Seasonal variability of element fluxes in two Central Siberian rivers draining high latitude permafrost dominated areas

In order to constrain the origin and fluxes of elements carried by rivers of high latitude permafrost-dominated areas, major and trace element concentrations as well as Sr and U isotopic ratios were analyzed in the dissolved load of two Siberian rivers (Kochechum and Nizhnyaya Tunguska) regularly sampled over two hydrological cycles (2005-2007). Large water volumes of both rivers were also collected in spring 2008 in order to perform size separation through dialysis experiments. This study was completed by spatial sampling of the Kochechum watershed carried out during summer and by a detailed analysis of the main hydrological compartments of a small watershed. From element concentration variations along the hydrological cycle, different periods can be marked out, matching hydrological periods. During winter baseflow period (October to May) there is a concentration increase for major soluble cations and anions by an order of magnitude. The spring flood period (end of May-beginning of June) is marked by a sharp concentration decrease for soluble elements whereas dissolved organic carbon and insoluble element concentrations strongly increase.When the spring flood discharge occurs, the significant increase of aluminum and iron concentrations is related to the presence of organo-mineral colloids that mobilize insoluble elements. The study of colloidal REE reveals the occurrence of two colloid sources successively involved over time: spring colloids mainly originate from the uppermost organic-rich part of soils whereas summer colloids rather come from the deep mineral horizons. Furthermore, U and Sr isotopic ratios together with soluble cation budgets in the Kochechum river impose for soluble elements the existence of three distinct fluxes over the year: (a) at the spring flood a surface flux coming from the leaching of shallow organic soil levels and containing a significant colloidal component (b) a subsurface flux predominant during summer and fall mainly controlled by water-rock interactions within mineral soils and (c) a deep groundwater flux predominant during winter which enters large rivers through unfrozen permafrost-paths. Detailed study of the Kochechum watershed suggests that the contribution of this deep flux strongly depends on the depth and continuous nature of the permafrost.     

Radiochemoecological Monitoring of the Salt Lakes of the Crimea

正1 Introduction The salt lakes of the Crimea contain the practically inexhaustible sources of salts of sodium,magnesium,bromine and other chemical elements(Ponizovskii,1965),being the potential powerful raw materials base for the     

Depositional history of the North Taymyr ice‐marginal zone,Siberia—a landsystem approach

The sediment–landform associations of the northern Taymyr Peninsula in Arctic Siberia tell a tale of ice sheets advancing from the Kara Sea shelf and inundating the peninsula, probably three times during the Weichselian. In each case the ice sheet had a margin frozen to its bed and an interior moving over a deforming bed. The North Taymyr ice‐marginal zone (NTZ) comprises ice‐marginal and supraglacial landsystems dominated by thrust‐block moraines 2–3 km wide and large‐scale deformation of sediments and ice. Large areas are still underlain by remnant glacier ice and a supraglacial landscape with numerous ice‐walled lakes and kames is forming even today. The proglacial landsystem is characterised by subaqueous (e.g. deltas) or terrestrial (e.g. sandar) environments, depending on location/altitude and time of formation. Dating results (OSL, ¹⁴C) indicate that the NTZ was initiated ca. 80 kyr BP during the retreat of the Early Weichselian ice sheet and that it records the maximum limit of a Middle Weichselian glaciation (ca. 65 kyr BP). During both these events, proglacial lakes were dammed by the ice sheets. Part of the NTZ was occupied by a thin Late Weichselian ice sheet (20–12 kyr BP), resulting in subaerial proglacial drainage. Copyright © 2002 John Wiley & Sons, Ltd.     

TanDEM-X multiparametric data features in sea ice classification over the Baltic sea

In this study, we assess the potential of X-band Interferometric Synthetic Aperture Radar imagery for automated classification of sea ice over the Baltic Sea. A bistatic SAR scene acquired by the TanDEM-X mission over the Bothnian Bay in March of 2012 was used in the analysis. Backscatter intensity, interferometric coherence magnitude, and interferometric phase have been used as informative features in several classification experiments. Various combinations of classification features were evaluated using Maximum likelihood (ML), Random Forests (RF) and Support Vector Machine (SVM) classifiers to achieve the best possible discrimination between open water and several sea ice types (undeformed ice, ridged ice, moderately deformed ice, brash ice, thick level ice, and new ice). Adding interferometric phase and coherence-magnitude to backscatter-intensity resulted in improved overall classification per- formance compared to using only backscatter-intensity. The RF algorithm appeared to be slightly superior to SVM and ML due to higher overall accuracies, however, at the expense of somewhat longer processing time. The best overall accuracy (OA) for three methodologies were achieved using combination of all tested features were 71.56, 72.93, and 72.91％ for ML, RF and SVM classifiers, respectively. Compared to OAs of 62.28, 66.51, and 63.05％ using only backscatter intensity, this indicates strong benefit of SAR interferometry in discriminating different types of sea ice. In contrast to several earlier studies, we were particularly able to successfully discriminate open water and new ice classes.     

The survival and disruption of cold dark matter microhaloes: implications for direct and indirect detection experiments

If the dark matter particle is a neutralino, then the first structures to form are cuspy cold dark matter (CDM) haloes collapsing after redshifts   z ≈ 100  in the mass range  10⁻⁶–10⁻³ M_⊙  . We carry out a detailed study of the survival of these microhaloes in the Galaxy as they experience tidal encounters with stars, molecular clouds, and other dark matter substructures. We test the validity of analytic impulsive heating calculations using high-resolution N -body simulations. A major limitation of analytic estimates is that mean energy inputs are compared to mean binding energies, instead of the actual mass lost from the system. This energy criterion leads to an overestimate of the stripped mass and an underestimate of the disruption time-scale, since CDM haloes are strongly bound in their inner parts. We show that a significant fraction of material from CDM microhaloes can be unbound by encounters with Galactic substructure and stars; however, the cuspy central regions remain relatively intact. Furthermore, the microhaloes near the solar radius are those which collapse significantly earlier than average and will suffer very little mass-loss. Thus, we expect a fraction of surviving bound microhaloes, a smooth component with narrow features in phase space, which may be uncovered by direct detection experiments, as well as numerous surviving cuspy cores with proper motions of arcminutes per year, which can be detected indirectly via their annihilation into gamma-rays.     

Effects of Dispersion of Wave Packets in the Determination of Lifetimes of High-Degree Solar <Emphasis Type="Italic">p</Emphasis> Modes from Time – Distance Analysis: MDI Data

The cross-correlation function of solar p modes in a time – distance analysis changes with travel distance (or travel time). The exponential decrease in the amplitude of the cross-correlation function with travel distance has been interpreted as the dissipation of solar p-mode power and used to determine the lifetimes of high-degree p modes. It is found that the width of the cross-correlation function increases with travel distance. We interpret the increase in width as the dispersion of the wave packet in a time – distance analysis. The dispersion would also cause a decrease in amplitude and affect the determination of lifetimes. We include the dispersion effect in the determination of lifetimes of high-degree p modes in a time – distance analysis and find that the derived lifetime increases significantly compared with the previous study for degree less than 400.     

New operational method of testing colloid complexation with metals in natural waters

A dialysis procedure was used to assess the distribution coefficients of ∼50 major and trace elements (TEs) between colloidal (1 kDa–0.22 μm) and truly dissolved (<1 kDa) phases in Fe- and organic-rich boreal surface waters. These measurements allowed quantification of both TE partitioning coefficients and the proportion of colloidal forms as a function of solution pH (from 3 to 8). Two groups of elements can be distinguished according to their behaviour during dialysis: (i) elements which are strongly associated with colloids and exhibit significant increases of relative proportion of colloidal forms with pH increase (Al, Ba, Cd, Co, Cr, Cu, Fe, Ga, Hf, Mn, Ni, Pb, rare earth elements (REEs), Sr, Th, U, Y, Zn, Zr and dissolved organic C) and (ii) elements that are weakly associated with colloids and whose distribution coefficients between colloidal and truly dissolved phases are not significantly affected by solution pH (As, B, Ca, Cs, Ge, K, Li, Mg, Mo, Na, Nb, Rb, Sb, Si, Sn, Ti, V). Element speciation was assessed using the Visual MINTEQ computer code with an implemented NICA-Donnan humic ion binding model and database. The model reproduces quantitatively the pH-dependence of colloidal form proportion for alkaline-earth (Ba, Ca, Mg, Sr) and most divalent metals (Co, Cd, Mn, Ni, Pb, Zn) implying that the complexation of these metals with low molecular weight organic matter (<1 kDa fraction) is negligible. In contrast, model prediction of colloidal proportion (fraction of 1 kDa–0.22 μm) of Cu²⁺ and all trivalent and tetravalent metals is much higher than that measured in the experiment. This difference may be explained by (i) the presence of strong metal-binding organic ligands in the <1 kDa fraction whose stability constants are several orders of magnitude higher than those of colloidal humic and fulvic acids and/or (ii) coprecipitation of TE with Fe(Al) oxy(hydr)oxides in the colloidal fraction, whose dissolution and aggregation controls the pH-dependent pattern of TE partitioning. Quantitative modeling of metal – organic ligand complexation and empirical distribution coefficients corroborate the existence of two colloidal pools, formerly reported in boreal surface waters: “classic” fulvic or humic acids binding divalent transition metals and alkaline-earth elements and large-size organo-ferric colloids transporting insoluble trivalent and tetravalent elements.     

Heat transport by groundwater flow during the Baikal rift evolution

A two-dimensional modelling study of sedimentation, fluid flow, and heat flow in the Baikal rift basin undergoing flank uplift and basin subsidence has been performed in order to understand the impact of these processes on the surface heat flow signal. Heat flow anomalies of different scales and magnitudes have been observed at the sediment surface of the lake Baikal basin, and the presence of a hydrothermal vent suggests that fluids play an important role in the regional distribution of heat flow. The BASIN-code applied for this study allows to simulate topographically and compaction-driven hydrodynamical fluid flow and coupled heat transfer.The flank uplift history provides the basis for a regional groundwater circulation towards the central basin area, with predicted Darcy velocities at present-day situation in the basement varying between 1 and 100 cm/year. Within the basin, the presence of aquifers and the pinch-out layering has a major control on the flow field, and compaction-driven flow velocities are strongly altered when combined with topography-driven flow. When velocities in the basement are larger than several centimeters per year, the regional fluid circulation is an effective mechanism of heat redistribution. Heat is brought from the flanks towards the basin area, with largest heat transported at a depth of 1–2 km at both sides. During the flank uplift, heat advection increases, with secondary variation related to the deposition of sedimentary layers. The heat flow is increased over the basin and reduced in the flanks, with a total heat output balance always positive. The extra heat output over the modelled transection is 2–10% of the initial heat output. The maximum computed heat fluxes are smaller than measured in the heat flow anomalies of the lake Baikal basin. Nevertheless, the model suggests that flow in the sedimentary basin combined with a topographically driven heat advection in the surrounding basement is a sufficient mechanism to account for the increased heat flow over the basin and the main features of the heat flow distribution.