Periglacial trimlines,former nunataks and the altitude of the last ice sheet in Wester Ross,northwest Scotland

High-level weathering limits separating ice-scoured topography from frost-weathered detritus were identified on 28 mountains in Wester Ross at altitudes of 700–960 m, and a further 22 peaks support evidence of ice scouring to summit level. Weathering limits are defined most clearly on sandstone and gneiss, which have resisted frost shattering during the Late Devensian Lateglacial, but can also be distinguished on schists and quartzite. Schmidt hammer measurements and analyses of clay mineral assemblages indicate significantly more advanced rock and soil weathering above the weathering limits. The persistence of gibbsite above weathering limits indicates that they represent the upper limit of Late Devensian glacial erosion. The regular decline of weathering-limit altitudes along former flowlines eliminates the possibility that the weathering limits represent former thermal boundaries between protective cold-based and erosive warm-based ice. The weathering limits are therefore interpreted as periglacial trimlines that define the maximum surface altitude of the last ice sheet. Calculated basal shear stresses of 50–95 kPa are consistent with this interpretation. Reconstruction of ice-sheet configuration indicates that the former ice-shed lay above 900 m along the present watershed, and that the ice surface descended northwestwards, with broad depressions along major troughs and localised domes around independent centres of ice dispersal. Extrapolation of the ice surface gradient and altitude suggests that the ice sheet did not overrun the Outer Hebrides, but was confluent with the independent Outer Hebrides ice-cap in the North Minch basin. Erratics located up to 140 m above the reconstructed ice surface are inferred to have been emplaced by a pre-Late Devensian ice sheet (or ice sheets) of unknown age. © 1997 John Wiley & Sons, Ltd.     

Paleoclimate changes inferred from stable isotopes and magnetic properties of organic-rich lake sediments in Arctic Norway

Stable isotope measures in organic matter are frequently used as indicators of past climate change. Although such analyses can provide valuable information, there is considerable uncertainty associated with studies of organic-rich sediments, especially those from Arctic lakes and bogs. We studied stable isotopes of carbon and nitrogen, and magnetic properties in a sediment core from a small alkaline lake with a high sedimentation rate, Lake Nattmålsvatn, Norway. There is good correspondence among the different sediment variables during the late glacial, and they seemingly reflect major climate variations such as the Allerød Interstade and the Younger Dryas, as well as the transition into the current interglacial. During the early Holocene, however, these relationships are more complex and δ¹³C and δ¹⁵N values do not stabilize until ~7,500 cal year BP. A significant excursion in all variables occurs between 6,850 and 6,500 cal year BP and is interpreted to represent climate deterioration. Holocene δ¹³C values vary little and indicate that isotopically-depleted dissolved inorganic carbon (DIC) in the lake, possibly influenced by methanotrophy and high pCO₂, dominated the lake’s carbon cycle. Holocene δ¹⁵N is similarly muted, likely due to the availability of abundant dissolved nitrogen. Bulk organic matter is probably dominated by phytoplankton remains produced beneath the ice cover in late spring and during ice breakup when isotopically-depleted DIC, pCO₂ and ammonium availability were maximal. Thus, use of δ¹³C and δ¹⁵N as indicators of Holocene paleoclimate and paleoproductivity variation can be challenging in a lake such as Nattmålsvatn, where ice cover isolates the basin for large parts of the year, allowing dissolved respiratory gases to accumulate in the water column. In contrast, magnetic variables appear to better track climate variations. In particular, runoff-driven influx of minerogenic sediments shows high variability that can be attributed to regional changes in Holocene winter precipitation. The most striking shifts occur between 4,000 and 2,300 cal year BP.     

Evaluation of trace element availability from secondary metallurgical slag generated in steelmaking by sequential chemical extraction

During carbon steel manufacture, slag residues are generated to remove material impurities from liquid metal and thus control the quality of carbon steel. As the utilization of secondary metallurgical slags is not as efficient as those of primary slags, a comprehensive characterization of steel ladle slag was performed. Pseudo-total concentrations of a wide range of elements were determined during a 6-week sampling period with relevant physical and chemical properties, sequential extraction of trace elements, and parallel mineralogical characterization of extraction residues from a representative combined sample. According to the results, only Cr and V occurred in elevated concentrations with respective 6-week mean values of 198 and 310 mg kg^?1 (d.w.). The residual standard deviation of the weekly pseudo-total concentration values of the aforementioned elements (24 and 31 %, respectively) indicated that significant variation in the concentration of trace elements can occur due to fluctuation in process conditions and/or slag characteristics. The sequential extraction procedure suggested potential phytoavailability of V (123 mg kg^?1, d.w., amounting to 41 % of the respective pseudo-total concentration) through, e.g., changes in prevailing redox conditions. Although the analytical approach was validated by the analysis of a certified reference material and the calculation of extraction recoveries, the mineralogical characterization of parallel extraction residues indicated non-selectivity of the procedure coupled with potential redistribution phenomena during extraction with hydrogen peroxide and ammonium acetate.     

Numerical simulation of groundwater flow in the Peshawar intermontane basin, northwest Himalayas

The hypothesis that abnormal fluid pressure is generated in basins under tectonic compression is tested. The study site, between the Main Karakoram Thrust (MKT), Main Mantle Thrust (MMT), Main Central Thrust (MCT), Main Boundary Thrust (MBT) and Salt Range Thrust (SRT) in northwest Pakistan, is experiencing a tectonic compression of 90 MPa. The Peshawar basin is a broad, oval depression comprising a thick sequence of lacustrine, deltaic and fluvial sediments overlain by loess and alluvial deposits dated at 2.8–0.6 Ma. It is surrounded by the Precambrian and Tertiary intrusive and metamorphic rocks on the north and sedimentary rocks of Paleogene and Neogene to the south. The basin was divided into four hydrostratigraphic units for numerical simulations using the three-dimensional finite-element model FEMWATER within groundwater modeling system (GMS) ver. 5.1. Simulated pressure head data have been compared with the field measurements of hydraulic heads. Transient simulations indicate that topography alone is not sufficient to induce the pressure heads observed in the field, generating consistently positive residuals 0.98–2.90 m over the topography-driven flow. The residuals disappeared after inclusion of the elastic properties of the four hydrostratigraphic units in the model, suggesting the effect of tectonic compression.     

Enhancing spatial accuracy of mobile phone data using multi-temporal dasymetric interpolation

Novel digital data sources allow us to attain enhanced knowledge about locations and mobilities of people in space and time. Already a fast-growing body of literature demonstrates the applicability and feasibility of mobile phone-based data in social sciences for considering mobile devices as proxies for people. However, the implementation of such data imposes many theoretical and methodological challenges. One major issue is the uneven spatial resolution of mobile phone data due to the spatial configuration of mobile network base stations and its spatial interpolation. To date, different interpolation techniques are applied to transform mobile phone data into other spatial divisions. However, these do not consider the temporality and societal context that shapes the human presence and mobility in space and time. The paper aims, first, to contribute to mobile phone-based research by addressing the need to give more attention to the spatial interpolation of given data, and further by proposing a dasymetric interpolation approach to enhance the spatial accuracy of mobile phone data. Second, it contributes to population modelling research by combining spatial, temporal and volumetric dasymetric mapping and integrating it with mobile phone data. In doing so, the paper presents a generic conceptual framework of a multi-temporal function-based dasymetric (MFD) interpolation method for mobile phone data. Empirical results demonstrate how the proposed interpolation method can improve the spatial accuracy of both night-time and daytime population distributions derived from different mobile phone data sets by taking advantage of ancillary data sources. The proposed interpolation method can be applied for both location- and person-based research, and is a fruitful starting point for improving the spatial interpolation methods for mobile phone data. We share the implementation of our method in GitHub as open access Python code.     

Integrated coastal resources management and community participation in a small island setting

The concept of integrated coastal zone management must be rethought to adapt it to the geography and social conditions of small islands. Because of their size, all small islands are in the coastal zone. Defining the whole of the island and its coastal waters as the management area may weaken a program's effectiveness. An alternative may be to adapt special area management planning to the socio-spatial organization found on small islands. Social conditions on islands, where people live in relatively small cohesive communities, makes resource user participation in planning and management particularly germane. This paper outlines an argument for small islands to use participation as a central strategy of coastal management based on experience with natural resource management efforts on the island of Pohnpei in the Federated States of Micronesia.     

Validation of very high cloud droplet number concentrations in air masses transported thousands of kilometres over the ocean

The microstructure of orographic clouds related to the aerosol present was studied during the second Aerosol Characterisation Experiment (ACE‐2). Very high cloud droplet number concentrations (almost 3000 cm⁻³) were observed. These high concentrations occurred when clouds formed on a hill slope at Tenerife in polluted air masses originating in Europe that had transported the order of 1000 km over the Atlantic Ocean. The validity of the measured droplet number concentrations was investigated by comparing with measurements of the aerosol upstream of the cloud and cloud interstitial aerosol. Guided by distributions of the ratios between the measurements, three criteria of typically 30% in maximum deviation were applied to the measurements to test their validity. Agreement was found for 88% of the cases. The validated data set spans droplet number concentrations of 150–3000 cm⁻³. The updraught velocity during the cloud formation was estimated to 2.2 m s⁻¹ by model calculations, which is typical of cumuliform clouds. The results of the present study are discussed in relation to cloud droplet number concentrations previously reported in the literature. The importance of promoting the mechanistic understanding of the aerosol/cloud interaction and the use of validation procedures of cloud microphysical parameters is stressed in relation to the assessment of the indirect climatic effect of aerosols.     

Total and opportunistic algal cover in relation to environmental variables

Based on a large data set from the national Danish monitoring program, spatial and temporal variability in total algal cover and in the fraction of opportunistic macroalgae was analysed in relation to environmental variables. Variations in water clarity and salinity combined with information on geographical location of sampling areas were found to explain almost 80% of the large-scale variation in algal cover between areas. As water clarity was largely regulated by concentrations of total-nitrogen (TN), and TN-concentrations by TN-input from land, total algal cover at given water depths was partly related to TN-input from land. The fraction of opportunistic algae responded predominantly to differences in salinity, the highest fractions being found in the most brackish areas. Temporal variability in algal cover and fraction of opportunists over the 14-year investigation period was much smaller than the variability between areas and could not be predicted from variations in environmental variables. In order for macroalgal cover to become a more sensitive indicator of water quality it would be necessary to either increase the sensitivity of the method or identify and include supplementary regulating factors in the model.