Sulfur Isotopes in the Upper Part of the Black Sea Anoxic Zone

New data are reported on the sulfur isotope composition and concentration of sulfide and sulfate in the upper part of the Black Sea anoxic zone as a function of the potential water density. The observations were performed at a station with the coordinates 44.489° N and 37.869° E three times a week every two days. A local negative deficiency in sulfate concentration up to 1.7% related to the sulfate reduction processes was recorded. This anomaly in sulfate concentration was short-lived and did not affect the sulfur isotope composition. In the upper part of the anaerobic zone, the δ³⁴S(SO₄) value varied from 21.2 to 21.5‰, which could have occurred from mixing of water masses from the oxic zone (21.1‰) and the Bottom Convective Layer (23.0 ± 0.2‰). The sulfur isotope composition of sulfide ranged from ?40.8% at a depth of 250 m to ?39.4‰ at the upper boundary of the anoxic zone with a H₂S content of only 2.7 μM. Two models (mass balance and fractionation of sulfur isotopes using the Rayleigh equation) are considered to explain the differences in δ³⁴S(H₂S) values observed.     

Environmental factors influencing aggregation of manta rays (Manta birostris) off the northeastern coast of the Yucatan Peninsula

Manta rays inhabit tropical, subtropical and temperate waters. Aggregation sites of manta rays have been recognized worldwide, but the reasons for this behavior are still poorly understood. This study describes environmental factors influencing aggregation sites of the giant manta ray (Manta birostris) off the northeastern coast of the Yucatan Peninsula. Observations of manta rays were obtained from scientific surveys conducted during 2006–2011. Environmental data were obtained from satellite imagery. The maximum entropy (Maxent) method for habitat modeling was used to determine the effects of environmental conditions on the species and predict suitable habitat for manta rays in this region. Primary productivity and distance to the coast were the most influential variables, suggesting that aggregation occurs in highly productive coastal waters. The distribution of manta rays predicted by the Maxent model showed that the most suitable habitat within the study area is located off the northeastern coast of the Yucatán Peninsula, more precisely, northeast of Isla Holbox and northwest of Isla Contoy. Seasonal patterns of distribution suggest that the most suitable conditions are present from July through September.     

Peculiarities of slick formation on the sea surface

This paper deals with surface slicks, their nature, and causes of formation in context of the development of remote detection methods and investigation of dynamic processes in the ocean and at the air–ocean interface. A simplified formalism is introduced for slick–sea surface contrast formation which takes into account the upward sea radiation and qualitatively explains in situ measurement results. The results of a detection of slicks on the coastal water surface are also described, which, together with the simplified formalism suggested, provide optimal experimental conditions for slick–sea surface contrast measurements; i.e., the contrast of the P component of reflected radiation is measured at viewing angles close to the horizon.     

Experimental analysis of breakwater stability with antifer concrete block

Armor is a pavement made of erosion-resistant materials like a stone or concrete that is constructed to protect breakwater, coasts, and other coastal line features against erosion. These armors are a kind of protective layer made of stone or concrete, used in breakwater constructions or coastal lines, arrayed with specific regular or irregular pattern on the breakwater or the coast. The antifer concrete blocks have almost cubic form, often changed into frustum by adding inclined plates to their sides. One of the most important advantages of these armors is their diversified regular and irregular placement patterns. In this study, using the physical modeling and different tests, the stability level of antifer concrete blocks was evaluated considering the decrease of the armor weight. Results of this study show that by a 10% decrease in the block weight, the failure graph slope is increased and the damage is intensified.     

Spatial Variation of Sea Level Trend Along the Bangladesh Coast

The Bangladesh coast is threatened by rising sea level due to various factors. The results based on the analysis of past 22 years of tidal data of the Bangladesh coast reveal that the annual mean tidal level in the eastern Bangladesh coast is rising at an alarmingly high rate of 7.8 mm/year, which is almost twice the observed rate in the western region. This type of sea level trend seems to be the result of changing local conditions like increased precipitation and land subsidence during the recent decades. It seems that the higher rate of land subsidence in the eastern Bangladesh coast is the main causative factor for the steeper sea level trends there. The differential sea level trends show that the subsidence component in the sea level rise may be as high as 4 mm/year in the eastern Bangladesh coast. However, this needs to be verified with actual geological observations.     

Environmental Impact Assessment of the Proposed Titanium Mining Project in Kwale District,Kenya

This article addresses both environmental and socioeconomic issues concerned with the development or operation of the envisaged titanium mining project in Kwale District of Kenya. TIOMIN Resources Inc., of Canada, through its wholly owned Kenyan subsidiary, Kenya Titanium Minerals Ltd., is proposing to develop a titanium sands mine and mineral processing plants which will produce high grades of heavy minerals including rutile, ilmenite, and zircon. In addition, TIOMIN has proposed to develop a ship loading facility at Shimoni, a significant marine habitat in Kenya. When properly designed and implemented, an Environmental Impact Assessment (EIA) is a powerful tool for ensuring that environmental issues are given due consideration during project design, allowing the benefits of the project to be maximized, while reducing the environmental and social costs of development. In Kenya, the EIA has to be conducted according to the requirements of the Kenya Environmental Management and Co-ordination Act (2000) and in compliance with World Bank standards. An EIA document submitted to the enforcement authority, National Environmental Management Authority (NEMA), enables the issuing of an Environmental Impact Assessment License and a Mining License. A number of exploration studies have been undertaken and several sites have been identified for the extraction of titanium minerals and zircon. Many have expressed concern that environmental matters should be considered before a decision about titanium mining is undertaken. Toxic chemicals used in heavy mineral separation processes and disturbance or redistribution of sediment could spell a disaster for the coastal waters. The Wasini channel is home to world class coral reefs, humpback and spotted dolphins, and marine turtles. Another contentious issue is that of radioactivity associated with the minerals zircon and monazite. The coastal zone is a crucial part of the economy, as it supplies a living for a large number of people along the coast. It is envisaged that involuntary resettlement without adequate compensation and viable alternative sites may result in serious socioeconomic consequences.     

Authigenic carbonate mineral formation in the Pagassitikos palaeolake during the latest Pleistocene, central Greece

The Pagassitikos Gulf in Greece is a semi-enclosed bay with a maximum depth of 102 m. According to the present-day bathymetric configuration and the sea level during the latest Pleistocene, the gulf would have been isolated from the open sea, forming a palaeolake since ~32 cal. ka b.p. Sediment core B-4 was recovered from the deepest sector of the gulf and revealed evidence of a totally different depositional environment in the lowest part of the core: this contained light grey-coloured sediments, contrasting strongly with overlying olive grey muds. Multi-proxy analyses showed the predominance of carbonate minerals (aragonite, dolomite and calcite) and gypsum in the lowest part of the core. Carbonate mineral deposition can be attributed to autochthonous precipitation that took place in a saline palaeolake with high evaporation rates during the last glacial–early deglacial period; the lowest core sample to be AMS ¹⁴C dated provided an age of 19.53 cal. ka b.p. The palaeolake was presumably reconnected to the open sea at ~13.2 cal. ka b.p. during the last sea-level rise, marking the commencement of marine sedimentation characterised by the predominance of terrigenous aluminosilicates and fairly constant depositional conditions lasting up to the present day.     

Consequences of powerful volcanic eruptions according to dendrochronological data

For the first time we identify the peculiarities of the effect of the most powerful (VEI > 5) volcanic eruptions on the regional climate of the Murmansk region on the basis of Kola Peninsula dendrochronological data for a period of more than 560 years. The analysis was based on the tree-ring chronology covering the period from 1445 to 2005. This chronology was derived from Pinus sylvestris samples collected near the northern tree line at Loparskaya station (68°37′ N; 33°14′ E). The data were processed using modern techniques adopted in dendrochronology (cross dating and standardization). We reveal a significant decrease in the radial tree-ring growth over 8 years (on average) after the eruptions; then its value is restored to the normal level. This finding will help evaluate the response of the regional climate system to external climate forcings in this economically important region for Russia.     

Protracted Environmental Issues on a Proposed Titanium Minerals Development in Kenya's South Coast

This study takes cognizance of the fact that the TIOMIN (TIOMIN Resources Inc. of Canada) project has resulted in controversy over its handling of environmental issues and especially the Environmental Impact Assessment (EIA). The authors address many of the protracted issues that have slowed the development of the mining project in Kwale. The main emphasis is on the impacts of the mining and mineral separation processes on the environment, including the governing legislation, the role of consultation and public participation, and socioeconomic issues. In their public documents TIOMIN has specified neither the type of minerals it wants to extract from the area nor their chemical composition. It is well known, however that the titanium minerals and zircon targeted have impurities of iron, thorium and uranium. In the absence of an Environmental Management Plan, the effects of stockpiling radioactive wastes and other impurities that could possibly lead to environmental degradation in both the terrestrial and marine environments have not been publically addressed. The measures proposed to mitigate ecological damage as a result of the establishment of a minerals processing plant in the area seem inadequate. Pollution resulting from accidental spillage or breakage could have significant impact on marine life and residents living near the mining site. Other issues that have not been addressed satisfactorily pertain to the use of surface and underground water. The area already faces a huge water deficit and the calculations presented on aquifer recharge and stream flow rates do not indicate the large quantities of water that would be required in the mineral processing plant. The project, if approved in its present state, risks violation of international conventions. Furthermore, it could cause a conflict between Kenya and Tanzania in the event of an oil spill at the proposed ship loading facility at Shimoni. The proposed mining area includes the district's most fertile land, is home to many fisherfolk and is a major tourist destination. An analysis of the effects of this project on other available opportunities must be thoroughly understood to ascertain the economic and environmental benefits and costs of the mining venture. The proposed compensation rate of $1,000 per acre, for resettlement for example, appears to be grossly inadequate. Compensation should take into account family size and structure family assets and the cost of relocation.     

Pathways of clay mineral transport in the coastal zone of the Brazilian continental shelf from Ceará to the mouth of the Amazon River

The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally, relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence, stronger sedimentation of Amazon sediments would occur only west of the river mouth.