Surface water quality evaluation in Odukpani, Calabar Flank, south-eastern Nigeria

 The present article is the second in a series of baseline water quality evaluation studies in parts of south-eastern Nigeria. Study results indicate that the water samples from the study are generally acidic, soft and fresh in addition to low sodium and salinity hazard. Regression equations indicate a good positive correlation between conductivity and Na, Ca, Mg and SO₄. Ca-SO₄ and Ca-Cl constitute the major facies in the area. Generally the waters in the area are good for most domestic and agricultural purposes. Received: 14 April 1997 · Accepted: 3 February 1998     

Geomagnetic Storm Effects at <Emphasis Type="Italic">F</Emphasis>1 Layer Altitudes in Various Periods of Solar Activity (Irkutsk Station)

The influence of geomagnetic disturbances on electron density Ne at F1 layer altitudes in different conditions of solar activity during the autumnal and vernal seasons of 2003–2015, according to the data from the Irkutsk digital ionospheric station (52° N, 104° Е) is examined. Variations of Ne at heights of 150–190 km during the periods of twenty medium-scale and strong geomagnetic storms have been analyzed. At these specified heights, a vernal–autumn asymmetry of geomagnetic storm effects is discovered in all periods of solar activity of 2003–2015: a considerable Ne decrease at a height of 190 km and a weaker effect at lower levels during the autumnal storms. During vernal storms, no significant Ne decrease as compared with quiet conditions was registered over the entire analyzed interval of 150?190 km.     

Continuous zircon growth during long-lived granulite facies metamorphism: a microtextural,U–Pb,Lu–Hf and trace element study of Caledonian rocks from the Arctic

Microtextural, U–Pb, trace element and Lu–Hf analyses of zircons from gneisses dredged from the Chukchi Borderland indicate a long-lived, Cambrian–Ordovician, granulite facies metamorphism. These results reveal a complete prograde, peak and cooling history of zircon growth during anatexis. Early increasing temperatures caused modification and Pb-loss of Precambrian zircons by recrystallization and dissolution/re-precipitation of existing grains. Small variations in initial ¹⁷⁶Hf/¹⁷⁷Hf results (0.282325–0.282042) and flat HREE patterns of these zircons indicate that they grew by dissolution/re-precipitation in the presence of garnet. Zircons subsequently crystallized from a partial melt during peak to post-peak metamorphism from 530 to 485 Ma. A broad range of initial ¹⁷⁶Hf/¹⁷⁷Hf ratios (0.282693–0.282050) and mineral inclusions within zircons suggest that this phase of growth incorporated Zr and Hf obtained from the breakdown of Zr-enriched phases. Microtextural evidence along with trace element and isotopic data suggests that final growth of metamorphic rims on zircon occurred during slow cooling and crystallization of residual partial melts during the early Ordovician (485–470 Ma). Younger, late Ordovician–Silurian (420–450 Ma) euhedral, oscillatory-zoned, trace element-enriched zircons crystallized within leucocratic veins that intrude the gneisses. Their age corresponds to granitoids dated from this same dredge. The intrusives and veins provide evidence that the Chukchi Borderland rifted from a position near Pearya and northwest Svalbard, which represent the northern continuation of the Caledonian orogen. Evidence for earlier Cambrian metamorphism has not been reported from this region. The age of granulite facies metamorphism reported here represents the earliest phase of deformation in the Arctic Caledonides.     

Über die Mischungsarbeit von stabil geschichteten Wassermassen

Zusammenfassung Es wird gezeigt, daß — entgegen der bisherigen Ansicht — die Mischungsarbeit von verschieden temperierten Wassermassen nicht unbegrenzt mit der Größe des Temperaturunterschiedes der Wassermassen anwächst, sondern daß sie für einen bestimmten Temperaturunterschied (bzw. bestimmten Temperaturgradienten) ein Maximum erreicht, für größere Temperaturunterschiede aber wieder auf wesentlich kleinere Beträge abnimmt.

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Summary It is shown that — in contradiction to the hitherto existing view — the energy resulting from the mixture of water-masses with different temperatures does not increase infinitely with the value of the temperature-difference of the water-masses, but that it reaches a maximum for a determined temperature-difference (respectively a determined temperature lapse rate), whereas it decreases to much smaller amounts for greater temperature-differences.

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Résumé On montre que, contrairement aux vues admises jusqu'ici, l'énergie résultant du mélange de masses d'eau à températures différentes ne croît pas sans limite avec l'écart de température, mais qu'elle atteint un maximum pour un écart déterminé (ou pour un gradient de température déterminé) et décroît de nouveau notablement pour des écarts plus grands.

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Mit 1 Textabbildung.     

Model for the formation of arsenic contamination in groundwater. 1. Datong Basin,China

Mineral equilibria were analyzed in the system As-bearing rock-meteoric water. It was shown that carbonate rocks are the most probable source of As and Sr in the waters of the Datong Basin (People's Republic of China). The reason for groundwater enrichment in As is the shift of the equilibrium FeCO₃ (siderite) + H₂O = FeOOH(goethite) + CO₂(g) + H₂(g) to the left (toward siderite formation) owing to organic matter oxidation by atmospheric oxygen and an increase in the equilibrium partial pressure of CO₂, while the Eh of the system remains below ?0.30 ± 0.06 V.     

Textural-structural,mineralogical, isotopic,and age characteristics of Jurassic terrigenous rocks of the northwestern Caucasus (the Belaya River section)

Results of the comprehensive study of structural, lithological, mineralogical, and isotopic characteristics of Lower Jurassic rocks exposed in the Belaya River valley (Adygeya) in meganticlinorium of the Greater Caucasus are presented. Deformation microstructures were studied. Lithological and textural-structural changes in sequences related to intense secondary transformations should affect the state of isotopic systems of rocks. To reveal basic trends in the evolution of isotopic systems, investigation using the K-Ar method was carried out. Clay fraction (less than 1 μm) separated from rocks and bulk samples were analyzed. Cleavage development, approximate value of rock contraction, and isotopic characteristics are compared with the available data on alteration of clay mineral assemblages. Relationship between the degree of rock deformation at the microlevel and calculated K-Ar ages has been established. K-Ar systems of clayey rocks indicate the age of cleavage formation and correspond to the Bajocian-Bathonian contraction period.     

Quaternary sediments in the axial zone of the Brazil Basin

Lithological and micropaleontological studies of sediments were carried out along the meridional profile across the Brazil Basin. Based on nannoplankton and diatom assemblages, the sediments represented by oxidized miopelagic clays, differently reduced hemipelagic clays, and clayey-siliceous (Ethmodiscus) and calcareous (coccolith-foraminiferal) oozes are attributed to the Pleistocene-Holocene. Specific features of sedimentary material indicate its redeposition by Antarctic bottom waters, mudflows, slumps, and rockslides. It is shown that sedimentation in the Brazil Basin corresponds to the incomplete pelagic (miopelagic) type of oceanic lithogenesis transitional to the near-continental one.     

Palaeoflood activity and climate change over the last 1400 years recorded by lake sediments in the north‐west European Alps

A high‐resolution sedimentological and geochemical study of a high‐altitude proglacial lake (Lake Blanc, Aiguilles Rouges, 2352 m a.s.l.) revealed 195 turbidites, 190 of which are related to flood events over the last 1400 years. We used the coarsest sediment fraction of each turbidite as a proxy for the intensity of each flood event. Because most flood events at this locality are triggered by localized summer convective precipitation events, the reconstructed sedimentary record reveals changes in the frequency and intensity of such events over the last millennium. Comparisons with other temperature, palaeohydrological and glacier reconstructions in the region suggest that the most intense events occurred during the warmest periods, i.e. during the Medieval Climate Anomaly (AD 800–1300) and the current period of global warming. On a multi‐decadal time scale, almost all the flood frequency peaks seem to correspond to warmer periods, whereas multi‐centennial variations in flood frequency appear to follow the regional precipitation pattern. Consequently, this new Alpine flood record provides further evidence of a link between climate warming and an increase in the frequency and intensity of flooding on a multi‐decadal time scale, whereas the centennial variability in flood frequencies is related to regional precipitation patterns. Copyright © 2013 John Wiley & Sons, Ltd.     

Some foundation stability problems of the railway bridge over the Mala Rijeka

SummarySome Foundation Stability Problems of the Railway Bridge over the Mala Rijeka The authors presented an outlay of problems occurring in estimating the stability of rocky slopes loaded by large vertical forces. General attitudes, kept by the authors during the stability analysis for an actual case — foundation of piers No. 3 and 4 of the railway bridge across the Mala Rijeka, are also presented. The results of calculation as well as the advantages of the approach applied are outlined in the paper. Finally, general conclusions are drawn regarding the method to be kept in solving the stability of slopes loaded by large artificial loading.With 7 Figures