Crystallization and eruption ages of Breccia Museo (Campi Flegrei caldera,Italy) plutonic clasts and their relation to the Campanian ignimbrite

The Campi Flegrei volcanic district (Naples region, Italy) is a 12-km-wide, restless caldera system that has erupted at least six voluminous ignimbrites during the late Pleistocene, including the >300 km³ Campanian ignimbrite (CI) which originated from the largest known volcanic event of the Mediterranean region. The Breccia Museo (BM), a petrologically heterogeneous and stratigraphically complex volcanic deposit extending over 200 km² in close proximity to Campi Flegrei, has long remained contentious regarding its age and stratigraphic relation to the CI. Here, we present crystallization and eruption ages for BM plutonic ejecta clasts that were determined via uranium decay series and (U–Th)/He dating of zircon, respectively. Despite mineralogical and textural heterogeneity of these syenitic clasts, their U–Th zircon rim crystallization ages are indistinguishable with an average age of 49.7 ± 2.5 ka (2σ errors; mean square of weighted deviates MSWD = 1.2; n = 34). A subset of these crystals was used to obtain disequilibrium-corrected (U–Th)/He zircon ages which average 41.7 ± 1.8 ka (probability of fit P = 0.54; n = 15). This age closely overlaps with published CI ⁴⁰Ar/³⁹Ar eruption ages (40.6 ± 0.1 ka) after recalibration to recently revised flux monitor ages. Concordant eruption ages for BM and CI agree with previous chemostratigraphic and paleomagnetic correlations, suggesting their origin from the same eruption. However, they are at variance with recalibrated ⁴⁰Ar/³⁹Ar ages which have BM postdate CI by 3 ± 1 ka. BM syenites show similar geochemical and Sr–Nd isotopical features of pre-caldera rocks erupted between 58 and 46 ka, but are distinctive from subsequent caldera-forming magmas. Energy-constrained assimilation and fractional crystallization modeling of Nd–Sr isotopic data suggests that pre-caldera magmas formed a carapace of BM-type intrusions in a mid-crust magma chamber (≥8 km depth) shielding the younger CI magma from contamination by Hercynian basement wall rocks. An ~41–50 ka hiatus in crystallization ages implies rapid solidification of these pre-CI intrusions. This argues against protracted pre-eruptive storage of a large volume of CI magma at shallow crustal levels.     

The origin of Himalayan anatexis and inverted metamorphism: Models and constraints

The key to comprehending the tectonic evolution of the Himalaya is to understand the relationships between large-scale faulting, anatexis, and inverted metamorphism. The great number and variety of mechanisms that have been proposed to explain some or all of these features reflects the fact that fundamental constraints on such models have been slow in coming. Recent developments, most notably in geophysical imaging and geochronology, have been key to coalescing the results of varied Himalayan investigations into constraints with which to test proposed evolutionary models. These models fall into four general types: (1) the inverted metamorphic sequences within the footwall of the Himalayan thrust and adjacent hanging wall anatexis are spatially and temporally related by thrusting; (2) thrusting results from anatexis; (3) anatexis results from normal faulting; and (4) apparent inverted metamorphism in the footwall of the Himalayan thrust is produced by underplating of right-way-up metamorphic sequences. We review a number of models and find that many are inconsistent with available constraints, most notably the recognition that the exposed crustal melts and inverted metamorphic sequences not temporally related. The generalization that appears to best explain the observed distribution of crustal melts and inverted metamorphic sequences is that, due to specific petrological and tectonic controls, episodic magmatism and out-of-sequence thrusting developed during continuous convergence juxtaposing allochthonous igneous and metamorphic rocks. This coincidental juxtaposition has proven to be something of a red herring, unduly influencing attention toward finding a causal relationship between anatexis and inverted metamorphism.     

Indirect effects of the intertidal burrowing crab<Emphasis Type="Italic">Chasmagnathus granulatus</Emphasis> in the habitat use of Argentina’s South West Atlantic salt marsh birds

The burrowing crab,Chasmagnathus granulatus, is the dominant benthic macroinvertebrate of southwest Atlantic salt marshes and tidal flats, having strong ecosystem engineering effects by direct and indirect effects on soil, vegetation, invertebrates, fishes, and birds. Vegetation structure is a main component for bird habitat selection, since greater habitat complexity generates higher niche diversity. This environmental complexity can be modified by species interactions or disturbance events (i.e., by crabs), in turn modifying the associated community. The bird species of salt marshes of the southwest Atlantic are highly dependent on these ecosystems. We assessed the effects of the burrowing crab on the structure of the cordgrass,Spartina densiflora, marshes, and how these changes affected the composition and diversity of birds. This study was conducted at the Mar Chiquita Coastal Lagoon, Argentina (37°40′S, 57°23′W).S. densiflora marshes were classified within three categories: marshes without burrowing crabs, marshes with low burrow densities, and marshes with high burrow densities. We made vegetation and bird surveys during spring beforeS. densiflora produce seeds and in summer when seeds are abundant. We also manipulated inflorescence (i.e., spike) density (a variable affected by crabs) to assess the effect on bird habitat use. The highest inflorescence density ofS. densiflora and highest bird diversity were recorded at low burrow densities. Cover and height ofS. densiflora were negatively correlated with burrow density. The number of bird species and the number of red-capped wren-spinetail,Spartonoica maluroides, were negatively related with cover and height ofS. densiflora. Experiments confirmed that granivorous species used areas with higher spike densities, a variable related to crab burrow density. Burrowing crabs directly and indirectly affect the cover, height, spike density, and morphologic characteristic of seeds ofS. densiflora marshes. These effects indirectly affect the bird community that uses these marshes, being negatively related toS. maluroides and total bird abundance, and positively related to bird diversity.     

Urban heat island and differences in outdoor comfort levels in Glasgow, UK

From extensive outdoor comfort campaigns, preliminary outdoor comfort ranges have been defined for the local population of Glasgow, UK, in terms of two thermal indices: ‘Temperature Humidity Sun Wind’ (THSW) and ‘Physiological Equivalent Temperature’ (PET). A series of measurements and surveys was carried out from winter through summer 2011 during 19 monitoring campaigns. For data collection, a Davis Vantage Pro2 weather station was used, which was equipped with temperature and humidity sensors, cup anemometer with wind vane, silicon pyranometer and globe thermometer. From concurrent measurements using two weather stations, one located close to the city core and another located at a rural setting, approximately at a 15-km distance from the urban area of Glasgow, comparisons were made with regard to thermal comfort levels and to urban–rural temperature differences for different periods of the year. It was found that the two selected thermal indices (THSW and PET) closely correlate to the actual thermal sensation of respondents. Moreover, results show that the urban site will have fewer days of cold discomfort, more days of ‘neutral’ thermal sensation and slightly higher warm discomfort. The most frequent urban heat island intensity was found to be around 3° C, whereas the fraction of cooling to heating degree-hours for a T _base of 65 °F was approximately 1/12th.     

Teaching Aid: Minimum/Maximum Autocorrelation Factors for Joint Simulation of Attributes

Multivariate conditional simulation is used to assess the multivariate grade risk in mineral deposits. With the presence of several spatially correlated attributes, it is important to ensure that their joint simulation is carried out properly and that the observed spatial correlation is reproduced in the realizations. The method of minimum/maximum autocorrelation factors (MAF) is a well established and practical technique that can be used for this purpose. MAF offers tremendous advantages over standard full cosimulation, principal component analysis, and stepwise techniques. In what follows, a detailed review of the MAF technique, its applications, and examples are provided to guide the practitioner on its use.     

The Geysers-Cobb Mountain Magma System, California (Part 2): timescales of pluton emplacement and implications for its thermal history

Over 400 ion microprobe U-Pb isotopic ages measured for zircons extracted from 24 geothermal wells that penetrate the Geysers Plutonic complex (GPC) allow us to conclude that the entire known extent of the GPC crystallized during the early Pleistocene. Nine samples of the microgranite porphyry that forms the shallow cupola (100-1,500 m below sea-level, mbsl) of the GPC yield the oldest model U-Pb age (1.75 ± 0.01 Ma after correction for initial U series disequilibrium; errors 1σ). Twelve samples from the main intrusive phase (orthopyroxene-biotite granite) present at depths >1,250 mbsl define a crystallization age of 1.27 ± 0.01 Ma. This coincides with the age determined for a structurally and compositionally distinct body of granodiorite (1.25 ± 0.01 Ma; N = 5 samples) that is intruded over a similar depth range. Two petrographically distinct varieties of orthopyroxene-biotite granite yield ages of 1.46 ± 0.03 (GPC21-6000) and 1.16 ± 0.02 Ma (CA5636 74F 21; three samples). U-Pb zircon ages for dikes intruded in metagraywacke country-rocks overlap with those obtained from the main body of the GPC and include the youngest material identified (dike sample NEGU2 ST1-7700: 1.11 ± 0.03 Ma). Overall, the U-Pb results demonstrate that the main body of the GPC (∼300 km³) was emplaced and crystallized within the upper crust over a short time interval (0.2 Ma) that overlaps with zircon crystallization ages of overlying silicic volcanic units.     

Crystal and molecular structure and spectroscopic behavior of isotypic synthetic analogs of the oxalate minerals stepanovite and zhemchuzhnikovite

The crystal structure of synthetic stepanovite, Na[Mg(H₂O)₆][Fe(C₂O₄)₃]·3H₂O, and zhemchuzhnikovite, Na[Mg(H₂O)₆][Al_0.55Fe_0.45(C₂O₄)₃]·3H₂O, has been determined by single-crystal X-ray diffraction methods. The compounds are isotypic to each other and to the previously reported Na[Mg(H₂O)₆][M(C₂O₄)₃]·3H₂O (M: Cr, Al). They crystallize in the trigonal P3c1 space group with Z = 6 molecules per unit cell and (hexagonal axes) a = 17.0483(4), c = 12.4218(4) Å for the iron compound, and a = 16.8852(5), c = 12.5368(5) Å for the Al/Fe solid solution. Comparison of our crystallographic results with previous X-ray diffraction and chemical data of type stepanovite and zhemchuzhnikovite minerals provides compelling evidence that these natural materials possess the same crystal and molecular structure as their synthetic counterparts. It is shown that the originally reported unit cell for stepanovite represents a pronounced sub-cell and that the correct unit cell and space group are based on weak superstructure reflections. The infrared and Raman spectra of both synthetic analogs were also recorded and are briefly discussed.     

On the moisture-related buckling of marine composite panels using approximate analysis

A discussion is presented that highlights the growing utilization of composite structures for marine applications. Important to this trend is an understanding of the buckling response of marine panels under hygroscopic loads. Consideration are presented for the use of eigensensitivity analysis as a means of developing an approximate closed-form expression for computing the critical buckling response in the absense of an exact solutions