Complex geographical analysis of the Greater Sochi region on the Black Sea coast

Results of the complex analysis of the unique natural territory of Greater Sochi from the point of view of physical geography are considered. The region of Greater Sochi is located on the S slopes of the Main Caucasus chain on the eastern coast of the Black Sea. Morphometrical analysis of the relief and analysis air surface temperature and precipitation allowed to distinguish four specific subregions within the whole territory. It is demonstrated that the period of stable snow cover in the two subregions which occupy more than half of the region's area is sufficient for successful development of winter tourism. Peculiar combination of the mild climate of the coast with stable snow cover in the mountains till the beginning of summer provide strong attractivity of the region for all-the-year-round tourists inflow to the most modern recreational centre of Russia. The work provides the methodology for similar studies.     

东昆仑南缘早三叠世洪水川组的源区特征:来自碎屑组成、重矿物和岩石地球化学的证据

分布于东昆仑南缘的早三叠世洪水川组系一套由砾岩、砂岩、页岩和鲕粒灰岩等浅海相和河流相沉积物构成的弧前盆地沉积组合.砂岩碎屑组成、重矿物组合、岩石地球化学和古水流综合研究结果表明,洪水川组砂岩物源主要来自于北侧的岛弧带,同时南侧的阿尼玛卿蛇绿混杂带也为其形成提供了部分物源;源区主要出露长英质岩石、变质岩和硅质岩.     

The surface chemistry of multi-oxide silicates

The surface chemistry of natural wollastonite, diopside, enstatite, forsterite, and albite in aqueous solutions was characterized using both electrokinetic techniques and surface titrations performed for 20 min in batch reactors. Titrations performed in such reactors allow determination of both proton consumption and metal release from the mineral surface as a function of pH. The compositions, based on aqueous solution analysis, of all investigated surfaces vary dramatically with solution pH. Ca and Mg are preferentially released from the surfaces of all investigated divalent metal silicates at pH less than ∼8.5-10 but preferentially retained relative to silica at higher pH. As such, the surfaces of these minerals are Si-rich and divalent metal poor except in strongly alkaline solutions. The preferential removal of divalent cations from these surfaces is coupled to proton consumption. The number of protons consumed by the preferential removal of each divalent cation is pH independent but depends on the identity of the mineral; ∼1.5 protons are consumed by the preferential removal of each Ca atom from wollastonite, ∼3 protons are consumed by the preferential removal of each Mg or Ca atom from diopside or enstatite, and ∼4 protons are consumed by the preferential removal of each Mg from forsterite. These observations are interpreted to stem from the creation of additional ‘internal’ adsorption sites by the preferential removal of divalent metal cations which can be coupled to the condensation of partially detached Si. Similarly, Na and Al are preferentially removed from the albite surface at 2 > pH > 11; mass balance calculations suggest that three protons are consumed by the preferential removal of each Al atom from this surface over this entire pH range. Electrokinetic measurements on fresh mineral powders yield an isoelectric point (pH_IEP) 2.6, 4.4, 3.0, 4.5, and <1, for wollastonite, diopside, enstatite, forsterite, and albite, respectively, consistent with the predominance of SiO₂ in the surface layer of all of these multi-oxide silicates at acidic pH. Taken together, these observations suggest fundamental differences between the surface chemistry of simple versus multi-oxide minerals including (1) a dependency of the number and identity of multi-oxide silicate surface sites on the aqueous solution composition, and (2) the dominant role of metal-proton exchange reactions on the reactivity of multi-oxide mineral surfaces including their dissolution rate variation with aqueous solution composition.     

Estimated SLR station position and network frame sensitivity to time-varying gravity

This paper evaluates the sensitivity of ITRF2008-based satellite laser ranging (SLR) station positions estimated weekly using LAGEOS-1/2 data from 1993 to 2012 to non-tidal time-varying gravity (TVG). Two primary methods for modeling TVG from degree-2 are employed. The operational approach applies an annual GRACE-derived field, and IERS recommended linear rates for five coefficients. The experimental approach uses low-order/degree $4\times 4$ coefficients estimated weekly from SLR and DORIS processing of up to 11 satellites (tvg4x4). This study shows that the LAGEOS-1/2 orbits and the weekly station solutions are sensitive to more detailed modeling of TVG than prescribed in the current IERS standards. Over 1993–2012 tvg4x4 improves SLR residuals by 18 % and shows 10 % RMS improvement in station stability. Tests suggest that the improved stability of the tvg4x4 POD solution frame may help clarify geophysical signals present in the estimated station position time series. The signals include linear and seasonal station motion, and motion of the TRF origin, particularly in Z. The effect on both POD and the station solutions becomes increasingly evident starting in 2006. Over 2008–2012, the tvg4x4 series improves SLR residuals by 29 %. Use of the GRGS RL02 $50\times 50$ series shows similar improvement in POD. Using tvg4x4, secular changes in the TRF origin Z component double over the last decade and although not conclusive, it is consistent with increased geocenter rate expected due to continental ice melt. The test results indicate that accurate modeling of TVG is necessary for improvement of station position estimation using SLR data.     

Spectrum of hot water in the 4750–13 000 cm−1 wavenumber range (0.769–2.1 μm)

The high resolution laboratory spectrum of hot water vapour has been recorded in the 500–13 000 cm⁻¹ wavenumber range and we report on the analysis of the 4750–13 000 cm⁻¹ (0.769–2.1 μm) portion. The emission spectrum was recorded using an oxy-acetylene welding torch and a Fourier transform spectrometer. Line assignments in the laboratory spectrum as well as in an absorption spectrum of a sunspot umbra were made with the help of the BT2 line-list. Our torch spectrum is the first laboratory observation of the 9300 Å'steam bands' seen in M-stars and brown dwarfs.     

Vertical profiling of SO2 and SO above Venus’ clouds by SPICAV/SOIR solar occultations

New measurements of sulfur dioxide (SO₂) and monoxide (SO) in the atmosphere of Venus by SPICAV/SOIR instrument onboard Venus Express orbiter provide ample statistics to study the behavior of these gases above Venus’ clouds. The instrument (a set of three spectrometers) is capable to sound atmospheric structure above the clouds in several observation modes (nadir, solar and stellar occultations) either in the UV or in the near IR spectral ranges. We present the results from solar occultations in the absorption ranges of SO₂ (190–230 nm, and at 4 μm) and SO (190–230 nm). The dioxide was detected by the SOIR spectrometer at the altitudes of 65–80 km in the IR and by the SPICAV spectrometer at 85–105 km in the UV. The monoxide’s absorption was measured only by SPICAV at 85–105 km. We analyzed 39 sessions of solar occultation, where boresights of both spectrometers are oriented identically, to provide complete vertical profiling of SO₂ of the Venus’ mesosphere (65–105 km). Here we report the first firm detection and measurements of two SO₂ layers. In the lower layer SO₂ mixing ratio is within 0.02–0.5 ppmv. The upper layer, also conceivable from microwave measurements by Sandor et al. (Sandor, B.J., Todd Clancy, R., Moriarty-Schieven, G., Mills, F.P. [2010]. Icarus 208, 49–60) is characterized by SO₂ increasing with the altitude from 0.05 to 2 ppmv, and the [SO₂]/[SO] ratio varying from 1 to 5. The presence of the high-altitude SO_x species could be explained by H₂SO₄ photodissociation under somewhat warmer temperature conditions in Venus mesosphere. At 90–100 km the content of the sulfur dioxide correlates with temperature increasing from 0.1 ppmv at 165–170 K to 0.5–1 ppmv at 190–192 K. It supports the hypothesis of SO₂ production by the evaporation of H₂SO₄ from droplets and its subsequent photolysis at around 100 km.