Solution mechanisms of H2O in depolymerized peralkaline melts

Solubility mechanisms of water in depolymerized silicate melts quenched from high temperature (1000°-1300°C) at high pressure (0.8-2.0 GPa) have been examined in peralkaline melts in the system Na₂O-SiO₂-H₂O with Raman and NMR spectroscopy. The Na/Si ratio of the melts ranged from 0.25 to 1. Water contents were varied from ∼3 mol% and ∼40 mol% (based on O = 1). Solution of water results in melt depolymerization where the rate of depolymerization with water content, ∂(NBO/Si)/∂X_H2O, decreases with increasing total water content. At low water contents, the influence of H₂O on the melt structure resembles that of adding alkali oxide. In water-rich melts, alkali oxides are more efficient melt depolymerizers than water. In highly polymerized melts, Si-OH bonds are formed by water reacting with bridging oxygen in Q⁴-species to form Q³ and Q² species. In less polymerized melts, Si-OH bonds are formed when bridging oxygen in Q³-species react with water to form Q²-species. In addition, the presence of Na-OH complexes is inferred. Their importance appears to increase with Na/Si. This apparent increase in importance of Na-OH complexes with increasing Na/Si (which causes increasing degree of depolymerization of the anhydrous silicate melt) suggests that water is a less efficient depolymerizer of silicate melts, the more depolymerized the melt. This conclusion is consistent with recently published ¹H and ²⁹Si MAS NMR and ¹H-²⁹Si cross polarization NMR data.     

Entry dynamics and acoustics/infrasonic/seismic analysis for the Neuschwanstein meteorite fall

Abstract— We have analyzed several types of data associated with the well‐documented fall of the Neuschwanstein meteorites on April 6, 2002 (a total of three meteorites have been recovered). This includes ground‐based photographic and radiometer data as well as infrasound and seismic data from this very significant bolide event (Spurný et al. 2002, 2003). We have also used these data to model the entry of Neuschwanstein, including the expected dynamics, energetics, panchromatic luminosity, and associated fragmentation effects. In addition, we have calculated the differential efficiency of acoustical waves for Neuschwanstein and used these values to compare against the efficiency calculated using available ground‐based infrasound data. This new numerical technique has allowed the source height to be determined independent of ray tracing solutions. We have also carried out theoretical ray tracing for a moving point source (not strictly a cylindrical line emission) and for an infinite speed line source. In addition, we have determined the ray turning heights as a function of the source height for both initially upward and downward propagating rays, independent of the explicit ray tracing (detailed propagation path) programs. These results all agree on the origins of the acoustic emission and explicit source heights for Neuschwanstein for the strongest infrasonic signals. Calculated source energies using more than four different independent approaches agree that Neuschwanstein was certainly <500 kg in initial mass, given the initial velocity of 20.95 km/s, resulting in an initial source energy ≤0.0157‐0.0276 kt TNT equivalent (4.185 times 10¹² J). Local source energies at the calculated infrasonic/seismic source altitudes are up to two orders of magnitude smaller than this initial source energy.     

Fossil midge associations and the historical status of fish in acidified lakes

Chaoborid and chironomid (Diptera) fossils were examined in sediment cores form nine Ontario Precambrian Shield lakes that were fishless in 1979. An abundance of Chaoborus americamus (intolerant of predation by fish) throughout cores from four lakes indicated that they were fishless historically. Occurrence of Chaoborus punctipennis and C. flavicans and absence of C. americanus in cores, except near the surface in two cases, indicated that four other lakes were inhabited by fish historically. One of these was probably periodically fishless as suggested by fluctuations among these Chaoborus species. The ninth lake was not suitable for Chaoborus; only one specimen of C. trivittatus was found in this core. Chironomid fossil associations were substantially different in historically fishless and inhabited lakes. Fishless lakes had chironomids typical of eutrophic conditions indicating that seasonal oxygen depletion likely was inimical to fish. Chironomid associations of oligotrophic waters occurred in lakes historically inhabited by fish. Both good water quality and accessibility were required for long-term habitation by fish. Partial recovery of alkalinity and rise in pH were accompanied by substantial re-invasion by fish in two lakes which had been inhabited historically by fish. Diptera associations provide valuable information on the historical suitability of lakes for fish and the presence/absence of fish in regions where acidification of surface waters has occurred.     

Chemical and mineralogical characterization of the Mineo (Sicily,Italy) pallasite: A unique sample

The Mineo pallasite is characterized here for the first time. The only 42 g still available worldwide is part of the collection of the Department of Physics and Geology, University of Perugia. A multianalytical approach was used, joining field-emission scanning electron microscopy, Raman analysis, X-ray powder diffraction, electron-probe microanalysis, and laser ablation inductively coupled plasma mass spectrometry. Results highlighted that (1) the Mineo pallasite belongs to the Main Group pallasites; (2) the silicate component is essentially olivine, with no pyroxene component; (3) the olivine chemical composition varies in terms of both iron and trace elements; (4) the metal phase is essentially kamacite with the taenite mainly found in the plessite structure; (5) phosphide phases are present as schreibersite and barringerite. The observed compositional variability in olivines as well as their occurrence as both angular and rounded crystals suggest that the Mineo pallasite could have been derived from a large impact of a differentiated parent body with a larger solid body. The resulting pallasite conglomerate consists of the compositionally different olivines, likely coming from different areas of the same differentiated parent body, and the residual molten Fe-Ni.     

Atmospheric forcing of the eastern tropical Pacific: A review

The increase in marine, land surface, atmospheric and satellite data during recent decades has led to an improved understanding of the air–sea interaction processes in the eastern tropical Pacific. This is also thanks to extensive diagnoses from conceptual and coupled ocean–atmosphere numerical models. In this paper, mean fields of atmospheric variables, such as incoming solar radiation, sea level pressure, winds, wind stress curl, precipitation, evaporation, and surface energy fluxes, are derived from global atmospheric data sets in order to examine the dominant features of the low level atmospheric circulations of the region. The seasonal march of the atmospheric circulations is presented to depict the role of radiative forcing on atmospheric perturbations, especially those dominating the atmosphere at low levels.In the tropics, the trade winds constitute an important north–south energy and moisture exchange mechanism (as part of the low level branch of the Hadley circulation), that determines to a large extent the precipitation distribution in the region, i.e., that associated with the Inter-Tropical Convergence Zone (ITCZ). Monsoonal circulations also play an important role in determining the warm season precipitation distribution over the eastern tropical Pacific through a large variety of air–sea–land interaction mechanisms. Westward traveling waves, tropical cyclones, low latitude cold air intrusions, and other synoptic and mesoscale perturbations associated with the ITCZ are also important elements that modulate the annual rainfall cycle. The low-level jets of the Gulf of California, the Intra-Americas Sea (Gulf of Mexico and Caribbean Sea) and Chocó, Colombia are prominent features of the eastern tropical Pacific low-level circulations related to sub-regional and regional scale precipitation patterns. Observations show that the Intra-Americas Low-Level Jet intensity varies with El Niño/Southern Oscillation (ENSO) phases, however its origin and role in the westward propagation and development of disturbances that may hit the eastern tropical Pacific, such as easterly waves and tropical cyclones, are still unclear. Changes in the intensity of the trade winds in the Caribbean Sea and the Gulf of Mexico (associated with eastern tropical Pacific wind jets) exert an important control on precipitation by means of wind–topography interactions. Gaps in the mountains of southern Mexico and Central America allow strong wind jets to pass over the continent imprinting a unique signal in sea surface temperatures and ocean dynamics of the eastern tropical Pacific.The warm pools of the Americas constitute an important source of moisture for the North American Monsoon System. The northeastern tropical Pacific is a region of intense cyclogenetic activity, just west of the coast of Mesoamerica. Over the oceanic regions, large-scale properties of key variables such as precipitation, moisture, surface energy fluxes and wind stress curl are still uncertain, which inhibits a more comprehensive view of the region and stresses the importance of regional field experiments. Progress has been substantial in the understanding of the ocean and atmospheric dynamics of the eastern tropical Pacific, however, recent observational evidence such as that of a shallow meridional circulation cell in that region, in contrast to the classic concept of the Hadley-type deep meridional circulation, suggests that more in situ observations to validate theories are still necessary.This paper is part of a comprehensive review of the oceanography of the eastern tropical Pacific Ocean.     

A degradation approach to accelerate simulations to steady-state in a 3-D tracer transport model of the global ocean

 We have developed a new method to accelerate tracer simulations to steady-state in a 3-D global ocean model, run off-line. Using this technique, our simulations for natural ¹⁴C ran 17 times faster when compared to those made with the standard non-accelerated approach. For maximum acceleration we wish to initialize the model with tracer fields that are as close as possible to the final equilibrium solution. Our initial tracer fields were derived by judiciously constructing a much faster, lower-resolution (degraded), off-line model from advective and turbulent fields predicted from the parent on-line model, an ocean general circulation model (OGCM). No on-line version of the degraded model exists; it is based entirely on results from the parent OGCM. Degradation was made horizontally over sets of four adjacent grid-cell squares for each vertical layer of the parent model. However, final resolution did not suffer because as a second step, after allowing the degraded model to reach equilibrium, we used its tracer output to re-initialize the parent model (at the original resolution). After re-initialization, the parent model must then be integrated only to a few hundred years before reaching equilibrium. To validate our degradation-integration technique (DEGINT), we compared ¹⁴C results from runs with and without this approach. Differences are less than 10‰ throughout 98.5% of the ocean volume. Predicted natural ¹⁴C appears reasonable over most of the ocean. In the Atlantic, modeled Δ¹⁴C indicates that as observed, the North Atlantic Deep Water (NADW) fills the deep North Atlantic, and Antartic Intermediate Water (AAIW) infiltrates northward; conversely, simulated Antarctic Bottom Water (AABW) does not penetrate northward beyond the equator as it should. In the Pacific, in surface eastern equatorial waters, the model produces a north–south assymetry similar to that observed; other global ocean models do not, because their resolution is inadequate to resolve equatorial dynamics properly, particularly the intense equatorial undercurrent. The model’s oldest water in the deep Pacific (at −239‰) is close to that observed (−248‰), but is too deep. Surface waters in the Southern Ocean are too rich in natural ¹⁴C due to inadequacies in the OGCM’s thermohaline forcing. Received: 18 March 1997 / Accepted: 27 July 1997     

Finite-difference migration of the field of refracted waves in studies of the deep structure of the Earth’s crust and the upper mantle based on the DSS (on the example of the <Emphasis Type="Italic">DOBRE</Emphasis> profile)

The main results of deep seismic sounding (DSS) are usually presented in the form of high-velocity models of the medium. Some model examples and the international DOBRE profile have shown that the informativeness of the data obtained can be significantly enhanced by the construction of wave images of the Earth’s crust, based on the migration of refracted and wide-angle reflected waves. The Donets Basin Refraction/Reflection Experiment (DOBRE) profile crosses the Dnieper-Donets paleorift zone in the Donbas region. Along the profile, refracted waves from the basement and the upper mantle and the reflections from the crust basement (the M boundary) are reliably traced. This wave migration has been used to construct a wave image of the structure of the Earth’s crust. As a result, a clear seismic image of the basement surface, whose depth changes along the profile from 0 to 20 km, was obtained. In near-slope parts of the basin, several major faults were identified that had not been identified previously during standard kinematic data processing. It is shown that the crust-upper mantle transition zone is a clearly reflective horizon only within the crystalline massifs; under a depression, it is represented by a lens-shaped highly-heterogeneous area. As shown in the model examples, the images obtained using such a migration accurately reflect the structural features of the medium, in spite of its complicated structure.     

Surface water quality evaluation in Odukpani, Calabar Flank, south-eastern Nigeria

 The present article is the second in a series of baseline water quality evaluation studies in parts of south-eastern Nigeria. Study results indicate that the water samples from the study are generally acidic, soft and fresh in addition to low sodium and salinity hazard. Regression equations indicate a good positive correlation between conductivity and Na, Ca, Mg and SO₄. Ca-SO₄ and Ca-Cl constitute the major facies in the area. Generally the waters in the area are good for most domestic and agricultural purposes. Received: 14 April 1997 · Accepted: 3 February 1998