Distribution of heavy metals in marine bivalves, fish and coastal sediments in the Gulf and Gulf of Oman

An assessment of marine contamination due to heavy metals was made in the Gulf and Gulf of Oman based on marine biota (fish and various bivalves) and coastal sediment collected in Bahrain, Oman, Qatar, and the United Arab Emirates (UAE) during 2000-2001. Sediment metal loadings were generally not remarkable, although hot spots were noted in Bahrain (Cu, Hg, Pb, Zn) and on the east coast of the UAE (As, Co, Cr, Ni). Concentrations of As and Hg were typically low in sediments and the total Hg levels in top predator fish commonly consumed in the region were < 0.5 microg g(-1) and posed no threat to public health. Very high Cd concentrations (up to 195 microg g(-1)) in the liver of some fish from southern Oman may result from food-chain bioaccumulation of elevated Cd levels brought into the productive surface waters by upwelling in the region. Very high As concentrations (up to 156 microg g(-1)) were measured in certain bivalve species from the region. Although not certain, the As is probably derived from natural origins rather than anthropogenic contamination.     

Statistical Tests of Load-Unload Response Ratio Signals by Lattice Solid Model: Implication to Tidal Triggering and Earthquake Prediction

— Statistical tests of Load-Unload Response Ratio (LURR) signals are carried in order to verify statistical robustness of the previous studies using the Lattice Solid Model (Mora et al., 2002b). In each case 24 groups of samples with the same macroscopic parameters (tidal perturbation amplitude A, period T and tectonic loading rate k) but different particle arrangements are employed. Results of uni-axial compression experiments show that before the normalized time of catastrophic failure, the ensemble average LURR value rises significantly, in agreement with the observations of high LURR prior to the large earthquakes. In shearing tests, two parameters are found to control the correlation between earthquake occurrence and tidal stress. One is, A/(k T) controlling the phase shift between the peak seismicity rate and the peak amplitude of the perturbation stress. With an increase of this parameter, the phase shift is found to decrease. Another parameter, A T/k, controls the height of the probability density function (Pdf) of modeled seismicity. As this parameter increases, the Pdf becomes sharper and narrower, indicating a strong triggering. Statistical studies of LURR signals in shearing tests also suggest that except in strong triggering cases, where LURR cannot be calculated due to poor data in unloading cycles, the larger events are more likely to occur in higher LURR periods than the smaller ones, supporting the LURR hypothesis.     

Finite Element Analysis of Fault Bend Influence on Stick-Slip Instability along an Intra-Plate Fault

— Earthquakes have been recognized as resulting from stick-slip frictional instabilities along the faults between deformable rocks. A three-dimensional finite-element code for modeling the nonlinear frictional contact behaviors between deformable bodies with the node-to-point contact element strategy has been developed and applied here to investigate the fault geometry influence on the nucleation and development process of the stick-slip instability along an intra-plate fault through a typical fault bend model, which has a pre-cut fault that is artificially bent by an angle of 5.6° at the fault center. The numerical results demonstrate that the geometry of the fault significantly affects nucleation, termination and restart of the stick-slip instability along the intra-plate fault, and all these instability phenomena can be well simulated using the current finite-element algorithm.     

Spatio-temporal Scanning and Statistical Test of the Accelerating Moment Release (AMR) Model Using Australian Earthquake Data

— The Accelerating Moment Release (AMR) preceding earthquakes with magnitude above 5 in Australia that occurred during the last 20 years was analyzed to test the Critical Point Hypothesis. Twelve earthquakes in the catalog were chosen based on a criterion for the number of nearby events. Results show that seven sequences with numerous events recorded leading up to the main earthquake exhibited accelerating moment release. Two occurred near in time and space to other earthquakes preceded by AMR. The remaining three sequences had very few events in the catalog so the lack of AMR detected in the analysis may be related to catalog incompleteness. Spatio-temporal scanning of AMR parameters shows that 80% of the areas in which AMR occurred experienced large events. In areas of similar background seismicity with no large events, 10 out of 12 cases exhibit no AMR, and two others are false alarms where AMR was observed but no large event followed. The relationship between AMR and Load-Unload Response Ratio (LURR) was studied. Both methods predict similar critical region sizes, however, the critical point time using AMR is slightly earlier than the time of the critical point LURR anomaly.     

A survey of antifoulants in sediments from Ports and Marinas along the French Mediterranean coast

Due to deleterious effects on non-target organisms, the use of organotin compounds on boat hulls of small vessels (<25 m) has been widely prohibited. The International Maritime Organisation (IMO) resolved that the complete prohibition on organotin compounds acting as biocides in antifouling systems should commence in 2008. As a result of restrictions on the use of organotin based paints, other antifouling formulations containing organic biocides have been utilised. This survey was conducted to assess the contamination of replacement biocides in the marine environment following the ban of TBT-based paints. Surface sediments samples were collected in the major ports and marinas along the France Mediterranean coastline (Cote d’Azur) and analysed for organotin compounds, Irgarol 1051, Sea-nine 211^TM, Chlorothalonil, Dichlofluanid and Folpet. Every port and marina exhibited high levels of organotin compounds, with concentrations in sediments ranging from 37 ng Sn g⁻¹dry wt in Menton Garavan to over 4000 ng Sn g⁻¹dry wt close to the ship chandler within the port of Villefranche-sur-Mer. TBT degradation indexes suggested that fresh inputs are still made. Among the other antifoulants monitored, only Irgarol 1051 exhibited measurable concentrations in almost every port, with concentrations ranging from 40 ng g⁻¹dry wt (Cannes) to almost 700 ng g⁻¹dry wt (Villefranche-sur-Mer, ship chandler).     

Spatial assessment of fishing effort around European marine reserves: implications for successful fisheries management

We examined the spatial dynamic of artisanal fishing fleets around five European marine protected areas (MPAs) to derive general implications for the evaluation of MPAs as fisheries management tools. The coastal MPAs studied were located off France, Malta and Spain and presented a variety of spatial designs and processes of establishment. We developed a standardized methodology to define factors influencing effort allocation and to produce fishing effort maps by merging GIS with geostatistical modelling techniques. Results revealed that in most cases the factors “distance to the no-take”, “water depth”, and “distance to the port” had a significant influence on effort allocation by the fishing fleets. Overall, we found local concentration of fishing effort around the MPA borders. Thus, neglecting the pattern of fishing effort distribution in evaluating MPA benefits, such as spillover of biomass, could hamper sound interpretation of MPAs as fisheries management tools.     

Critical response of structures to multicomponent earthquake excitation

This paper aims to develop an improved understanding of the critical response of structures to multicomponent seismic motion characterized by three uncorrelated components that are defined along its principal axes: two horizontal and the vertical component. An explicit formula, convenient for code applications, has been derived to calculate the critical value of structural response to the two principal horizontal components acting along any incident angle with respect to the structural axes, and the vertical component of ground motion. The critical response is defined as the largest value of response for all possible incident angles. The ratio r_cr/r_srss between the critical value of response and the SRSS response—corresponding to the principal components of ground acceleration applied along the structure axes—is shown to depend on three dimensionless parameters: the spectrum intensity ratio γ between the two principal components of horizontal ground motion characterized by design spectra A(T_n) and γA(T_n); the correlation coefficient α of responses r_x and r_y due to design spectrum A(T_n) applied in the x‐ and y‐directions, respectively; and β = r_y/r_x. It is demonstrated that the ratio r_cr/r_srss is bounded by 1 and . Thus the largest value of the ratio is , 1.26, 1.13 and 1.08 for γ = 0, 0.5, 0.75 and 0.85, respectively. This implies that the critical response never exceeds times the result of the SRSS analysis, and this ratio is about 1.13 for typical values of γ, say 0.75. The correlation coefficient α depends on the structural properties but is always bounded between −1 and 1. For a fixed value of γ, the ratio r_cr/r_srss is largest if β = 1 and α = ±1. The parametric variations presented for one‐storey buildings indicate that this condition can be satisfied by axial forces in columns of symmetric‐plan buildings or can be approximated by lateral displacements in resisting elements of unsymmetrical‐plan buildings. Copyright © 2000 John Wiley & Sons, Ltd.     

Reliability-based design of R/C water tank structures under seismic action

Based on a reliability level 2 method, a procedure is proposed to design reinforced concrete structures for elevated tanks subjected to seismic action, with a specified probability of failure in a 50-year design life. To evaluate the probability of failure the ultimate limit state is obtained when the top column displacement demanded by the earthquake, a random variable, reaches the allowable displacement, which is here treated as deterministic. The seismic action is characterized probabilistically by the power spectral density function of the ground acceleration, which is obtained from a design spectrum. The strength and ductility of an annular column section of confined reinforced concrete for cyclic loads are evaluated with design aids. Design charts are made for a given tank capacity and specified seismic zone that allow one to choose different combinations of strength, stiffness and ductility for the same tolerable probability of failure. A step by step method is suggested for the design of the annular column section, choosing finally the most convenient design. The advantage of this methodology is shown through a numerical example.     

Distribution of petroleum hydrocarbons and organochlorinated contaminants in marine biota and coastal sediments from the ROPME Sea Area during 2005

The composition and spatial distribution of various petroleum hydrocarbons (PHs), comprising both aliphatic and polycyclic aromatic hydrocarbons (PAHs), and selected chlorinated pesticides and PCBs were measured in biota and coastal sediments from seven countries in the Persian Gulf and the Gulf of Oman (Bahrain, Iran, Kuwait, Oman, Qatar, Saudi Arabia and the United Arab Emirates). Evidence of extensive marine contamination with respect to organochlorinated compounds and PHs was not observed. Only one site, namely the BAPCO oil refinery in Bahrain, was considered to be chronically contaminated. Comparison of the results from this survey for Σ DDTs and Σ PCBs in rock oysters from the Gulf of Oman with similar measurements made at the same locations over the past two decades indicates a temporal trend of overall decreasing Σ PCB concentrations in oysters, whereas Σ DDTs levels have little changed during that period.     

Estimation of rainfall from infrared‐microwave satellite data for basin‐scale hydrologic modelling

The infrared‐microwave rainfall algorithm (IMRA) was developed for retrieving spatial rainfall from infrared (IR) brightness temperatures (TBs) of satellite sensors to provide supplementary information to the rainfall field, and to decrease the traditional dependency on limited rain gauge data that are point measurements. In IMRA, a SLOPE technique (ST) was developed for discriminating rain/no‐rain pixels through IR image cloud‐top temperature gradient, and 243K as the IR threshold temperature for minimum detectable rainfall rate. IMRA also allows for the adjustment of rainfall derived from IR‐TB using microwave (MW) TBs. In this study, IMRA rainfall estimates were assessed on hourly and daily basis for different spatial scales (4, 12, 20, and 100 km) using NCEP stage IV gauge‐adjusted radar rainfall data, and daily rain gauge data. IMRA was assessed in terms of the accuracy of the rainfall estimates and the basin streamflow simulated by the hydrologic model, Sacramento soil moisture accounting (SAC‐SMA), driven by the rainfall data. The results show that the ST option of IMRA gave accurate satellite rainfall estimates for both light and heavy rainfall systems while the Hessian technique only gave accurate estimates for the convective systems. At daily time step, there was no improvement in IR‐satellite rainfall estimates adjusted with MW TBs. The basin‐scale streamflow simulated by SAC‐SMA driven by satellite rainfall data was marginally better than when SAC‐SMA was driven by rain gauge data, and was similar to the case using radar data, reflecting the potential applications of satellite rainfall in basin‐scale hydrologic modelling. Copyright © 2010 John Wiley & Sons, Ltd.