and plagioclase phases and the plagioclase is removable at longer leaching times during which no disruptive effect on the fine microscopic pores of the particles was observed. Thus, the diatomite based powders have potential use in the fabrication of porous coating as a membrane-separating layer: sintering at a relatively high temperature (1300 °C) still showed a significantly high apparent porosity of 48%.