Depositional history of the North Taymyr ice‐marginal zone,Siberia—a landsystem approach

The sediment–landform associations of the northern Taymyr Peninsula in Arctic Siberia tell a tale of ice sheets advancing from the Kara Sea shelf and inundating the peninsula, probably three times during the Weichselian. In each case the ice sheet had a margin frozen to its bed and an interior moving over a deforming bed. The North Taymyr ice‐marginal zone (NTZ) comprises ice‐marginal and supraglacial landsystems dominated by thrust‐block moraines 2–3 km wide and large‐scale deformation of sediments and ice. Large areas are still underlain by remnant glacier ice and a supraglacial landscape with numerous ice‐walled lakes and kames is forming even today. The proglacial landsystem is characterised by subaqueous (e.g. deltas) or terrestrial (e.g. sandar) environments, depending on location/altitude and time of formation. Dating results (OSL, ¹⁴C) indicate that the NTZ was initiated ca. 80 kyr BP during the retreat of the Early Weichselian ice sheet and that it records the maximum limit of a Middle Weichselian glaciation (ca. 65 kyr BP). During both these events, proglacial lakes were dammed by the ice sheets. Part of the NTZ was occupied by a thin Late Weichselian ice sheet (20–12 kyr BP), resulting in subaerial proglacial drainage. Copyright © 2002 John Wiley & Sons, Ltd.     

The survival and disruption of cold dark matter microhaloes: implications for direct and indirect detection experiments

If the dark matter particle is a neutralino, then the first structures to form are cuspy cold dark matter (CDM) haloes collapsing after redshifts   z ≈ 100  in the mass range  10⁻⁶–10⁻³ M_⊙  . We carry out a detailed study of the survival of these microhaloes in the Galaxy as they experience tidal encounters with stars, molecular clouds, and other dark matter substructures. We test the validity of analytic impulsive heating calculations using high-resolution N -body simulations. A major limitation of analytic estimates is that mean energy inputs are compared to mean binding energies, instead of the actual mass lost from the system. This energy criterion leads to an overestimate of the stripped mass and an underestimate of the disruption time-scale, since CDM haloes are strongly bound in their inner parts. We show that a significant fraction of material from CDM microhaloes can be unbound by encounters with Galactic substructure and stars; however, the cuspy central regions remain relatively intact. Furthermore, the microhaloes near the solar radius are those which collapse significantly earlier than average and will suffer very little mass-loss. Thus, we expect a fraction of surviving bound microhaloes, a smooth component with narrow features in phase space, which may be uncovered by direct detection experiments, as well as numerous surviving cuspy cores with proper motions of arcminutes per year, which can be detected indirectly via their annihilation into gamma-rays.     

Effects of Dispersion of Wave Packets in the Determination of Lifetimes of High-Degree Solar <Emphasis Type="Italic">p</Emphasis> Modes from Time – Distance Analysis: MDI Data

The cross-correlation function of solar p modes in a time – distance analysis changes with travel distance (or travel time). The exponential decrease in the amplitude of the cross-correlation function with travel distance has been interpreted as the dissipation of solar p-mode power and used to determine the lifetimes of high-degree p modes. It is found that the width of the cross-correlation function increases with travel distance. We interpret the increase in width as the dispersion of the wave packet in a time – distance analysis. The dispersion would also cause a decrease in amplitude and affect the determination of lifetimes. We include the dispersion effect in the determination of lifetimes of high-degree p modes in a time – distance analysis and find that the derived lifetime increases significantly compared with the previous study for degree less than 400.     

Surface properties, solubility and dissolution kinetics of bamboo phytoliths

Although phytoliths, constituted mainly by micrometric opal, exhibit an important control on silicon cycle in superficial continental environments, their thermodynamic properties and reactivity in aqueous solution are still poorly known. In this work, we determined the solubility and dissolution rates of bamboo phytoliths collected in the Réunion Island and characterized their surface properties via electrophoretic measurements and potentiometric titrations in a wide range of pH. The solubility product of “soil” phytoliths ( at 25 °C) is equal to that of vitreous silica and is 17 times higher than that of quartz. Similarly, the enthalpy of phytoliths dissolution reaction is close to that of amorphous silica but is significantly lower than the enthalpy of quartz dissolution. Electrophoretic measurements yield isoelectric point pH_IEP = 1.2 ± 0.1 and 2.5 ± 0.2 for “soil” (native) and “heated” (450 °C heating to remove organic matter) phytoliths, respectively. Surface acid-base titrations allowed generation of a 2-pK surface complexation model. Phytoliths dissolution rates, measured in mixed-flow reactors at far from equilibrium conditions at 2 ? pH ? 12, were found to be intermediate between those of quartz and vitreous silica. The dissolution rate dependence on pH was modeled within the concept of surface coordination theory using the equation:

     

New operational method of testing colloid complexation with metals in natural waters

A dialysis procedure was used to assess the distribution coefficients of ∼50 major and trace elements (TEs) between colloidal (1 kDa–0.22 μm) and truly dissolved (<1 kDa) phases in Fe- and organic-rich boreal surface waters. These measurements allowed quantification of both TE partitioning coefficients and the proportion of colloidal forms as a function of solution pH (from 3 to 8). Two groups of elements can be distinguished according to their behaviour during dialysis: (i) elements which are strongly associated with colloids and exhibit significant increases of relative proportion of colloidal forms with pH increase (Al, Ba, Cd, Co, Cr, Cu, Fe, Ga, Hf, Mn, Ni, Pb, rare earth elements (REEs), Sr, Th, U, Y, Zn, Zr and dissolved organic C) and (ii) elements that are weakly associated with colloids and whose distribution coefficients between colloidal and truly dissolved phases are not significantly affected by solution pH (As, B, Ca, Cs, Ge, K, Li, Mg, Mo, Na, Nb, Rb, Sb, Si, Sn, Ti, V). Element speciation was assessed using the Visual MINTEQ computer code with an implemented NICA-Donnan humic ion binding model and database. The model reproduces quantitatively the pH-dependence of colloidal form proportion for alkaline-earth (Ba, Ca, Mg, Sr) and most divalent metals (Co, Cd, Mn, Ni, Pb, Zn) implying that the complexation of these metals with low molecular weight organic matter (<1 kDa fraction) is negligible. In contrast, model prediction of colloidal proportion (fraction of 1 kDa–0.22 μm) of Cu²⁺ and all trivalent and tetravalent metals is much higher than that measured in the experiment. This difference may be explained by (i) the presence of strong metal-binding organic ligands in the <1 kDa fraction whose stability constants are several orders of magnitude higher than those of colloidal humic and fulvic acids and/or (ii) coprecipitation of TE with Fe(Al) oxy(hydr)oxides in the colloidal fraction, whose dissolution and aggregation controls the pH-dependent pattern of TE partitioning. Quantitative modeling of metal – organic ligand complexation and empirical distribution coefficients corroborate the existence of two colloidal pools, formerly reported in boreal surface waters: “classic” fulvic or humic acids binding divalent transition metals and alkaline-earth elements and large-size organo-ferric colloids transporting insoluble trivalent and tetravalent elements.     

Late Holocene diatom assemblages in a lake-sediment core from Central Kamchatka,Russia

Fossil diatom assemblages in a sediment core from a small lake in Central Kamchatka (Russia) were used to reconstruct palaeoenvironmental conditions of the late Holocene. The waterbody may be a kettle lake that formed on a moraine of the Two-Yurts Lake Valley, located on the eastern slope of the Central Kamchatka Mountain Chain. At present, it is a seepage lake with no surficial outflow. Fossil diatom assemblages show an almost constant ratio between planktonic and periphytic forms throughout the record. Downcore variations in the relative abundances of diatom species enabled division of the core into four diatom assemblage zones, mainly related to changes in abundances of Aulacoseira subarctica, Stephanodiscus minutulus, and Discostella pseudostelligera and several benthic species. Associated variations in the composition and content of organic matter are consistent with the diatom stratigraphy. The oldest recovered sediments date to about 3220 BC. They lie below a sedimentation hiatus and likely include reworked deposits from nearby Two-Yurts Lake. The initial lake stage between 870 and 400 BC was characterized by acidic shallow-water conditions. Between 400 BC and AD 1400, lacustrine conditions were established, with highest contributions from planktonic diatoms. The interval between AD 1400 and 1900 might reflect summer cooling during the Little Ice Age, indicated by diatoms that prefer strong turbulence, nutrient recycling and cooler summer conditions. The timing of palaeolimnological changes generally fits the pattern of neoglacial cooling during the late Holocene on Kamchatka and in the neighbouring Sea of Okhotsk, mainly driven by the prevailing modes of regional atmospheric circulation.     

Heat transport by groundwater flow during the Baikal rift evolution

A two-dimensional modelling study of sedimentation, fluid flow, and heat flow in the Baikal rift basin undergoing flank uplift and basin subsidence has been performed in order to understand the impact of these processes on the surface heat flow signal. Heat flow anomalies of different scales and magnitudes have been observed at the sediment surface of the lake Baikal basin, and the presence of a hydrothermal vent suggests that fluids play an important role in the regional distribution of heat flow. The BASIN-code applied for this study allows to simulate topographically and compaction-driven hydrodynamical fluid flow and coupled heat transfer.The flank uplift history provides the basis for a regional groundwater circulation towards the central basin area, with predicted Darcy velocities at present-day situation in the basement varying between 1 and 100 cm/year. Within the basin, the presence of aquifers and the pinch-out layering has a major control on the flow field, and compaction-driven flow velocities are strongly altered when combined with topography-driven flow. When velocities in the basement are larger than several centimeters per year, the regional fluid circulation is an effective mechanism of heat redistribution. Heat is brought from the flanks towards the basin area, with largest heat transported at a depth of 1–2 km at both sides. During the flank uplift, heat advection increases, with secondary variation related to the deposition of sedimentary layers. The heat flow is increased over the basin and reduced in the flanks, with a total heat output balance always positive. The extra heat output over the modelled transection is 2–10% of the initial heat output. The maximum computed heat fluxes are smaller than measured in the heat flow anomalies of the lake Baikal basin. Nevertheless, the model suggests that flow in the sedimentary basin combined with a topographically driven heat advection in the surrounding basement is a sufficient mechanism to account for the increased heat flow over the basin and the main features of the heat flow distribution.     

SENSITIVITY OF THE RUSSIAN AGRICULTURE TO CHANGES IN CLIMATE, CO2 AND TROPOSPHERIC OZONE CONCENTRATIONS AND SOIL FERTILITY

Russian agriculture sensitivity to changes in climate, soil and atmosphere chemistry were analyzed. Calculated data are presented on crop productivity of grain crops and grasses (C₃) under arid and humid scenarios of climate taking account of one-, two-, three and four-factor natural environment impacts. All four factors under studies (climatic parameters, CO₂ and tropospheric ozone concentrations, soil degradation extent) greatly impact agriculture productivity. The effect of interaction between all considered factors on agroecosystem productivity is studied. It is established that a simple additive scheme for explaining the complex effect of some factors can be much violated. In this case, not only variations in the mean crop yield levels but also variations in the degree of crop stability have been assessed in some regions, that may be more important for determining the social-economic consequences. It turned out that the recurrence of critically very low yields in steppe regions may increase two fold as a result of global warming.     

Multiphase flow modeling with density functional method

This paper is a review of applications of density functional theory (DFT) in compositional hydrodynamics. The basic idea is representation of the entropy or the Helmholtz energy of the mixture as the functional depending on the molar densities of chemical components (density functional). The hydrodynamics is governed by local conservation laws of chemical components, momentum, and energy, while constitutive relations and boundary conditions are introduced in accordance with the explicit form of the density functional. The general ideas and the history of the DFT in compositional hydrodynamics are discussed. Then the DFT for multiphase multicomponent mixtures is presented including the exposition of the first principles, governing equations and constitutive relations, and explicit expressions of density functional depending on physical situation. The DFT-based numerical simulator is described, and several multiphase simulation results are presented to illustrate the scope and effectiveness of DFT: sessile drop with and without surfactant, droplet breakup in shear flow, and three-phase hydrodynamics with mobile solid phase. Also, two practical scenarios with multiphase simulations in micro-CT porous rock models are presented: two-phase immiscible water-oil flow and three-phase water-gas-condensate flow with phase transitions. All numerical results are obtained by essentially the same code; both the number of chemical components and the Helmholtz energy have been set up in accordance with physical situation.