A new approach to verify the model core with idealized experiments

Summary ?A newly developed ocean general circulation model has been tested and verified with some idealized experiments. Generally two types of idealized experiments have been done here. First types are called as “symmetric experiments” and second types are called as “transport experiments”. The first types of experiment help to correct the model core and any deficiency from boundary conditions. The second types of experiment are the type of validation experiment. In both the experiments there are no continents, so in the first type of experiments where symmetric forcings are provided one can expect that model should maintain the symmetric nature. In the second type of experiments one can expect that model should respond correctly to the wind forcings, if no wind curl is present in the wind forcing there will be no circulation in the extratropics and if there is no wind the equator there will be no circulation. The model reproduces the possible envisaged results of these experiments and gives the confidence for performing the realistic integration. Received February 20, 2002; accepted July 7, 2002 Published online: February 20, 2003     

Reactive Nitrogen Compounds at Spitsbergen in the Norwegian Arctic

Simultaneousindependent measurements of NO_y and NO_x(NO_x= NO + NO₂) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NO_xmixing ratio was 27 pptv and did not show any cyclethrough the period. The NO_y mixing ratio showeda maximum in late March, while the difference betweenNO_y and PAN decreased during spring. This is anindication of the dominance of PAN in the NO_ybudget in the Arctic, but possible changes in theefficiency of the NO_y converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h^-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1.     

Seismic facies and architecture of ice-contact submarine fans in high-relief fjords, Troms, Northern Norway

During the Late Weichselian, large marginal moraines were deposited in the Norwegian fjords. In Troms County these features are termed the Skarpnes and Tromsø-Lyngen moraines, respectively, and have been mapped from land into the marine environment where they were formed as ice-contact submarine fans. High-resolution seismic data from several fjords have been studied and reveal a typical sediment thickness of 150–320 m for these ice-contact systems. All of the ice-contact submarine fans were formed under similar climatic conditions, but display wide variation in geometry, architecture and seismic pattern. This variation is related to differences in sediment supply, the nature of the subsurface of the fan (e.g. position of thresholds), basin geometry and basin depth. Based on interpretation of the different seismic facies and the architecture of the fans, former ice-front positions have been suggested and a model has been presented for the formation of different types of ice-contact submarine fans dependent upon variation in local basin condition.     

ELNES spectroscopy of mixed Si coordination minerals

 Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds varying in Si^VI:Si^IV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of Si^VI/(Si^VI+Si^IV): (1) A linear relationship between the L_2,3-L₁ splitting and Si^VI/(Si^VI+Si^IV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied to both Si K- and L-edge ELNES spectra. Received: February 10, 1997 / Revised, accepted: May 23, 1997     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

Nitrogen isotope indicators of seasonal source variability to groundwater

 A nitrogen isotope study of soil water and groundwater in southern Indiana, USA, in 1991–1992 demonstrated considerable variations in nitrate degradation processes compared to an earlier investigation in 1986–1987. Although N-fertilizers were applied in May 1991, the δ¹⁵N values in soil water decreased in February 1992, indicating its delayed release into the system after substantial rainfall. The δ¹⁵N values of groundwater decreased from +12.3‰ in November 1991 to +11.3‰ in February 1992, and to +7.5‰ in March 1992. The increased residence time of nitrate in the soil resulted in increased denitrification, ammonia volatilization and plant uptake, and reduced threat to the groundwater quality. The 1986–1987 study in the area reported that excessive rainfall during the summer rapidly transported the nitrate to deeper horizons and drastically reduced volatilization and microbial reduction of nitrate, thus increasing the immediate threat to the groundwater quality in the area. The present study demonstrated that nitrogen isotopic signatures can be used to determine the effects of local soil type, rainfall, and land-use practices on the fate of nitrate in the subsurface. Received: 18 February 1997 · Accepted: 17 June 1997     

Study of sporadic-E clouds by backscatter radar

It is shown that swept-frequency backscatter ionograms covering a range of azimuths can be used to study the dynamics of sporadic-E clouds. A simple technique based on analytic ray tracing can be used to simulate the observed narrow traces associated with E_s patches. This enables the location and extent of the sporadic-E clouds to be determined. The motion of clouds can then be determined from a time sequence of records. In order to demonstrate the method, results are presented from an initial study of 5 days of backscatter ionograms from the Jindalee Stage B data base obtained during March-April 1990. Usually 2–3 clouds were observed each day, mainly during the evening and up to midnight. The clouds lasted from 1–4 h and extended between 30°–80° in azimuth and 150–800 km in range. The clouds were mostly stationary or drifted generally westward with velocities of up to 80 ms^–1. Only one cloud was observed moving eastward.