Rare-earth elements in Lower Palaeozoic epicontinental and eugeosynclinal sediments from the Oslo and Trondheim regions

Eight rare-earth elements (REE) have been determined in Cambro-Silurian sediments and volcanics from nine stratigraphic units in the Trondheim Region and ten stratigraphic units in the Oslo Region by neutron-activation analyses. In the eugeosynclinal sediments from the Trondheim Region the REE variations are related to variations in source material, which mainly are volcanic debris of local origin. In the foreland sediments from the Oslo Region significant development of clays has occurred and therefore the REE variations reflect the deposition environment.     

Soil-5, A New IAEA CErtifiEd Reference Material for Trace Element Determinations*

60 geochemical laboratories from the world over, contributing in all 3687 bits of chemical data on 60 elements, haue willingly participated in the study of SOIL-5 as a reference material. The preparation of SOIL-5 in 45 kg and homogeneity teats are described; in addition, all the data compiled are presented. In evaluating the compiled data, the use of four concurrent tests for outlier-rejection at the same level of significance, has been applied. After proper statistical treatment, “recommended values” could be established for 31 elements, most of them trace elements and “information values” for 29 elements. 23 of the recommended values could be given with a “relatively high” degree confidence whereas the other 18 recommended Values with a “reasonable” degree of confidence. An attempt is made to compare the analytical methods employed; the existence of possible sy3tematic differences is pointed ont.     

A possible manifestation of spiral shock waves in the accretion disks of cataclysmic variables

We present the results of three-dimensional numerical simulations of flow structures in binary systems with spiral shock waves. Variations of the mass-transfer rate perturb the equilibrium state of the accretion disk; consequently, a condensation (blob) behind the shock breaks away from the shock front and moves through the disk with variable speed. Our computations indicate that the blob is a long-lived formation, whose mean parameters do not vary substantially on timescales of several tens of orbital periods of the system. The presence of the spiral shocks maintains the compact blob in the disk: it prevents the blob from spreading due to the differential motion of matter in the disk, and dissipative spreading on this timescale is negligible. A number of cataclysmic variables display periodic or quasi-periodic photometric variations in their light curves with characteristic periods ～0.1–0.2P _orb, where P _orb is the orbital period. The blobs formed in systems with spiral shock waves are examined as a possible origin for these variations. The qualitative (and, in part, quantitative) agreement between our computations and observations of IP Peg and EX Dra provides evidence for the efficacy of the proposed model.     

Fish assemblage structure in relation to environmental variation in a Texas Gulf coastal wetland

We described seasonal fish-assemblages in an estuarine marsh fringing Matagorda Bay, Gulf of Mexico. Habitat zones were identified by patterns of fish species abundance and indicator species optima along gradients in salinity, dissolved oxygen (DO), and depth in our samples. Indicators of the lower brackish zone (lower lake and tidal bayou closest to the bay) were gulf menhaden (Brevoortia patronus), bay anchovy (Anchoa mitchilli), silver perch (Bairdiella chrysoura), and spotted seatrout (Cynoscion nebulosus) at salinity >15‰, DO 7–10 mg l⁻¹, and depth <0.5 m. Indicators of the upper brackish zone (lake and fringing salt marsh) were pinfish (Lagodon rhomboides) and spot (Leiostomus xanthurus) at salinity 10–20‰, DO >10 mg l⁻¹, and depth <0.5 m. In the freshwater wetland zone (diked wetland, ephemeral pool, and perennial scour pool), indicators were sheepshed minnow (Cyprinod on variegatus), rainwater killifish (Lucania parva), mosquitofish (Gambusia affinis), and sailfin molly (Poecilia latipinna) at salinity <5‰, DO <5 mg l⁻¹, and depth ≥1 m. In the freshwater channelized zone (slough and irrigation canal), indicators were three sunfish species (Lepomis), white crappie (Pomoxis annularis), and gizzard shad (Dorosoma cepedianum) at salinity <5‰, DO <5 mg l⁻¹, and depth >1.5 m. In brackish zones, seasonal variation in species diversity among sites was positively correlated with temperature, but assemblage structure also was influenced by depth and DO. In the freshwater zones, seasonal variation in species diversity among sites was positively correlated with depth, DO, and salinity, but assemblage structure was weakly associated with temperature. Species diversity and assemblage structure were strongly affected by the connectivity between freshwater wetland and brackish zones. Uncommon species in diked wetlands, such as tarpon (Megalops atlanticus) and fat sleeper (Dormitator maculatus), indicated movement of fishes from the brackish zone as the water level rose during natural flooding and scheduled (July) releases from the diked wetland. From September to July, diversity in the freshwater wetland zone decreased as receding waters left small isolated pools, and fish movement became blocked by a water-control structure. Subsequently, diversity was reduced to a few species with opportunistic life histories and tolerance to anoxic conditions that developed as flooded vegetation decayed.     

Sulfides in petroleum

The homologous series of terpenoid sulfides previously reported to be present in Athabasca bitumen have been detected in a variety of petroleums from the Western Hemisphere. All 22 samples examined, ranging in age from Devonoan to Cretaceous, contained the terpenoid sulfides. A method is described for the isolation of sulfides from petroleums based on the selective oxidation of sulfides to more polar sulfoxides which are easily removed from the mixture and their subsequent reduction to sulfides. The sulfide content in the petroleum maltenes examined ranged from 0.3 to 16.1% w/w. In addition to the bicyclic and tetracyclic terpenoid sulfides a new series of tricyclic terpenoid sulfides has been identified, and the details of the isoprenoid side chain have been elucidated for all three homologous series. The distributions by carbon number of the bicyclic and tetracyclic homologous series of terpenoid sulfides show pronounced variations which are attributed to thermal maturity and degree of water washing of the petroleum, thus the ability to identify terpenoid sulfides should provide a useful tool for oil-oil and oil-source rock correlation studies. The bicyclic and tricyclic terpenoid sulfides have the same carbon framework as the carotenoids which suggest that these sulfides were accessory pigments in photosynthesis.     

Mangrove ecology,aquatic primary productivity,and fish community dynamics in the Teacapán-Agua Brava Lagoon-Estuarine system (Mexican Pacific)

Aquatic primary productivity, mangrove ecology, and fish community dynamics were investigated in the Teacapán-Agua Brava lagoon-estuarine system, the most extensive mangrove ecosystem on the Pacific coast of Mexico with three species of mangroves distributed heterogeneously (Laguncularia racemosa, Rhizophora mangle, andAvicennia germinans). Tree density was 3,203 trees ha^?1 and basal area was 14.0 m² ha^?1. Litterfall was 1,417 g m^?2 yr^?1, characteristic of a productive riverine forest. The degradation constant forLaguncularia racemosa leaves varied from 1.71 to 4.7 yr^?1 and mean annual net aquatic productivity was 0.41 g C m^?3 d^?1. There were high concentrations of humic substances (up to 150 mg l^?1) early in the wet season. Seasonal variations of the above parameters seemed closely related to the ecology of fish populations. There were 75 fish species distributed in two principal assemblages associated with wet and dry seasons. Diversity and biomass analysis indicated 18 dominant species. Total biomass of the community in this coastal system was estimated at 10 g wet wt m^?2. The highest biomass occurred in the wet season. The most common fish species wereMugil curema, Achirus mazatlanus, Galeichthys caerulescens, Arius liropus, Diapterus peruvianus, Lile stolifera, Centropomus robalito, andEucinostomus sp., all of which have fishery importance. Primary productivity and fish community ecology are controlled by habitat characteristics, river discharge, and climatic seasonality.     

Study of rock joints under cyclic loading conditions

Summary A conceptual model for the behaviour of rock joints during cyclic shear and under constant normal stresses was proposed according to results from shear tests with 50 concrete replicas of rock joints. The shear strength and deformability of joint samples were found to be both anisotropic and stress dependent. Based on these experimental results, a two-dimensional constitutive model was developed for rock joints undergoing monotonic or cyclic loading sequences. The joint model was formulated in the framework of non-associated plasticity, coupled with empirical relations representing the surface roughness degradation, appearance of peak and residual shear stresses, different rates of dilatancy and contraction, variable normal stiffness with normal deformation, and dependence of shear strength and deformability on the normal stress. The second law of thermodynamics was represented by an inequality and used to restrict the values of some of the material parameters in the joint model. The new joint model was implemented into a two-dimensional Distinct Element Method Code, UDEC, and its predictions agreed well with some well-known test results.     

3D electrical resistivity tomography survey for the basement of the Abeokuta terrain of Southwestern Nigeria

Geological structures are 3-Dimensional (3D) in nature, thus 1-Dimensional and 2-Dimensional surveys cannot adequately model them. However, sophisticated 3D survey equipment are very expensive. In this study, a singlechannel ABEM SAS 300B Terrameter was used to obtain 3D models of the subsurface. This survey was carried out at three different locations within Abeokuta, a basement complex terrain of southwestern Nigeria. The area falls within longitudes 3.35° and 3.38° East and latitudes 7.22° and 7.46° North respectively, with coordinates of 2550.0 m North and 1724.2 m East. A manual 4-electrode system was used in the Electrical Resistivity Tomography survey at the three locations. Each location was marked into 7 by 7 square grids with 1 m, 3 m and 5 m unit electrode spacings in succession. The pole-pole array was used with the two remote electrodes placed at distances of 23 m, 40 m and 65 m from the grids of 1 m, 3 m and 5 m unit electrode spacings respectively, to reduce their telluric effects on the measured apparent resistivity values. To reduce survey time consumption, the cross-diagonal survey method was adopted. The data obtained were analysed using a 3D inversion software called RES3DINV and 3-Dimensional models of the subsurface were also generated using Slicer Dicer graphics software. The study revealed layers extending to depths of 7.75 m, 23.2 m and 38.7 m for unit electrode spacings of 1 m, 3 m and 5 m respectively. It revealed resistivity values ranging from 7.3 Ωm to 300 Ωm for electrode spacing of 1.0 m; 13.8 Ωm to 200 Ωm for electrode spacing of 3 m and 3.9 Ωm to 200 Ωm for electrode spacing of 5 m at the first location. At the second location, it revealed resistivity values ranging from 0.53 Ωm to 120.0 Ωm for electrode spacing of 3 m and 0.30 Ωm to 100 Ωm for electrode spacing of 5 m. For electrode spacings of 1 m, 3 m and 5 m, resistivity values ranging from 6.1 Ωm to 600 Ωm, 12 Ωm to 600 Ωm and 0.85 Ωm to 1700 Ωm were obtained respectively at the third location. Generally, this study revealed lithologies composed of lateritic soil, sand, sandstone, sandyclay, clayeysand, weathered rock, fractured rock, clay and fresh basement; to a depth of about 39 m. Also, location 3 was discovered to have good groundwater prospects; though not as good as for locations 1 and 2.     

Population Structure of the SW Atlantic Estuarine Crab Neohelice granulata Throughout Its Range: a Genetic and Morphometric Study

Phylogeographic patterns of the SW Atlantic estuarine crab Neohelice granulata were examined using mitochondrial DNA cytochrome oxidase I sequences and analyzed together with morphometric data. Specimens were sampled during a 4-year period (2001?C2004) from 11 localities encompassing the full distributional range of this species along the SW Atlantic (22°57?? S to 42°25?? S). DNA sequences were obtained from 69 individuals belonging to seven localities, and morphometric variation in 12 continuous characters was analyzed for 646 crabs from ten localities. Strong genetic differentiation, consistent with a pattern of isolation-by-distance, was detected among all localities indicating that gene flow occurs mainly between neighboring populations. Analyses of molecular variance showed genetic subdivision between the southern (Argentina) and the northern (Brazil) sites, suggesting restricted gene flow at a regional scale. The genetic structure of this species could be divided into two distinct groups due to a limited gene flow between southern and northern regions as a consequence of larval dispersal patterns. Coastal currents in the vicinity of the Rio de la Plata likely act as a barrier to dispersal within the species range. Moreover, genetic data indicate that populations of N. granulata might have undergone a northward demographic expansion since the late Pleistocene. The morphometric analysis showed no geographical pattern of morphological differentiation, although there were differences among sampling sites.