Electronic and magnetic properties of a natural aegirine as observed from its Mössbauer spectra

A natural sample of aegirine, ideally NaFeSi₂O₆, has been studied by transmission Mössbauer spectroscopy in the range 4.2–480?K. At selected temperatures, a longitudinal external field of 60?kOe was applied to the absorber. The sample was observed to order magnetically at 11±1?K. The paramagnetic Mössbauer spectra (MS) show the presence of ～10% Fe²⁺ in the M1 sites of the clinopyroxene structure. These MS have been decomposed into four quadrupole doublets: two minor ones for Fe²⁺ on M1 sites, a dominant one due to Fe³⁺ on M1 sites, and a second ferric component, with a contribution of ～3% and attributable to the tetrahedral sites. Two possibilities concerning the origin of the two distinct Fe²⁺ (M1) doublets are discussed. They are respectively based on inter-valence charge transfer and on the existence of distinct Fe²⁺ orbital configurations at the two M1 sites. Neither of the two models could be firmly excluded. The asymmetry parameter η of the electric field gradient at the Fe³⁺ (M1) sites is close to 1.0 and the quadrupole splitting within 0.34±0.01?mm/s at all temperatures. The MS at 4.2?K shows an asymmetric hyperfine-field distribution for Fe³⁺, with a maximum-probability field of 468?kOe. The maximum-probability field for Fe²⁺ is found to be 220?kOe. The shape of the applied-field MS at 4.2?K implies a static antiferromagnetic ordering and was successfully interpreted by a bidimensional distribution of the magnitude and orientation of the hyperfine field. Finally, the temperature variations of the respective centre shifts and quadrupole splittings could be explained on the basis of existing theoretical models.     

Extragalactic source counts and contributions to the anisotropies of the cosmic microwave background: predictions for the Planck Surveyor mission

We present predictions for the counts of extragalactic sources, the contributions to fluctuations and their angular power spectrum in each channel foreseen for the Planck Surveyor (formerly COBRAS/SAMBA ) mission. The contribution to fluctuations owing to clustering of both radio and far-IR sources is found to be generally small in comparison with the Poisson term; however the relative importance of the clustering contribution increases and may eventually become dominant if sources are identified and subtracted down to faint flux limits. The central Planck frequency bands are expected to be 'clean': at high galactic latitude (| b | > 20°), where the reduced galactic noise does not prevent the detection of the extragalactic signal, only a tiny fraction of pixels is found to be contaminated by discrete extragalactic sources. Moreover, the 'flat' angular power spectrum of fluctuations resulting from extragalactic sources substantially differs from that of primordial fluctuations; therefore, the removal of contaminating signals is eased even at frequencies where point sources give a sizeable contribution to the foreground noise.     

Theory and statistics of weak lensing from large-scale mass inhomogeneities

Weak lensing by large-scale mass inhomogeneities in the Universe induces correlations in the observed ellipticities of distant sources. We first review the harmonic analysis and statistics required of these correlations and discuss calculations for the predicted signal. We consider the ellipticity correlation function, the mean-square ellipticity, the ellipticity power spectrum and a global maximum-likelihood analysis to isolate a weak-lensing signal from the data. Estimates for the sensitivity of a survey of a given area, surface density, and mean intrinsic source ellipticity are presented. We then apply our results to the FIRST radio-source survey. We predict an rms ellipticity of roughly 0.011 in 1 × 1 deg² pixels and 0.018 in 20 × 20 arcmin² pixels if the power spectrum is normalized to σ₈ Ω^0.53 = 0.6, as indicated by the cluster abundance. The signal is significantly larger in some models if the power spectrum is normalized instead to the COBE anisotropy. The uncertainty in the predictions from imprecise knowledge of the FIRST redshift distribution is about 25 per cent in the rms ellipticity. We show that FIRST should be able to make a statistically significant detection of a weak-lensing signal for cluster-abundance-normalized power spectra.     

Effect of Spectral Resolution on the Mg II Index as a Measure of Solar Variability

The solar Mgii core-to-wing ratio is a useful index of UV variability throughout the solar cycle because it has been measured since 1978 in a series of successive satellite missions: Nimbus 7, Solar Mesosphere Explorer (SME), the NOAA 9–14 series, Upper Atmosphere Research Satellite (UARS), and ERS-2. Eventual construction of a single time series from 1978 to the present by combining these measurements will give a long record of almost daily UV variability to serve as a surrogate for estimating both UV and EUV solar radiation. Here we address the effect of spectral resolution on determination of both long-term and short-term solar variability from this index. We use UARS/SOLSTICE measurements of the Mgii line from October 1991 to December 1996 to study the effect of two spectral resolution regimes characteristic of existing measurements, 0.20 to 0.25 nm and 1.10 to 1.15 nm, on determination of the amplitude of 27-day rotational modulation and the more gradual change in chromospheric radiation in the declining phase of solar cycle 22. The two Mgii indices give solar variations that differ by a scaling factor of 2× for both the solar cycle change from 1992 to 1997 and the amplitude of 27-day modulation over the same period. Both types of measurements appear to yield solar signal equally well except at solar minimum when the solar changes become quite small.     

Effect of hydrologic management on marsh surface sediment deposition in coastal Louisiana

High rates of coastal land loss in Louisiana have prompted efforts to maintain or restore coastal wetland habitats, and structural management of marsh hydrology is one of a number of approaches that has been adopted. The aim of this study was to determine the effect of hydrologic management measures on marsh-surface sediment deposition in the Mississippi deltaic plain. Four impoundments, ranging in size from 50 ha to 177 ha and similarly sized control sites were included in the study. At each site, marsh-surface sediment traps were collected approximately biweekly for 3.5 yr to measure changes in sediment deposition. There was no significant difference in sediment deposition between any of the impoundment and control sites during the premanagement period. The results show no significant difference in marsh-surface sediment deposition between management year 1992–1993 and management year 1994–1995, but management year 1993–1994 had significantly lower sediment deposition than either the first or the last year of the study. Management year 1992–1993 showed the highest sediment deposition when it was assessed across all basins, areas, and sites, and this high rate of deposition is accounted for by the impact of Hurricane Andrew. For all management years there were significant differences between impoundment and control sites, with control sites showing higher rates of marsh surface sediment deposition than impoundments. No clear pattern was identified concerning the influence of various types of hydrologic management on rates of sediment deposition. This reduction in sediment deposition indicated that the areas under management in this study are receiving insufficient inorganic sediment deposition to keep pace with sea-level rise.     

Stress, failure and fluid flow deduced from earthquakes accompanying eruptions at Piton de la Fournaise volcano

In the present episode of eruptive activity, evidence from seismicity for sustained magma inflow from depth into the edifice of Piton de la Fournaise is lacking. Pre-eruptive main deformation and shallow seismicity help to identify very small volumes of magma that are in motion beneath the rim of the Dolomieu summit crater, and oriented along the azimuth of the future vents. Small magma pockets may reside in the cone above sea level, or may be expelled repeatedly, due to crystallisation in a small, low-velocity, aseismic region below sea level under the high-velocity central plug of the cone in which pre-eruptive earthquake swarms are located. In cross-section the hypocentres define two steep sheets diverging from the aseismic zone at sea level towards 1.5 km above sea level (or 1 km beneath the 2632 m high cone). However, failure induced by increased pressure in the suggested chamber does not account for the observed focal mechanisms.The occurrence and timing of magma transport are attested by eruption, and seismic activity may be related to magma transport. Focal mechanisms document strike-slip, not normal faulting or tensile failure. Vertical propagation of the edge of a feeder dike may enhance strike-slip motion above the edge, in a region where effective normal stress is decreased by thermally induced groundwater flow. The strike-slip mechanisms could also be caused by a tensile-shear widening of the horizontal section of vertical conduits.Fournaise strike-slip earthquakes occur in two orientations, with P axes orthogonal between them, within a single pre-eruptive event. Earthquakes are distributed in the same volume but mechanisms switch from one to another type systematically with time, indicating a reversal of stress conditions. The orientations of P axes with respect to the epicentral trend suggest that in the later parts of events leading to eruptions, a compression of the medium occurs after a dilation in the first part. The activated zone might respond successively to the arrival and the departure of the magma on its way from the reservoir at depth to the vent, radial to the cone.     

Mineral water exploration and exploitation at the Portuguese Hercynian Massif

The thermal baths and bottled water industry are highly related to the hydrogeology of hard rocks in Portugal. In the last 15 years, almost all classical dug wells or simple spring arrangements were replaced by drilled wells. The completion of these new wells was normally preceded by geological, geophysical, and hydrogeological surveys as well as by exploration and observation wells. A step-by-step approach resulted in a positive well location in most sites. Some small-scale, low-enthalpy geothermal projects are in operation in some locations.     

Warming at 18,000 yr B.P. in the Tropical Andes

Palynological, paleopedological, and glacial geomorphological evidence from the area of the high plain of Bogotá in the Colombian Eastern Cordillera indicates a significant climatic warming around 18,000¹⁴C yr B.P. Comparison of dated vegetation changes, pedogenic episodes, and glacier fluctuations provides the basis for defining the so-called “La Laguna Interstadial” that lasted from 19,500 to 17,000 yr B.P. During this interstadial period, mean annual temperatures in the tropical Andes were up to 4°C higher than during the preceding and following stadial periods, when full-glacial conditions prevailed and temperatures were up to 8°C colder than at present.     

Modelling of ground acceleration in the near source range: the case of 1976, Friuli earthquake (M = 6.5), northern Italy

A mixed statistical-deterministic model of earthquake rupture is developed for evaluating the strong ground motion in the near source range (receiver distance comparable to the fault length). The source parametrization is based on the k-square model and the propagation is computed by asymptotic Green's functions. The method is applied to the case of 1976, Friuli earthquake (M = 6.5) in northern Italy which occurred on a low-dip thrusting fault. Acceleration records at 29 stations are computed for 100 simulations of rupture histories. The mean value map of peak ground accelerations shows clearly a maximum to the south due to the inner geometry and directivity of the source. The variation of the estimated PGA versus the epicentral distance is strongly dependent on azimuth and is not decreasing monotonically. The comparison of these curves with those predicted by empirical acceleration–distance relationships shows discrepancies in the near source distance range. This study shows the importance of considering the complexity of the source rupture process for strong motion estimate in the near source range.