Soil Budget,Net Export,and Potential Sinks of Nitrogen in the Lower Oglio River Watershed (Northern Italy)

A nitrogen mass balance, realized for the lower Oglio River basin (Po River Plain, northern Italy), suggested an elevated impact of agricultural activities in this watershed. Livestock manure, synthetic fertilizers, biological fixation, atmospheric deposition, and wastewater sludge contributed 51, 34, 12, 2, and 1% of total N (TN) input, respectively (basin average 450 kg N ha^?1 arable land (AL) year^?1, overall input 100 115 t N year^?1). Crop uptake, ammonia volatilization and denitrification in soils contributed 65, 21, and 14%, respectively, of TN output (basin average 270 kg N ha^?1 AL year^?1, overall output 60 060 t N year^?1). N inputs exceeded outputs by 40 056 t N year^?1, resulting in a basin average surplus of about 180 kg N ha^?1 AL year^?1. About 34% of the N surplus was exported annually from the basin while the remaining amount (about 26 800 t N year^?1) underwent other unaccounted for processes within the watershed. The relevance of nitrogen removal via denitrification in aquatic compartments within the watershed was evaluated. Denitrification in the secondary drainage network can represent a relevant nitrogen sink due to great linear extension (over 12 500 km), with estimated nitrogen loss up to 8500 t N year^?1. Denitrification in the riverbed and in perifluvial wetlands have the potential to remove only a small fraction of the nitrogen surplus (<3%). Evidence suggests the relevance of groundwater as a site of nitrogen accumulation.     

Phosphorus Cycling in a Freshwater Estuary Impacted by Cyanobacterial Blooms

The availability of reactive phosphorus (P) may promote cyanobacterial blooms, a worldwide increasing phenomenon. Cyanobacteria may also regulate benthic P cycling through labile organic input to sediments, favouring reduced conditions and P release, ultimately acting as self-sustainment mechanism for the phytoplankton blooms. To analyse P–cyanobacteria feedbacks and compare external versus internal loads, we investigated P cycling in the Curonian Lagoon, a freshwater estuary with recurrent summer blooms. At two sites representing the dominant sediment types, we characterised P pools and mobility, via combined pore water analysis, calculation of diffusive exchanges and flux measurements via sediment core incubations. Annual P budgets were also calculated, to analyse the whole lagoon role as net sink or source. Muddy sediments, representing nearly 50 % of the lagoon surface, displayed higher P content if compared with sandy sediments, and most of this pool was reactive. The muddy site had consequently higher pore water dissolved inorganic phosphorus (DIP) concentrations maintaining high diffusive gradients. However, measured fluxes suggested that both sediment types were mostly P sinks except for a large DIP regeneration (nearly 30 μmol m^?2 h^?1) recorded at the muddy site during an intense cyanobacteria bloom. Such internal regeneration had the same order of magnitude as the annual external P load and may offset the net annual DIP sink role of the estuary. It may also prolong the duration of the bloom. Our results suggest that positive feedbacks can regulate N-fixing cyanobacteria blooms and internal P recycling, through either diffusive fluxes or sediment settling and resuspension.     

Improved Pile Geometry to Reduce Negative Skin Friction on Single Driven Pile and Pile Groups Subjected to Lateral Loads

Geotechnical and Geological Engineering - Negative skin friction on piles represents a severe problem when piles were installed in soft clay due to consolidation process. It reduces the bearing...     

Natural and anthropogenic heavy metals in estuarine cohesive sediments: geochemistry and bioavailability

The geochemistry, mineralogy, and grain size distribution of several estuarine cohesive sediment samples from potentially human-influenced areas without such an influence were analyzed to determine the natural heavy metal content and evaluate its impact on the Bahía Blanca estuarine environment. The data were compared with different ranges of concentrations for heavy metals in marine sediments established by the NOAA Screening Quick Reference Tables in which values range from background levels to those considered toxic to the marine environment. Our total heavy metal contents were below the established hazardous levels in all the analyzed samples, even though the potentially human-influenced areas (harbors, industry, urban spread) showed the highest total concentration values as well as greater percentages of bioavailable compounds. This would imply a low and not extensive anthropogenic input into the environment. The relatively high proportions in which Cd, Pb, and Cr appear as bioavailable compounds at some sites not influenced by human activity suggest the presence of a natural source for these elements. This could be attributed to the weathering of naturally occurring volcanic minerals, indicating that special care must be taken when monitoring of sediment for anthropogenic activity is carried out within this environment. According to the results obtained, and in order to minimize the environmental impact caused by periodic water injection dredging, relocation of sewage outfalls from vessel mooring areas into open waters is strongly recommended.     

The relevance of energy damping in unreinforced masonry rocking mechanisms. Experimental and analytic investigations

Existing unreinforced masonry buildings frequently suffer out-of-plane local collapse mechanisms when undergoing earthquake ground motion. The energy damping that occurs during the motion, due to impacts of a wall against the foundation or against other walls, is a relevant parameter on the response. An experimental investigation has been carried out to estimate the dissipation of kinetic energy that takes place during free oscillations. Restraint conditions allow for two-sided rocking (wall resting on a foundation) and one-sided rocking (wall resting on a foundation adjacent to transverse walls). Five specimens have been tested, modelling walls acted out-of-plane (fa?ades). When one-sided rocking is under consideration, different depths of the contact surface between fa?ade and transverse walls are considered. In the case of two-sided rocking, the experimental coefficient of restitution is slightly lower than the analytic coefficient. In the case of one-sided rocking, an analytic formulation is proposed and this is compared against experimental data. Although the coefficient of restitution of one-sided rocking is less than half that of two-sided rocking, it is not equal to zero. Thus, it cannot induce a sudden stop of the motion. Hence, nonlinear time history analyses performed under this assumption may prove unsafe. Moreover, a comparison has been carried out between overturning maps, induced by twenty natural accelerograms, computed for the analytic coefficient of restitution and those computed for the experimental coefficient of restitution. The increased energy dissipation reduces the frequency of overturning and causes a more regular behaviour.     

Mineralogy and palynology of the Mesopotamian plain sediments, Central Iraq

This work was done on the representative section (230 cm) in Dora site which located in Baghdad in the central of the Mesopotamian Plain. Eleven soil samples were examined mineralogically and palynologically. Grain size analyses showed that silt is the higher fraction (61%), clay is the least (9%), whereas sand forms 30%. Translucent and opaque heavy minerals contributed 57% from the sand fraction, whereas the light minerals formed just 43%. The type of heavy minerals and its maturity defined four provenances—they are granitic, basic igneous and metamorphic rocks—that belong to the high lands of south Turkey and north of Iraq. The fourth provenance is the sedimentary rocks which are located north of Mesopotamian Plain around the Tigris River and their tributaries. Dinoflagellate within thin bed of marine origin clearly indicated the transgression of the Arabian Sea northward through Tigris and Euphrates valleys or high marine waves reached to Baghdad before 10,000 years P.B. approximately. This means that the marine sediments were also an additional source of the Mesopotamian Plain. Three specific climatic features are identified via palynological interpretation; a temperate-wet climate extended from 10,000 to 5,000 years P.B. followed by dry period extended from 5,000 to 3,500 years P.B. and the last climatic feature is characterized by oscillation of wet to dry periods which is dominant since 3,500 till now.     

Evaluation of Methods Used for Reducing Heavy Metal Leaching from Sandy Soil

Excessive heavy metal content in sandy soils poses risk to human health and the environment. The rapid expansion of urban areas makes it imperative to manage contaminated sites so that land can be reclaimed for beneficial purposes. Several methods have been proposed to control the leaching of heavy metals from contaminated soils. In this study, four techniques for mobilization and immobilization of metals in sandy soil were compared. The assessed mobilization techniques included chemical extraction using aqueous solutions of acids and chelating agents as well as biochemical extraction using sulfur-oxidizing microorganisms. The evaluated immobilization techniques included lime-cement-pozzolan stabilization and natural-zeolite stabilization. The immobilization techniques do not involve removing metals from soil and instead focus on addition of substances to the soil that alter its composition, volume, and properties. On the other hand, mobilization techniques entail the removal of metals from soil and changes in the soil properties. The findings confirmed that both mobilization and immobilization are effective in controlling the leaching of metals from sandy soils and thereby minimize the risk to the environment and human health. However, the appropriate technique for application at a given site should be chosen on a case-by-case basis, while accounting for the economic and technical feasibility, the necessary level of cleanup, and effect of residual metals on human health and the environment.     

Silver and silver-bearing minerals at the Um Samiuki volcanogenic massive sulphide deposit, Eastern Desert, Egypt

The Um Samiuki Zn–Cu–Pb–Ag mineralisation, south Eastern Desert, Egypt is hosted by felsic volcanic rocks which form part of the 712-Ma-old, east-west-trending Shadli Volcanic Belt. Two major occurrences of massive sulphides are present at the top of rhyolitic breccia in the Western and Eastern mine areas. In each occurrence, a bornite-bearing zone is overlain by a pyrite-chalcopyrite-bearing zone and underlain by a disseminated, Cu-depleted zone. In the massive sulphide ore, sphalerite, chalcopyrite, pyrite, galena, bornite and tetrahedrite–tennantite are major minerals, whereas arsenopyrite, pyrrhotite, molybdenite and magnetite are accessory phases. Covellite and digenite are common secondary minerals. Bornite, tetrahedrite–tennantite and covellite contain high amounts of silver (averages of 1.97, 1.39 and 1.82 wt% respectively). Based on mineralogical balance calculations, bornite and covellite accommodate 80% of silver in the Um Samiuki deposit. Ag was incorporated in the crystal structure of the early-crystallised copper sulphides and sulphosalts and silver minerals. The temperature, sequential precipitation of the fluids and the structure of the crystallising phases control the distribution of silver. Post-depositional deformation and metamorphic processes caused liberation, remobilisation and redeposition of silver within the massive sulphides.Editorial handling: D. Lentz     

Origin of disc lopsidedness in the Eridanus group of galaxies

The H  i surface density maps for a sample of 18 galaxies in the Eridanus group are Fourier analysed. This analysis gives the radial variation of the lopsidedness in the H  i spatial distribution. The lopsidedness is quantified by the Fourier amplitude A ₁ of the m = 1 component normalized to the average value. It is also shown that in the radial region where the stellar disc and H  i overlap, their A ₁ coefficients are comparable. All the galaxies studied show significant lopsidedness in H  i . The mean value of A ₁ in the inner regions of the galaxies (1.5–2.5 scalelengths) is ≥ 0.2. This value of A ₁ is twice the average value seen in the field galaxies. Also, the lopsidedness is found to be smaller for late-type galaxies; this is opposite to the trend seen in the field galaxies. These two results indicate a different physical origin for disc lopsidedness in galaxies in a group environment compared to the field galaxies. Further, a large fraction (∼30 per cent) shows a higher degree of lopsidedness ( A ₁≥ 0.3). It is also seen that the disc lopsidedness increases with the radius as demonstrated in earlier studies, but over a radial range that is two times larger than done in the previous studies. The average lopsidedness of the halo potential is estimated to be ∼10 per cent, assuming that the lopsidedness in H  i disc is due to its response to the halo asymmetry.     

Cenozoic denudation in the Marrakech High Atlas,Morocco: insight from apatite fission‐track thermochronology

In North Africa, the High Atlas belt culminates at more than 4000 m. In Morocco, recent work shows that a lithospheric thinning explains about 1000 m of the mean topography, the remaining topography being related to crustal shortening. We combine regional geology with new apatite fission‐track (AFT) ages to constrain the timing of these events in the Marrakech High Atlas (MHA). In the inner belt, 10 AFT ages are comprised between 9 ± 1 and 27 ± 3 Ma. These Neogene ages indicate that the MHA underwent significant denudation during that time. In the southern foreland domain of the belt, three samples give scattered AFT ages between 27 ± 2 and 87 ±5 Ma. Geological evidences allow us to constrain the age of a major denudation event during Middle Miocene age. We propose that it is linked to the thermal doming highlighted in the whole Moroccan Atlas domain.