Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong

Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources.     

Mineral distribution and feldspar weathering in a saprolite from northeastern Nigeria

Mineral composition was analysed within a saprolite profile from NE Nigeria. The determination of identifiable feldspar phases is only based on X-ray powder diffractograms. Representative K-feldspar fragments were selected for detailed SEM (scanning electron microscope) studies and EDX (energy-dispersive X-ray analysis) from the profile.

The analytical data indicate a significant contrast in weathering states between the lower and the upper profile section. This contrast reflects a different weathering history: the feldspars from the lower section exhibit weathering features that are characteristic for decomposition below the water table. When raised above the water table, another type of decomposition attacked only the feldspars within the upper section while those in the lower section still preserve the older weathering state.     

Amorphous copper and zinc sulfides in the metalliferous sediments of the Red Sea

Detailed studies on the copper and zinc distribution in metalliferous sediments from the Atlantis II Deep (Red Sea) demonstrate that beside chalcopyrite and sphalerite appreciable amounts of copper and zinc are found in X-ray amorphous copper and zinc sulfides not previously described. Only low contents of copper and zinc are present in nontronites, hydroxides and carbonates.     

Nitratbestimmung im Trinkwasser nach dem flow-stream-Prinzip mittels einer ionensensitiven Meßzelle

Beschrieben wird eine automatisierte Methode zur Bestimmung des Nitrats in Trinkwässern mittels einer ionensensitiven Meßzelle. Mit dem vorgestellten Verfahren können 80 Proben pro Stunde auf ihren Nitratgehalt im Konzentrationsbereich von 1,5 · 10^–5 bis 1,0 · 10^–3 Mol/l analysiert werden. Der Aufbau der Automateneinheit, der Durchflußmeßzelle, sowie das Meßprinzip weiden erläutert.     

Weathering characteristics of arctic islands in northern Norway

The arctic islands of the Lofoten-Vesterålen archipelago in northern Norway have a wide distribution of weathered land surfaces commonly located above 250 m with several apparent similarities. In order to investigate the characteristics of (deep) weathering in this region, northern Langøya and Hadseløya were chosen for in-depth analyses. Eight weathering profiles were excavated from various surfaces, and the stratigraphies were logged in detail. Material was collected throughout the weathering horizons, and all samples were subsequently analysed for clay mineralogy (< 63 μm fraction) and grain size distribution. The sampling strategy was complemented by samples from additional saprolites and other landforms such as moraines and rock glaciers. The XRD results indicate that the presence of secondary minerals, such as gibbsite (Al(OH)₃) and kaolinite (Al₂Si₂O₅(OH)₄), are very common throughout the profiles. Gibbsite is an extreme end product of silicate weathering and usually associated with a warmer and more humid climate, as found in Scandinavia during the Tertiary. The grain size analyses (< 63 μm) show that the finer silt fractions (< 8 μm) tend to be high in the profiles (20–40%), with significant amounts of clay (5–15%) demonstrating that the regolith itself is susceptible to frost sorting mechanisms.¹⁰Be exposure dates from in situ quartz knobs on tors and boulders of local origin suggest > 40,000 years of subaerial conditions. Considering the steady surface erosion, this figure should be viewed as an absolute minimum age estimate. Mapping of the superficial sediments and geomorphological features of the study areas has revealed several common morphological features, which indicate dominance of glacial and periglacial processes in the areas lying below the lower boundary of blockfields (c. 250 m). The weathering mantles are not a periglacial end product, but rather a relict tertiary landform that were modulated by permafrost processes as well as biological processes at later stages. The regolith cover constrain the vertical extension of warm-based Quaternary ice sheets challenging the notion of a parabolic ice mass consuming every mountain top of Lofoten and Vesterålen.     

Cycling of trace metals (Mn, Fe, Mo, U, V, Cr) in deep pore waters of intertidal flat sediments

Trace metals (Mn, Fe, Mo, U, Cr, V) were studied in pore waters of an intertidal flat located in the German Wadden Sea. The study system is an example of a permeable tidal flat system where pore water exchange is affected by tidal driven pressure gradients besides diffusion. Permanently installed in situ samplers were used to extract pore waters down to 5 m depth throughout one year. The samplers were either located close to the tidal flat margin or in central parts of the tidal flat. Despite dynamic sedimentological and hydrological conditions, the general trends with depth in deep tidal flat pore waters are remarkably similar to those observed in deep sea environments. Rates of trace metal cycling must be comparably large in order to maintain the observed pore water profiles. Trace metals further show similar general trends with depth close to the margin and in central parts of the tidal flat. Seasonal sampling revealed that V and Cr vary concurrent with seasonal changes in dissolved organic carbon (DOC) concentration. This effect is most notable close to the tidal flat margin where sulphate, DOC, and nutrients vary with season down to some metres depth. Seasonal variations of Mn, Fe, Mo, and U are by contrast limited to the upper decimetres of the sediment. Their seasonal patterns depend on organic matter supply, redox stratification, and particulate matter deposited on sediment surfaces. Pore water sampling within one tidal cycle provides evidence for pore water advection in margin sediments. During low tide pore water flow towards the creekbank is generated by a hydraulic gradient suggesting that deep pore waters may be seeping out of creekbank sediments. Owing to the enrichment of specific elements like Mn in pore water compared to sea water, seeping pore waters may have an impact on the chemistry of the open water column. Mass balance calculations reveal that the impact of deep pore waters on the Mn budget in the open water column is below 4%. Mn deep pore water discharge of the whole Wadden Sea is estimated to be about 9% of the total dissolved riverine Mn input into the Southern North Sea.     

Modeling reactive transport in non-ideal aqueous–solid solution system

The numerical simulation of reactive mass transport processes in complex geochemical environments is an important tool for the performance assessment of future waste repositories. A new combination of the multi-component mass transport code GeoSys/RockFlow and the Gibbs Energy Minimization (GEM) equilibrium solver GEM-Selektor is used to calculate the accurate equilibrium of multiple non-ideal solid solutions which are important for the immobilization of radionuclides such as Ra. The coupled code is verified by a widely used benchmark of dissolution–precipitation in a calcite–dolomite system. A more complex application shown in this paper is the transport of Ra in the near-field of a nuclear waste repository. Depending on the initial inventories of Sr, Ba and sulfate, non-ideal sulfate and carbonate solid solutions can fix mobile Ra cations. Due to the complex geochemical interactions, the reactive transport simulations can describe the migration of Ra in a much more realistic way than using the traditional linear K_D approach only.     

Identification of high energy gamma-ray sources and source populations in the era of deep all-sky coverage

A large fraction of the anticipated source detections by the Gamma-ray Large Area Space Telescope (GLAST-LAT) will initially be unidentified. We argue that traditional approaches to identify individuals and/or populations of gamma ray sources will encounter procedural limitations. Those limitations are discussed on the background of source identifications from EGRET observations. Generally, our ability to classify (faint) source populations in the anticipated GLAST dataset with the required degree of statistical confidence will be hampered by sheer source wealth. A new paradigm for achieving the classification of gamma ray source populations is discussed.     

INTEGRAL/XMM views on the MeV source GRO J1411-64

The COMPTEL unidentified source GRO J 1411-64 was observed by INTEGRAL and XMM-Newton in 2005. The Circinus Galaxy is the only source detected within the 4σ location error of GRO J1411-64, but in here excluded as the possible counterpart. At soft X-rays, 22 reliable and statistically significant sources (likelihood >10) were extracted and analyzed from XMM-Newton data. Only one of these sources, XMMU J141255.6-635932, is spectrally compatible with GRO J1411-64 although the fact the soft X-ray observations do not cover the full extent of the COMPTEL source position uncertainty make an association hard to quantify and thus risky. At the best location of the source, detections at hard X-rays show only upper limits, which, together with MeV results obtained by COMPTEL suggest the existence of a peak in power output located somewhere between 300–700 keV for the so-called low state. Such a spectrum resembles those in blazars or microquasars, and might suggest at work by the models accordingly. However, an analysis using a microquasar model consisting on a magnetized conical jet filled with relativistic electrons, shows that it is hard to comply with all observational constrains. This fact and the non-detection at hard X-rays introduce an a-posteriori question mark upon the physical reality of this source, what is discussed here.     

Autochthonous block fields in southern Norway: Implications for the geometry,thickness, and isostatic loading of the Late Weichselian Scandinavian ice sheet

The consistent geographical and altitudinal distribution of autochthonous block fields (mantle of bedrock weathered in situ) and trimlines in southern Norway suggests a multi-domed and asymmetric Late Weichselian ice sheet. Low-gradient ice-sheet profiles in the southern Baltic region, in the North Sea, and along the outer fjord areas of southern Norway, are best explained by movement of ice on a bed of deforming sediment, although water lubricated sliding or a combination of the two, may not be excluded. The ice-thickness distribution of the Late Weichselian Scandinavian ice sheet is not in correspondence with the modern uplift pattern of Fennoscandia. Early Holocene crustal rebound was apparently determined by an exponential, glacio-isostatic rise. Later, however, crustal movements appear to have been dominated by large-scale tectonic uplift of the Fennoscandian Shield, centred on the Gulf of Bothnia, the region of maximum lithosphere thickness.