T-XCO2 stability relations and phase equilibria of a calcic carbonate scapolite

At a total pressure of 5 kb, calcic, Cl-free scapolite (Me₈₃) is stable relative to plagioclase-bearing assemblages at $\text{T ≧ 625°C}$, . With decreasing temperature, scapolite breaks down to plagioclase + calcite. Scapolite is replaced by plagioclase + grossular + cancrinite + CO₂ in the presence of H₂O-rich fluids. The stable coexistence of scapolite and calcite, an assemblage typical of most natural occurrences of calcic scapolite, is limited by the reaction: scapolite + calcite → grossular + cancrinite + CO₂, which occurs at 750°C, X_CO2 = 0.46; 700°C, X_CO2 = 0.33; 650°C, X_CO2 = 0.18, for the chosen bulk composition.Generalization of the experimental results to encompass the complete range of fully carbonated scapolite compositions indicates that mizzonite (Me₇₅) has the largest T-X_CO2 stability field. For scapolite more calcic than mizzonite, stable growth is restricted to conditions of increasingly higher temperature and X_CO2.The experimental results are consistent with various petrologic features of scapolite-bearing rocks, particularly scapolite-clinopyroxene granulites, and indicate that such rocks were formed in the presence of CO₂-rich fluids.     

Magnetohydrodynamic oscillations due to precessional motion

Summary The motion of a non-viscous liquid medium with an ideal electrical conductivity, enclosed in the ellipsoidal cavity of an envelope subject to precessional motion, is investigated. Inside the cavity there is a toroidal magnetic field. It is proved that the precessional motion of the envelope generates forced oscillations of the medium with a period of 24 hours and two different types of eigen oscillations. Expressions for computing the amplitudes and frequencies of all types of oscillations are derived. The maximum values of disturbance fields are determined for geophysically acceptable parameters.     

MINI-MACtm—A new generation dual—Band surveyor

Summary Litton Divisions presently produce both high accuracy GPS surveyors and low—cost GPS navigation sets. Aero Service'sMACROMETER ^R Interferometric Surveyors, have become the standard against which GPS surveying equipment is measured. Litton Aero Products has developed a highly digitized, low costL ₁,C/A code GPS card set. The integration of these technologies had led to the development of a low-cost, high-precision, GPS survey system which can be configured with or without a codelessL ₂ capability. TheMINI-MAC surveying system is the first member of the new generation of GPS survey systems resulting from this joint development. The system design is described in this paper, and initial survey test results using a prototypeMINI-MAC surveying system are presented.     

Selenium concentration in food and blood of residents of Abeokuta Metropolis,Southwestern Nigeria

Selenium like any other element can both be essential and toxic depending upon the concentration at which it occurs in human diet. This paper assessed the level of this trace element in twenty different (20) types of locally produced food items around Abeokuta town and the blood obtained from the antecubital fossa vein of eighty-eight (88) healthy adults resident in Abeokuta.     

The Two-Point Covariance Function of Galaxy Clustering for Extreme Values of its Argument

The two-point covariance function of galaxy clustering is discussed for small and large values of its argument.     

Frost risk mapping for landscape planning: A methodology

Summary Minimum air temperatures were measured during three winters with a network of stations in open, undulating terrain. It was observed that the change in minimum air temperature with elevation could be predicted from mean nighttime windspeed, total nighttime net radiation loss and a hill-top reference minimum temperature. It was also found that the deviation of temperatures at individual sites could be predicted from a local terrain parameter which reflects the extent of cold air accumulations. Thus a methodology for frost risk mapping has been developed which is based on regional weather dataand local terrain analysis. This paper describes the model and illustrates the regional weather and terrain effects with three-dimensional block diagrams.With 8 Figures     

A preliminary investigation into the use of ochre as a remedial amendment in arsenic-contaminated soils

Ochre is an unwanted waste product that accumulates in wetlands and streams draining abandoned coal and metal mines. A potential commercial use for ochre is to remediate As contaminated soil. Arsenic contaminated soil (605 mg kg⁻¹) was mixed with different ochres (A, B and C) in a mass ratio of 1:1 and shaken in 20 mL of deionised water. After 72 h As concentration in solution was ca. 500 μg kg⁻¹ in the control and 1–2.5 μg kg⁻¹ in the ochre treated experiments. In a second experiment soil:ochre mixtures of 0.05–1:1 were shaken in 20 mL of deionised water for 24 h. For Ochres A and C, as solution concentration was reduced to ca. 1 μg kg⁻¹ by 0.2–1:1 ochre:soil mixtures. For Ochre B, as concentration only reached ca. 1 μg kg⁻¹ in the 1:1 ochre:soil mix. Sorption of As was best modelled by a Freundlich isotherm using As sorption per mass of goethite in the ochre (log K = 1.64, n = 0.79, R² = 0.76, p 0.001). Efficiency of ochre in removing As from solution increased with increasing total Fe, goethite, citrate dithionite extractable Fe and surface area.     

Age and source material of the Kingash ultramafic-mafic massif,East Sayan

The REE distribution patterns and Nd whole-rock and mineral isotope ratios of the Kingash ultramafic-mafic massif enabled us to propose a multistage history for its evolution at 1410 and 875 Ma. These stages reflect the magmatic evolution of the Siberian paleocontinent margin during the Late Precambrian. The age of metamorphism of the massif during collision and accretion in the Early Paleozoic (∼500 Ma) was obtained based on a Sm-Nd mineral isochron from rheomorphic veined albitite. The Nd and Sr isotopic compositions of rocks from the Kingash massif suggest mantle sources for picritic and basic magmas, which are thought to have originated by mixing of different proportions of depleted (PREMA or DM) and enriched (EM) melts. The initial isotope ratios of the parental melts transformed during interaction with Sr-rich material from the host metasedimentary complexes.     

Estimating water balance components of tropical wetland lakes in the Pantanal dry season,Brazil

Abstract

Water balance studies with stable water isotopes have rarely been conducted in remote and tropical wetland areas. As such, little is known regarding the water balance and groundwater–surface water interaction in the Pantanal, one of the largest and most pristine wetlands in the world. We applied MINA TrêS, a water balance model utilizing stable water isotopes (δ¹⁸O, δ²H) and chloride (Cl^-) to assess the dry-season hydrological processes controlling groundwater–surface water interactions and the water balance of six floodplain lakes in the northern Pantanal, Brazil. Qualitatively, all lakes exhibited similarity in hydrological controls. Quantitatively, they differed significantly due to morphological differences in controlling groundwater inflow and lake volume. Our approach is readily transferable to other remote and tropical wetland systems with minimal data input requirements, which is useful in regions with sparse hydrometric monitoring.

Editor Z.W. Kundzewicz