Contribution of long-term hydrothermal experiments for understanding the smectite-to-chlorite conversion in geological environments

The smectite-to-chlorite conversion is investigated through long-duration experiments (up to 9 years) conducted at 300 °C. The starting products were the Wyoming bentonite MX80 (79 % smectite), metallic iron and magnetite in contact with a Na–Ca chloride solution. The predominant minerals in the run products were an iron-rich chlorite (chamosite like) and interstratified clays interpreted to be chlorite/smectite and/or corrensite/smectite, accompanied by euhedral crystals of quartz, albite and zeolite. The formation of pure corrensite was not observed in the long-duration experiments. The conversion of smectite into chlorite over time appears to take place in several steps and through several successive mechanisms: a solid-state transformation, significant dissolution of the smectite and direct precipitation from the solution, which is over-saturated with respect to chlorite, allowing the formation of a chamosite-like mineral. The reaction mechanisms are confirmed by X-ray patterns and data obtained on the experimental solutions (pH, contents of Si, Mg, Na and Ca). Because of the availability of some nutrients in the solution, total dissolution of the starting smectite does not lead to 100 % crystallization of chlorite but to a mixture of two dominant clays: chamosite and interstratified chlorite/smectite and/or corrensite/smectite poor in smectite. The role of Fe/(Fe + Mg) in the experimental medium is highlighted by chemical data obtained on newly formed clay particles alongside previously published data. The newly formed iron-rich chlorite has the same composition as that predicted by the geothermometer for diagenetic to low-grade metamorphic conditions, and the quartz + Fe-chlorite + albite experimental assemblage in the 9-year experiment is close to that fixed by water–rock equilibrium.     

A fast computation of the diurnal secondary ion production in the ionosphere of Titan

We propose an analytic model that allows rapid computation of the secondary ion production due to electron impact from the primary photo-production in the ionosphere of Titan. The model parameters are given for each of the 5 major ion productions (N⁺₂, CH⁺₄, N⁺, CH⁺₃, N⁺⁺₂) as well as for the electron production.     

Climatic oscillations in central Italy during the Last Glacial–Holocene transition: the record from Lake Accesa

This paper presents an event stratigraphy based on data documenting the history of vegetation cover, lake‐level changes and fire frequency, as well as volcanic eruptions, over the Last Glacial–early Holocene transition from a terrestrial sediment sequence recovered at Lake Accesa in Tuscany (north‐central Italy). On the basis of an age–depth model inferred from 13 radiocarbon dates and six tephra horizons, the Oldest Dryas–Bølling warming event was dated to ca. 14 560 cal. yr BP and the Younger Dryas event to ca. 12 700–11 650 cal. yr BP. Four sub‐millennial scale cooling phases were recognised from pollen data at ca. 14 300–14 200, 13 900–13 700, 13 400–13 100 and 11 350–11 150 cal. yr BP. The last three may be Mediterranean equivalents to the Older Dryas (GI‐1d), Intra‐Allerød (GI‐1b) and Preboreal Oscillation (PBO) cooling events defined from the GRIP ice‐core and indicate strong climatic linkages between the North Atlantic and Mediterranean areas during the last Termination. The first may correspond to Intra‐Bølling cold oscillations registered by various palaeoclimatic records in the North Atlantic region. The lake‐level record shows that the sub‐millennial scale climatic oscillations which punctuated the last deglaciation were associated in central Italy with different successive patterns of hydrological changes from the Bølling warming to the 8.2 ka cold reversal. Copyright © 2006 John Wiley & Sons, Ltd.     

High-resolution simulations of the last glacial maximum climate over Europe: a solution to discrepancies with continental palaeoclimatic reconstructions?

The analyses of low-resolution models simulations of the last glacial maximum (LGM, 21 kyr BP) climate have revealed a large discrepancy between all the models and pollen-based palaeoclimatic reconstructions. In general, the models are too warm relative to the observations, especially in winter, where the difference is of the order of 10°C over western Europe. One of the causes of this discrepancy may be related to the low spatial resolution of these models. To assess the impact of using high-resolution models on simulated climate sensitivity, we use three approaches to obtain high-resolution climate simulations over Europe: first an atmospheric general circulation model (AGCM) with a stretched grid over Europe, second a homogeneous T106 AGCM (high resolution everywhere on the globe) and last a limited area model (LAM) nested in a low-resolution AGCM. With all three methods, we have performed simulations of the European climate for present and LGM conditions, according to the experimental design recommended by the Palaeoclimate Modeling Intercomparison Project (PMIP). Model results have been compared with updated pollen-based palaeoclimatic indicators for temperature and precipitation that were initially developed in PMIP. For each model, a low-resolution global run was also performed. As expected, the low-resolution simulations underestimate the large cooling indicated by pollen data, especially in winter, despite revised slightly warmer reconstructions of the temperatures of the coldest month, and show results in the range of those obtained in PMIP with similar models. The two high-resolution AGCMs do not improve the temperature field and cannot account for the discrepancy between model results and data, especially in winter. However, they are able to reproduce trends in precipitation more closely than their low-resolution counterparts do, but the simulated climates are still not as arid as depicted by the data. Conversely, the LAM temperature results compare well with climate reconstructions in winter but the simulated hydrological cycle is not consistent with the data. Finally, these results are discussed in regard of other possible causes for discrepancies between models and palaeoclimatic reconstructions for the LGM European climate.     

Proposal for a poverty-adaptation-mitigation window within the Green Climate Fund

The stakes for alleviating poverty and avoiding unbridled climate change are inextricably linked. Climate change impacts will slow down and may even reverse trends in poverty reduction. The pathways consistent with global warming of no more than 2?°C require strategies for poverty alleviation to make allowance for the constraint of low-carbon development. Existing climate funds have failed to target poverty alleviation as a high-priority strategy for adaptation or as a component of low-carbon development. This article proposes a funding window as part of the Green Climate Fund in order to foster synergies targeting greater satisfaction of basic needs, while making allowance for adaptation and mitigation. This financial mechanism is based on indicators of the satisfaction of basic needs and could respond to the claims of the developing countries, which see alleviating poverty as the first priority in climate negotiations. It defines a country continuum, given that there are poor people everywhere; all developing countries are therefore eligible with a mechanism of this sort.

Policy relevance

The Intergovernmental Panel on Climate Change (IPCC) calls for substantial emissions reductions and adaptation strategies over the next decades to reduce the high risks of severe impacts of climate change over the 21st century. Industrialized countries and developing countries alike recognize the need to mitigate climate change and to adapt to it. But they face many challenges that lead to an ‘emissions gap’ between an emissions level consistent with the 2?°C increase limit and the voluntary pledges that they have made thus far in the climate negotiations (United Nations Environment Programme. (2014). The Emissions Gap Report 2014. A UNEP synthesis report). In this arena, many developing countries underline that their first domestic priority is the satisfaction of basic needs. In the run-up to the next climate negotiations at the 21st Conference of the Parties (COP 21) in Paris, the proposed poverty-adaptation-mitigation funding window could contribute to alleviate the conflict between development and climate goals in developing countries. In this sense, it could spur developing countries to integrate more ambitious emissions limitations pledges into their Intended Nationally Determined Contributions. This could in turn entice industrialized countries to act similarly. In the end, it could pave the way to an ambitious climate agreement in Paris at COP 21.     

Implementing the Kyoto Protocol without Russia

Abstract

This paper examines implementation of the Kyoto Protocol without Russia. It concludes that implementation without Russia is possible, although it requires political will on the part of the countries that wish to proceed with the Protocol. It would lead to higher compliance costs for Annex B buyer regions, but other regions, except Russia, would benefit financially. Russia would forego revenue of at least $20 billion for the first commitment period. Implementation without Russia could improve the environmental performance of the Protocol. It would reduce reliance on Annex B sinks, use of surplus assigned amount units (AAUs) for compliance, and the quantity of Kyoto units banked for subsequent commitment periods. Actual emissions by Kyoto Protocol Parties would fall, but the reduction may be offset by leakage to the US and Russia.     

A Compilation of Silicon and Thirty One Trace Elements Measured in the Natural River Water Reference Material SLRS-4 (NRC-CNRC)

The natural river water certified reference material SLRS-4 (NRC-CNRC, National Research Council-Conseil National de Recherches Canada) has been routinely analysed for major and trace elements by six French laboratories. Most measurements were made using inductively coupled plasma-mass spectrometry. For silicon and thirty one trace elements (rare earth elements, Ag, B, Br, Cs, Ga, Ge, Li, P, Pd, Rb, Se, Th, Ti, Tl, W, Y and Zr), no certified values are assigned by NRC-CNRC. We propose some compilation values and related uncertainties according to the results obtained by the different laboratories.     

Pollen‐inferred palaeoclimate reconstruction in the Alps during the Lateglacial and the early Holocene: how to estimate the effect of elevation and local parameters

The modern analogue technique (MAT) was applied to six pollen sequences from the Belledonne Massif (northwestern French Alps) to estimate the effect of altitude and local parameters on pollen‐based climate reconstruction during the Lateglacial and the early Holocene. The six sites (Le Vivier (345 m a.s.l.), Les Etelles (700 m a.s.l.), La Coche (980 m a.s.l.), Montendry (1330 m a.s.l.), Le Grand Leyat (1660 m a.s.l.), La Gouille (1800 m a.s.l.)) are located in different vegetation belts (mixed deciduous woods, conifer woods, alpine pastures with maple). The main vegetation changes in the past are recorded at each site. The evolution of four climate parameters (coldest month temperature, warmest month temperature, mean annual temperature, annual precipitation) was quantitatively inferred from pollen data using MAT. The curves obtained were compared to the Les Etelles site, which was the least affected by non‐local pollen transport. The results show consistent trends for the climate parameters reconstructed at the different sites. However, the reconstruction does not indicate a decrease in temperature values related to the increasing elevation. Difficulties in reconstructing the altitudinal variations of climate parameters from pollen data during the periods studied are discussed and perspectives for improvement are considered. Copyright © 2009 John Wiley & Sons, Ltd.