Assessment of spatial distribution of contaminants and their levels in soil and water resources of Calabar,Nigeria using geophysical and geological data

The contamination levels of soils and water resources in Calabar, Nigeria have been investigated using resistivity (vertical electrical sounding and electrical resistivity tomography), geochemical analyses of soil and water resources and textural analysis. Sixty randomly sited VES sites were investigated in two seasons while ERT investigations were performed along four profiles. The geochemical investigations were spread across seasons in order to track seasonal changes in physico-chemical parameters: hydrogen ion concentration (pH), electrical conductivity, total dissolved solids, chloride ion (Cl^?), nitrate ion (\( {\text{NO}}_{ 3}^{ - } \)), bicarbonate (\( {\text{HCO}}_{ 3}^{ - } \)), sulphate ion (\( {\text{SO}}_{ 4}^{2 - } \)), calcium ion (Ca²⁺), sodium ion (Na⁺), potassium ion (K⁺) and magnesium ion (Mg²⁺). Additionally, concentrations of ammonium, aluminium and nitrite ions in soils were determined. Results show that ionic concentrations in the sand-dominated soils and water are within permissible limits and baseline standards. The resistivities follow known trends in the area. However, at the central waste disposal site, a localised thin (< 5 m), low resistivity (< 15 Ωm) anomaly suspected to be due to contamination by leachates was observed. Comparatively, the contaminated area is also characterised by marginal increase in ionic concentrations. Strong attenuation capacities of overlying and adjoining clay/lateritic sediments and optimal design of the waste dump site probably reduced the spread of contaminants. The contaminated zone need to be closely monitored so that it does not extend to the aquifers. Hence, all strategies presently being used in managing wastes in Calabar should be sustained.     

A study of the factors influencing the occurrence of landslides in the Wushan area

Due to the complex natural geological conditions, many slope-related geological hazards occur in the Three Gorges Reservoir area in China. This study focuses on the characteristics of landslide development and their underlying mechanisms in this area. A statistical analysis is conducted to determine the characteristics of landslide development in the Wushan area, including the landslide distribution as a function of the elevation, slope, landslide material composition, scale, lithology, boundary conditions, instability mechanism, stratigraphic age, attitude, and sliding direction. The mechanisms of slope instability and the effect on the occurrence of landslides are analyzed. This study provides important reference material for landslide research in the Three Gorges Reservoir area and similar stratigraphic areas.     

Up-to-date urban rainstorm intensity formulas considering spatial diversity in China

With accelerating urbanization in China, urban waterlogging has had a serious impact on urban sustainable development and citizen welfare. Simple urban rainstorm intensity formulas with a monotonous frequency distribution type cannot meet the practical needs of urban drainage planning and design. This study focuses on the development of urban rainstorm intensity formulas based on spatial diversity in China. Using the annual maximum sampling method, rainstorm data of 607 cities throughout China were collected into a database, with a total of 24,933 rainfall samples (annual observations) under various specified precipitation durations. The database was used to verify that integrating the Pearson III and Gumbel distributions would constitute an optimal theoretical distribution type, owing to its small error and increased fitting precision. Modification and coordination of four important parameters in the rainstorm intensity formula were done using a digital elevation model, which improved the accuracy of the formula. In addition, precipitation distributions in China were treated from the perspective of topographic features to validate the calculations from up-to-date formulas. Accuracy assessment was accomplished using a national code (GB-50014-2006), GIS-based isograms, and authoritative results from the Hydrological Bureau of the Ministry of Water Resources. This work provides a comprehensive foundation for the establishment of an up-to-date rainstorm intensity formula for China, which can be used widely in different cities.     

Borehole diffusive flux apparatus for characterizing diffusive mass-transfer in subsurface systems

The concept of the Borehole Diffusive Flux Apparatus (BDFA) is presented herein. The BDFA is an innovative apparatus designed to provide continuous direct access to an undisturbed column of sediment that can be monitored at multiple discrete vertical intervals to provide high-resolution characterization of local-scale mass transfer and attenuation. The conceptual basis and technical design of the device are presented, along with an example of borehole design and installation at a field site. Mathematical simulations are used to illustrate its application for two scenarios. The results of these simulations indicate that test periods of several weeks to a few months should be sufficient to obtain robust results. The device has the potential to improve our ability to characterize critical mass-transfer and attenuation processes and to quantify the associated rates. This information is key to the evaluation of remediation alternatives, for enhancing the accuracy of mathematical models, and to support more effective long-term management of large groundwater contaminant plumes present at many sites.     

Extreme deformation characteristics and countermeasures for a tunnel in difficult grounds in southern Shaanxi,China

The Qingling–Bashan (QB) mountain region in southern Shaanxi mainly consists of strongly compressive zones from east to west, with tight folds and compressive fractures. There is a wide distribution of soft rocks of various types, such as phyllite and slate, accompanied by complex geological structures. Ironically, tunnel construction in these difficult grounds with complicated geological conditions embraces a high risk of extreme deformation due to various unpredictable reasons, which can frequently cause collapse and result in budget overruns during the construction period. Therefore, it is crucial to conduct effective countermeasures to eliminate or avoid such adverse impacts. This paper provides a case study on the “Yingfeng tunnel” (a tunnel constructed in soft rock consisting of a slate ground) based on a geological survey, indoor experiments and in situ monitoring. A successive rock mass deformation resulted in the tunnel lining seriously intruding into construction clearance and some other sections, even collapsing during the construction. The maximum displacement amount was 62.5 cm, while the maximum deformation speed reached as high as 34.18 mm/day. Additionally, to evaluate the construction impacts of tunnelling-induced geo-hazards, an investigation on extreme deformation was conducted. Considering the time-dependent features of the rock mass deformation, the constraint-convergence method was used to put forward applicable countermeasures in this paper. Finally, from the feedbacks of monitoring results, extreme deformation of the Yingfeng tunnel was effectively controlled.     

Socioenvironmental issues of river bed material extraction in the Himalayan piedmont (India)

The present study focuses on the Balason river running through the Himalayan piedmont zone (near Siliguri, India). The objective of the study is an assessment of the environmental effects of river bed material extraction by humans and the dependence of indigenous people on the river and its ecosystem services. The analysis is based on results of field work consisting of geodetic measurements of the river channel and interviews among the local community from the Nimtijot village. Historical hydrological data were also used for the study. The results of the investigation show that the Balason river is heavily affected by excessive exploitation of river bed material during dry season and the replenishment of extracted material in a monsoon season is not always sufficient. It leads to channel deepening. The local community working in the river heavily depends for its livelihood on continuing this activity. A decreasing amount of bed material to be extracted may lead to degradation of the strong relationship between the local community and their natural environment (river).     

Study on the natural radioactivity level of stone coal-bearing strata in East China

Based on γ-radiation dose rate and radon concentration measurements and ²³⁸U, ²³²Th, ²²⁶Ra, and ⁴⁰K radionuclide testing, this study identifies the radioactive anomalies of stone coal-bearing strata in East China and evaluates the natural radioactivity levels in the air, solid, water and plant media in the typical area of the regional stone coal-bearing layers. The stone coal-bearing strata in East China occur in the lower Cambrian system along the margin of the Yangtze block; additionally, the radioactive anomaly area is sporadically distributed in the stone coal-bearing layers. The background values of ²³⁸U, ²³²Th, ²²⁶Ra, and ⁴⁰K are higher in the stone coal-bearing areas, and the spatial distribution of these natural radionuclides shows significant variability. ²³⁸U and ²²⁶Ra clearly accumulate in the coal, coal gangue and soil and are the main sources of the environmental radiation in coal mines. The γ-radiation shows a higher background value in the stone coal-bearing area, and this radioactive pollution cannot be ignored. Typically, the effective dose of γ-radiation exceeds the limit value of 5 mSv/a, and the total α and total β concentrations of the groundwater are 10–30 times the limit value at some points. The residents near the mining area are subjected to a higher radiation dose, and the groundwater, building materials, and plants have been contaminated by the radioactive pollution sporadically through time. It is necessary to strengthen the monitoring work of radioactive environments and to take appropriate control measures.     

Laboratory investigations of inert gas flow behaviors in compact sandstone

The seepage evolution behavior of compact rock is significant for the stability and safety of many engineering applications. In this research, both hydrostatic and triaxial compression tests were conducted on compact sandstone using an inert gas, namely argon. A triaxial compression test with a water permeability measurement was carried out to study the difference between the gas permeability and water permeability evolutions during the complete stress–strain process. Based on the experimental data, the hydrostatic stress-dependent gas permeability was discussed firstly. A second-order function was proposed to predict and explain the gas slippage effect. The mechanical properties and crack development of the sandstone samples were discussed to better understand the permeability evolution with crack growth during the complete stress–strain process. The results show that the gas permeability evolution can be divided into five stages according to the different crack growth stages. Then, the permeability changes in the crack closure stress \( \sigma_{\text{cc}} \), crack initiation stress \( \sigma_{\text{ci}} \), crack damage stress \( \sigma_{\text{cd}} \) and peak stress \( \sigma_{\text{p}} \) with confining pressures were analyzed. Finally, we found that the difference between the corrected gas permeability and water permeability can be attributed to the interaction between the water and sandstone grains.     

The synergistic effect of calcium on organic carbon sequestration to ferrihydrite

Sequestration of organic carbon (OC) in environmental systems is critical to mitigating climate change. Organo-mineral associations, especially those with iron (Fe) oxides, drive the chemistry of OC sequestration and stability in soils. Short-range-ordered Fe oxides, such as ferrihydrite, demonstrate a high affinity for OC in binary systems. Calcium commonly co-associates with OC and Fe oxides in soils, though the bonding mechanism (e.g., cation bridging) and implications of the co-association for OC sequestration remain unresolved. We explored the effect of calcium (Ca²⁺) on the sorption of dissolved OC to 2-line ferrihydrite. Sorption experiments were conducted between leaf litter-extractable OC and ferrihydrite at pH 4 to 9 with different initial C/Fe molar ratios and Ca²⁺ concentrations. The extent of OC sorption to ferrihydrite in the presence of Ca²⁺ increased across all tested pH values, especially at pH ≥ 7. Sorbed OC concentration at pH 9 increased from 8.72 ± 0.16 to 13.3 ± 0.20 mmol OC g^?1 ferrihydrite between treatments of no added Ca²⁺ and 30 mM Ca²⁺ addition. Batch experiments were paired with spectroscopic studies to probe the speciation of sorbed OC and elucidate the sorption mechanism. ATR-FTIR spectroscopy analysis revealed that carboxylic functional moieties were the primary sorbed OC species that were preferentially bound to ferrihydrite and suggested an increase in Fe-carboxylate ligand exchange in the presence of Ca at pH 9. Results from batch to spectroscopic experiments provide significant evidence for the enhancement of dissolved OC sequestration to 2-line ferrihydrite and suggest the formation of Fe–Ca-OC ternary complexes. Findings of this research will inform modeling of environmental C cycling and have the potential to influence strategies for managing land to minimize OM stabilization.