In-situ measurement of dielectric parameter of soil at microwave frequencies

Knowledge of dielectric permittivity of the soil provides direct measure of soil moisture content. A methodology to determine soil moisture based on the reflection coefficient measurement by a pseudo vector method using a horn antenna has been presented. To verify the efficacy of the method, measurements have been carried out at S, C & X band frequencies at two moisture levels and the corresponding emissivity parameters computed. Results so obtained are in good agreement with the already reported data and the direct moisture measurements. This method is expected to be of interest to agricultural scientists and to those involved in the application of remote sensing in crop studies.     

Geodynamics of NW India: Subduction, lithospheric flexure, ridges and seismicity

Spectral analysis of digital data of the Bouguer anomaly map of NW India suggests maximum depth of causative sources as 134 km that represents the regional field and coincides with the upwarped lithosphere — asthenosphere boundary as inferred from seismic tomography. This upwarping of the Indian plate in this section is related to the lithospheric flexure due to its down thrusting along the Himalayan front. The other causative layers are located at depths of 33, 17, and 6 km indicating depth to the sources along the Moho, lower crust and the basement under Ganga foredeep, the former two also appear to be upwarped as crustal bulge with respect to their depths in adjoining sections. The gravity and the geoid anomaly maps of the NW India provide two specific trends, NW-SE and NE-SW oriented highs due to the lithospheric flexure along the NW Himalayan fold belt in the north and the Western fold belt (Kirthar -Sulaiman ranges, Pakistan) and the Aravalli Delhi Fold Belt (ADFB) in the west, respectively. The lithospheric flexures also manifest them self as crustal bulge and shallow basement ridges such as Delhi — Lahore — Sagodha ridge and Jaisalmer — Ganganagar ridge. There are other NE-SW oriented gravity and geoid highs that may be related to thermal events such as plumes that affected this region. The ADFB and its margin faults extend through Ganga basin and intersect the NW Himalayan front in the Nahan salient and the Dehradun reentrant that are more seismogenic. Similarly, the extension of NE-SW oriented gravity highs associated with Jaisalmer — Ganganagar flexure and ridge towards the Himalayan front meets the gravity highs of the Kangra reentrant that is also seismogenic and experienced a 7.8 magnitude earthquake in 1905. Even parts of the lithospheric flexure and related basement ridge of Delhi — Lahore — Sargodha show more seismic activity in its western part and around Delhi as compared to other parts. The geoid highs over the Jaisalmer — Ganganagar ridge passes through Kachchh rift and connects it to plate boundaries towards the SW (Murray ridge) and NW (Kirthar range) that makes the Kachchh as a part of a diffused plate boundary, which, is one of the most seismogenic regions with large scale mafic intrusive that is supported from 3-D seismic tomography. The modeling of regional gravity field along a profile, Ganganagar — Chandigarh extended beyond the Main Central Thrust (MCT) constrained from the various seismic studies across different parts of the Himalaya suggests crustal thickening from 35-36 km under plains up to ～56 km under the MCT for a density of 3.1 g/cm³ and 3.25 g/cm³ of the lower most crust and the upper mantle, respectively. An upwarping of ～3 km in the Moho, crust and basement south of the Himalayan frontal thrusts is noticed due to the lithospheric flexure. High density for the lower most crust indicates partial eclogitization that releases copious fluid that may cause reduction of density in the upper mantle due to sepentinization (3.25 g/cm³). It has also been reported from some other sections of Himalaya. Modeling of the residual gravity and magnetic fields along the same profile suggest gravity highs and lows of NW India to be caused by basement ridges and depressions, respectively. Basement also shows high susceptibility indicating their association with mafic rocks. High density and high magnetization rocks in the basement north of Chandigarh may represent part of the ADFB extending to the Himalayan front primarily in the Nahan salient. The Nahan salient shows a basement uplift of ～ 2 km that appears to have diverted courses of major rivers on either sides of it. The shallow crustal model has also delineated major Himalayan thrusts that merge subsurface into the Main Himalayan Thrust (MHT), which, is a decollment plane.     

An enhanced SMA based SCS-CN inspired model for watershed runoff prediction

Incorporation of initial soil moisture (V ₀) in the Soil Conservation Service Curve Number (SCS-CN) methodology helps to avoid the sudden jumps in Curve Number (CN) and, in turn, in computed runoff. It invoked the development of an enhanced (yet simple) Soil Moisture Accounting (SMA) procedure-based-SCS-CN inspired model, by incorporating initial moisture (V ₀). Its performance is tested using a dataset of 152 small to large watersheds of USDA (total 38,169 storm events), and compared with original SCS-CN method, Mishra and Singh (Acta Geophys Polon 50(3):457–477, 2002), Michel et al. (Water Resour Res 41(2):W02011, 2005) and Singh et al. (Water Resour Manag 29(11): 4111–4127, 2015) model using four statistical indices (RMSE, R ², PBIAS and NSE) and rank grading system (RGS). The proposed model scores highest (= 691 marks out of maximum 2280 marks) (Rank I) followed by Singh et al. (Water Resour Manag 29(11):4111–4127, 2015) model with 642 marks (Rank II), Michel et al. (Water Resour Res 41(2):W02011, 2005) model with 376 marks (Rank III) and Mishra and Singh model with 362 marks (= Rank IV). The original SCS-CN model, however, performs the poorest of all with 209 marks (Rank V).     

Kinetics,Mechanistic and Thermodynamics of Zn(II) Ion Sorption: A Modeling Approach

Biosorption potential of Cedrus deodara sawdust (CDS) in terms of sorption of Zn(II) ion across liquid phase has been evaluated in the present investigation. The surface of the CDS biomass before the sorption of Zn(II) ions seemed to be more porous, non‐crystalline and heterogeneous. The maximum uptake capacity of CDS was 97.39 mg g^?1. Sorption of Zn(II) ion on the surface of CDS sawdust was maximum at pH 5, temperature 45°C, initial concentration of Zn(II) ion 100 mg L^?1, biomass dose 1 g L^?1, contact time 150 min, and agitation rate 160 rpm. Pseudo second‐order kinetics with the highest linear regression coefficient (R² = 0.99), and lowest values of error functions, i.e., chi (χ²) and sum of square errors (SSE) against pseudo first‐order rate kinetics showed that the sorption of Zn(II) ion on the surface of CDS was mediated by chemosoprtive forces of attraction rather than physical adsorption. Mechanistically, relatively higher proportion of sorption of Zn(II) ion in early phase of contact time was profoundly explained by Bangham's equation and film diffusivity (D^f). Intraparticle or pore diffusion (D_p) of Zn(II) ion inside the pores of CDS was rate limiting step at the later stage of contact time. Furthermore, the thermodynamic study on sorption of metal ion delineated the fact that the Zn(II) sorption on the surface of CDS was spontaneous, endothermic together with increased entropy at solid liquid interface.     

Size distribution and roundness of clasts within pseudotachylytes of the Gangavalli Shear Zone,Salem, Tamil Nadu: An insight into its origin and tectonic significance

Gangavalli (Brittle) Shear Zone (Fault) near Attur, Tamil Nadu exposes nearly 50 km long and 1–3 km wide NNE–SSW trending linear belt of cataclasites and pseudotachylyte produced on charnockites of the Southern Granulite Terrane. Pseudotachylytes, as well as the country rock, bear the evidence of conjugate strike slip shearing along NNE–SSW and NW–SE directions, suggesting an N–S compression. The Gangavalli Shear Zone represents the NNE–SSW fault of the conjugate system along which a right lateral shear has produced seismic slip motion giving rise to cataclasites and pseudotachylytes. Pseudotachylytes occur as veins of varying width extending from hairline fracture fills to tens of meters in length. They carry quartz as well as feldspar clasts with sizes of few mm in diameter; the clast sizes show a modified Power law distribution with finer ones (<1000 \({\upmu }\)m\(^{2})\) deviating from linearity. The shape of the clasts shows a high degree of roundness (>0.4) due to thermal decrepitation. In a large instance, devitrification has occurred producing albitic microlites that suggest the temperature of the pseudotachylyte melt was >1000\(^{\circ }\hbox {C}\). Thus, pseudotachylyte veins act as a proxy to understand the genetic process involved in the evolution of the shear zone and its tectonic settings.     

Assessment of reservoir sedimentation using remote sensing and recommendations for desilting Patratu Reservoir,India

ABSTRACT

This study describes the assessment of reservoir sedimentation of the Patratu Reservoir using Satellite Remote Sensing (SRS). The sedimentation assessment was carried out using satellite data and reservoir water level data from 2006 to 2012. Water spread area was analysed from satellite data. The Normalized Difference Water Index (NDWI) has been used to delineate open water features and to enhance the presence of water surface in satellite imagery of the Patratu Reservoir. Water spread area of the reservoir at a particular elevation on the date of the passing of the satellite was used to develop an elevation-area curve. For the present case, fluctuation of water level was found to vary from 387.096 to 406.152 m. The linear interpolation/extrapolation technique has been employed to assess the water spread area of Patratu Reservoir at different elevations. Further, these areas were used to compute the live storage capacity of the reservoir between two elevations by the Prismoidal formula. From the study, it was found that due to sedimentation, the live storage capacity of Patratu Reservoir has reduced from 101.95 to 89.96 hm³, thus showing capacity loss of 11.76% in a span of 44 years. To increase the live storage capacity of the reservoir it is proposed to adopt manual and mechanical digging combined with flushing for desilting of the deposited sediment.

EDITOR D. Koutsoyiannis ASSOCIATE EDITOR S. Kanae     

Dynamic,Mechanistic, and Thermodynamic Modeling of Zn(II) Ion Biosorption onto Zinc Sequestering Bacterium VMSDCM

The surface of the bacterial cells before the biosorption of Zn(II) ion has been found rough, heterogeneous, and non‐crystalline together with tremendous protrusions and negatively charged functional groups. The bacterium was characterized as rod shaped with Gram‐negative type of cell wall structure. In reaction dynamics, pseudo‐second‐order kinetics with higher linear correlation coefficient (R²) ranging between 0.97 and 0.99, lower sum of square errors (SSE) (0.035–0.081) and chi (χ²) (0.0013–0.009) provided a better explanation of sorption of Zn(II) ion on bacterium surface as compared to pseudo‐first‐order model. The removal of Zn(II) was governed by both film and intra‐particle diffusion at onset and later stage of sorption of metal ion on the surface of bacterial cells. The R² (0.92–0.94) for intra‐particle diffusion model was quite higher with lower values of SSE (9.56–16.33) and chi (χ²) (11.26–19.65) against the Bangham's model. The positive value of ΔH (16.628 × 10^?6 kJ/mol) and ΔS (5320.90 kJ/mol/K) showed that the biosorption of Zn(II) ion across liquid phase on bacterial surface was endothermic with increased randomness at solid–liquid interface. The negative values of ΔG demarcated the whole process as spontaneous in nature. In the present work, the distribution coefficient was found to be > 0.5 at various temperature ranges. At the attainment of equilibrium, the residual concentration of Zn(II) ion in liquid phase was around 0.6 mg/L, which was much below the limit described by United States Environmental Protection Agency (USEPA), i.e. 5 mg/L.     

Analysis and farmers’ perception of climate change in the Kashmir Valley,India

Theoretical and Applied Climatology - Analysis of climatic variables is important for the detection and attribution of climate change trends and has received considerable attention from researchers...