Effects of natural and calcined poultry waste on Cd, Pb and As mobility in contaminated soil

The reuse of waste materials as soil additives could be a welcome development in soil remediation. The mobility of Cd, Pb and As in a contaminated soil was investigated using natural and calcined poultry wastes (eggshell and chicken bone), CaCO₃ and CaO at different application rates (0, 1, 3 and 5 %). The chemical composition accompanied with mineralogical composition indicated that CaCO₃ and CaO were the major components in natural and calcined eggshells, respectively, while hydroxyapatite (HAP) dominated the natural and calcined chicken bones. The results showed that soil pH tended to increase in response to increasing application rates of all soil additives. The effectiveness of the additives in reducing Cd, Pb and As mobility was assessed by means of chemical extractions with 0.1 N HCl for Cd and Pb or 1 N HCl for As, according to Korean Standard Test (KST) method. Both calcined eggshell and chicken bone were equally effective with CaO or CaCO₃ in reducing the concentration of 0.1 N HCl-extractable Cd from 6.17 mg kg^?1 to below warning level of 1.5 mg kg^?1, especially at the highest application rate. The application of calcined eggshell, CaO and CaCO₃ also decreased the concentration of 0.1 N HCl-extractable Pb from 1,012 mg kg^?1 to below warning level of 100 mg kg^?1. The Pb concentration decreased significantly with an increasing application rate of chicken bone, but remained above warning level even at the highest application rate. On the contrary, natural and calcined chicken bones led to a significant increase in the mobility of As when compared with the control soil. These findings illustrate that calcined eggshell in particular is equally effective as pure chemical additives in stabilizing Cd and Pb in a contaminated agricultural soil. The presence of As in metal-contaminated soils should be taken into consideration when applying phosphate-containing materials as soil additives, because phosphate can compete with arsenate on adsorption sites and result in As mobilization.     

Study on the kinetics of iron oxide leaching by oxalic acid

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.     

The effect of mineralogy on the mobility of heavy metals in mine tailings: a case study in the Samsanjeil mine,Korea

This study examined the chemical speciation and mobility of As and heavy metals in a tailings impoundment in Samsanjeil mine located in Gosung, Korea, as well as the factors affecting them. XRD, SEM, and 5-step sequential extraction were used to examine the samples at two sampling sites (NN and SN sites). The pH of the tailings decreased with increasing depth at the NN site (from 7.2 to 2.8), whereas no significant differences were observed at the SN site (8.1–8.8). The samples at the SN site showed a larger amount of calcite than those at the NN site, indicating that calcite plays an important role buffering the pH in the study sites. Jarosite was found only at the lower part of the NN site, where calcite was not found. The mineralogical observation of jarosite and calcite was also confirmed by SEM. The concentrations of As and heavy metals in the tailings were as follows: Cu > As > Zn > > Pb > Co > Cr > Ni > Cd. The total concentrations of Ni, Zn, Co, and Cd were higher at the SN site than those at the NN site. On the other hand, the concentrations of As and Cr existing as oxyanions were higher at the NN site, which can be explained by the mobility changes of those elements affected by pH variations. At the NN site, the fractions of heavy metals bound to the Fe/Mn oxides, except for As and Cr, decreased, and Cu, Zn, and Co showed an increasing fraction of exchangeable metals with increasing depth. This suggests that the pH and resulting surface charge of minerals, such as goethite and jarosite, are the dominant factors controlling the chemical speciation of metals. These results highlight the importance of mineralogy in controlling the mobility and possible bioavailability of heavy metals in tailings.     

Natural disasters as the end of the insurance industry? Scalar competitive strategies, Alternative Risk Transfers, and the economic crisis

The aftermath of Hurricane Katrina has piqued interest in the insurance industry, and this scrutiny has led to assumptions that the industry has become unstable and unprofitable with the increased incidence of disasters in highly-insured regions of the world. This paper challenges that assumption by arguing that the insurance industry has responded by spreading risk through scaled and networked recovery schemes. We found that because of competitive strategies of risk-spreading and displacement arrangements, the industry has actually profited as a whole. Regional insurance companies have always relied on the higher financial scales of the reinsurance industry in Munich, Zurich, and London. But with claims reaching into the billions of dollars, the reinsurance industry itself has raised premiums, spread risk farther afield, and jumped scale by spreading risk to futures markets called Alternative Risk Transfers (ARTs). However, the recession beginning in 2008 has called into question the viability of using futures markets as insurance. It is shown through a media analysis of four major business publications (The Economist, The New York Times, The Financial Times and The Wall Street Journal) how the industry responded to the costs of the 2004, 2005, and 2006 hurricane seasons. Because geography is rather new to this literature, this paper also offers a broad review of the insurance industry.     

Estimation of soil weathering degree using electrical resistivity

In this study, the electrical resistivity of soil having different chemical weathering index (CWI) was measured, and the correlation between CWI and the electrical resistivity was estimated. The electrical resistivity of soil varies with CWI of soil. The difference in the electrical resistivities of soils having different weathering degrees is clear at lower water contents. At the volumetric water contents estimated in this study, CWI could be described by a linear equation of electrical resistivity with the constants related to the volumetric water content. The findings in this study suggest that the electrical resistivity could be used as an effective alternative for estimating the weathering degree of soil.     

Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

A case study for the integration of predictive mineral potential maps

This study aims to elaborate on the mineral potential maps using various models and verify the accuracy for the epithermal gold (Au) — silver (Ag) deposits in a Geographic Information System (GIS) environment assuming that all deposits shared a common genesis. The maps of potential Au and Ag deposits were produced by geological data in Taebaeksan mineralized area, Korea. The methodological framework consists of three main steps: 1) identification of spatial relationships 2) quantification of such relationships and 3) combination of multiple quantified relationships. A spatial database containing 46 Au-Ag deposits was constructed using GIS. The spatial association between training deposits and 26 related factors were identified and quantified by probabilistic and statistical modelling. The mineral potential maps were generated by integrating all factors using the overlay method and recombined afterwards using the likelihood ratio model. They were verified by comparison with test mineral deposit locations. The verification revealed that the combined mineral potential map had the greatest accuracy (83.97%), whereas it was 72.24%, 65.85%, 72.23% and 71.02% for the likelihood ratio, weight of evidence, logistic regression and artificial neural network models, respectively. The mineral potential map can provide useful information for the mineral resource development.     

A study on the sociospatial context of ethnic politics and entrepreneurial growth in Koreatown and Monterey Park

The study examines the various sociospatial features of immigrant populations in two transnationally-linked ethnic enclaves in terms of how they may facilitate and constrain the politics of growth and development. In recent decades, the growing ethnic enclave economies of Koreatown and Monterey Park have witnessed the emergence of progrowth ethnic interest groups comprised of immigrant capitalists, entrepreneurs, developers, and organizations, who are playing key roles in politically spearheading (re)development projects in the Los Angeles metropolitan area. Our aim is to understand how the sociospatial, entrepreneurial, and residential layout of these host municipalities set the context for the politics of growth in these ethnic enclave economies based on an analysis of GIS spatial mapping, 2000–2010 census data, and other secondary sources. The data suggests that Korean and Chinese elite face different political opportunities and challenges because of their different sociospatial characteristics—the former based on their greater entrepreneurial influence and weak electoral impact and the latter on their stronger political presence as residents.     

Characterization of Effective Parameters in Abrasive Waterjet Rock Cutting

The rock cutting performance of an abrasive waterjet is affected by various parameters. In this study, rock cutting tests are conducted with different energy (i.e., water pressure, traverse speed, and abrasive feed rate), geometry (i.e., standoff distance), and material parameters [i.e., uniaxial compressive strength (UCS)]. In particular, experimental tests are carried out at a long standoff distance (up to 60 cm) to consider field application. The effective parameters of the rock cutting process are identified based on the relationships between the cutting performance indices (depth, width, and volume) and parameters. In addition, the cutting efficiency is analyzed with effective parameters as well as different pump types and the number of cutting passes considering the concept of kinetic jet energy. Efficiency analysis reveals that the cutting depth efficiency tends to increase with an increase in the water pressure and traverse speed and with a decrease in the standoff distance and UCS. Cutting volume efficiency strongly depends on standoff distance. High efficiency of cutting volume is obtained at a long standoff distance regardless of the pump type. The efficiency analysis provides a realistic way to optimize parameters for abrasive waterjet rock excavation.