Groundwater Pumping Is a Significant Unrecognized Contributor to Global Anthropogenic Element Cycles

Quantifying anthropogenic contributions to elemental cycles provides useful information regarding the flow of elements important to industrial and agricultural development and is key to understanding the environmental impacts of human activity. In particular, when anthropogenic fluxes reach levels large enough to influence an element's overall cycle the risk of adverse environmental impacts rises. While intensive groundwater pumping has been observed to affect a wide-range of environmental processes, the role of intensive groundwater extraction on global anthropogenic element cycles has not yet been characterized. Relying on comprehensive datasets of groundwater and produced water (groundwater pumped during oil/gas extraction) chemistry from the U.S. Geological Survey along with estimates of global groundwater usage, I estimate elemental fluxes from global pumping, consumptive use, and depletion of groundwater. I find that groundwater fluxes appreciably contribute to a number of elements overall cycles and thus these cycles were underestimated in prior studies, which did not recognize groundwater pumping's role. I also estimate elemental loadings to agricultural soils in the United States and find that in some regions, groundwater may provide a significant portion (more than 10%) of crop requirements of key nutrients (K, N). With nearly 40% of globally irrigated land under groundwater irrigation, characterizing nutrient and toxic element fluxes to these soils, which ultimately influence crop yields, is important to our understanding of agricultural production. Thus, this study improves our basic understanding of anthropogenic elemental cycles and demonstrates that quantification of groundwater pumping elemental fluxes provides valuable information about the potential for environmental impacts from groundwater pumping.     

Features of the Balance Structure Formation of Groundwater Withdrawal and Its Effect on River Flow at a Subsoil Water Level Drawdown

Water Resources - The balance structure of the pumpage sourses of riverside water-intakes, developing a subsoil aquifer or intermediate water that hydraulically interacts with it, can show the...     

Strong-Earthquake-Prone Areas Recognition Based on an Algorithm with a Single Pure Training Class: I. Altai–Sayan–Baikal Region, М ≥ 6.0

Izvestiya, Physics of the Solid Earth - A new version of the Barrier algorithm is proposed for recognition of strong-earthquake prone regions based on training over a single reliable training...     

Features of the Behavior of Ionospheric Parameters В0 and В1 in the High-Latitude Zone

Geomagnetism and Aeronomy - The climatological features and behavior of the parameters B0_Neh_I, B1_Neh_I found from N(h) profiles calculated by the curves from the virtual heights during...     

Structure of Prominences with Normal and Inverse Polarities

Geomagnetism and Aeronomy - Based on the measurements of their magnetic fields, solar prominences can be divided into two types: filaments with normal (N) or inverse (I) polarity. In an N-type...     

Estimates of Lithospheric Failure Cycle Parameters from Regional Earthquake Catalogues

Izvestiya, Physics of the Solid Earth - Abstract—Based on the generalized frequency–magnitude relation for earthquakes, the failure cycle parameters are estimated from regional seismic...     

Mechanical and low-cycle fatigue behavior of stainless reinforcing steel for earthquake engineering applications

Use of stainless reinforcing steel (SRS) in reinforced concrete (RC) structures is a promising solution to corrosion issues. However, for SRS to be used in seismic applications, several mechanical properties need to be investigated. These include specified and actual yield strengths, tensile strengths, uniform elongations and low-cycle fatigue behavior. Three types of SRSs (Talley S24100, Talley 316LN and Talley 2205) were tested and the results are reported in this paper. They were compared with the properties of A706 carbon reinforcing steel (RS), which is typical for seismic applications, and MMFX II, which is a high strength, corrosion resistant RS. Low-cycle fatigue tests of the RS coupons were conducted under strain control with constant amplitude to obtain strain life models of the steels. Test results show that the SRSs have slightly lower moduli of elasticity, higher uniform elongations before necking, and better low-cycle fatigue performance than A706 and MMFX II. All five types of RSs tested satisfy the requirements of the ACI 318 code on the lower limit of the tensile to yield strength ratio. Except Talley 2205, the other four types of RSs investigated meet the ACI 318 requirement that the actual yield strength does not exceed the specified yield strength by more than 18 ksi (124 MPa). Among the three types of SRSs tested, Talley S24100 possesses the highest uniform elongation before necking, and the best low-cycle fatigue performance.     

Groundwater Quality in the Yucatan Peninsula: Insights from Stable Isotope and Metals Analysis

High surface water-groundwater connectivity characterizes watersheds underlain by karsts, increasing contaminant transport risks. However, karsts are highly complex, making research necessary to understand the transport of contaminants from the surface, through the aquifer, to discharge areas. In Yucatan, the lack of waste water treatment raises the risk of groundwater contamination. We monitored stable isotopes (δ¹⁸O-NO₃ and δ¹⁵N-NO₃), cadmium, and lead to document waste water contamination and transport during the rainy and dry seasons, using water samples collected along the Ring of Cenotes during each season. Specific conductance and pH showed no consistent seasonality, with conductance ranging from 0.5 to 55 mS/cm and pH ranging from 6.6 to 8.6 for most samples. Nitrate concentrations in the cenotes averaged 205 ± 260 μM and no seasonal pattern was observed. Cd and Pb concentrations were 0.1 to 37.9 μg/L and 0.2 to 243.2 μg/L, respectively. Nitrate stable isotope values were 2.6 to 27.2‰ for δ¹⁸O and 1.2 to 20.7‰ for δ¹⁵N. The statistical relationship between δ¹⁵N and δ¹⁸O, in dry season samples, indicated that denitrification was occurring. A scale measure for waste water recognition showed: (1) high variability among sites probably related with dry/rainy seasons and/or diverse anthropogenic activities; and (2) specific water quality variables that contribute to contamination at each site during each season. Importantly, our analyses indicate that in the area surrounding the Ring of Cenotes, waste water exhibits spatial and temporal patterns related to complex transport and dilution processes, as is the case in karsts in general.     

A reduced-rank prediction model of stream-channel size response to traditional agricultural land-use practices in southwestern Nigeria

Stream-channel morphologic responses are found to be related to different parameters measuring traditional agricultural land-use patterns and practices in 50 small headwater basins in southwest Nigeria. The problem of intercorrelations among these parameters made it initially difficult to establish their precise channel enlargement effects and to calibrate an impact prediction model. Through factor analysis of the 22 land-use and morphometric parameters, six factors identified as measures of traditional land-use practice, farm size, planting activities, shortened fallow, relief and overland flow, were found to account for 86% of the variance in the data. The factor-defining variables are length of cropping period, areas in short fallow, farm-plot size, length of farm preparation, relief ratio and overland flow. In a multiple regression analysis, only the first three variables were found to be statistically significant in explaining stream-channel morphologic responses. Thus, areas in short fallows, average farm size and length of cropping period adequately described those aspects of the traditional farming practices that affect basin hydrologic and channel responses. Since these variables were orthogonally derived, they formed the basis for the evaluation of the channel impact status of traditional land-use activities. The duplication of information and effects in the original 22-variable full-rank model were removed while utilizing the three-factor reduced model.