Photoelectron fluxes in cometary atmospheres

The photoelectron fluxes in cometary atmospheres are calculated by a Monte Carlo method. This is the first quantitative model calculation of this kind. A pure H₂O atmosphere is assumed with a sublimation rate of 10³⁰ molecules sec^?1 at 1 AU. Discussions of the energetics of electron gas and of the elementary collisional processes in determining the fluxes largely concern this water atmosphere. Influences on the photoelectron fluxes are also investigated for CO, another possible constituent. The excitation rate of the ${}^1\text{D}$ level of atomic oxygen in electron impacts is evaluated. It is highly improbable that the photoelectrons are responsible for the observed 6300 Å emission of the order of 1 kR at a heliocentric distance of 1 AU. The structure of the heat equation for thermal electrons is analyzed and a drastic change of the plasma behavior within the coma region is expected.     

Type IV dm bursts: Onset and sudden reductions

The effect of collisions of suprathermal electrons with a thermal background plasma is investigated and is shown to cause flattening of a monotonically descending velocity distribution of fast particles. As a result flare-produced energetic electrons that are trapped in a coronal magnetic arch and that are initially distributed in energy according to a power-law, can give rise to an instability of Langmuir waves in the background plasma and the subsequent emission of continuum radiation as observed in type IV dm bursts.To explain the appearance of sudden reductions observed in type IV dm outbursts the effects both of magnetic compressions of the source region and of renewed injections of fast particles on the continuum source are investigated. It is found that the latter process can explain the observed reductions.     

Rare-earth elements in Lower Palaeozoic epicontinental and eugeosynclinal sediments from the Oslo and Trondheim regions

Eight rare-earth elements (REE) have been determined in Cambro-Silurian sediments and volcanics from nine stratigraphic units in the Trondheim Region and ten stratigraphic units in the Oslo Region by neutron-activation analyses. In the eugeosynclinal sediments from the Trondheim Region the REE variations are related to variations in source material, which mainly are volcanic debris of local origin. In the foreland sediments from the Oslo Region significant development of clays has occurred and therefore the REE variations reflect the deposition environment.     

Interpretation of faraday rotation in the galactic magnetic field

The autocorrelation function of Faraday rotation measures is discussed in terms of different types of galactic field configurations. The autocorrelation function evaluated from published data of 139 radio galaxies and quasars is found to resemble a form typical for a quasi-longitudinal field, whereas the autocorrelation function of 38 pulsars turns out to be of the form expected for a longitudinal field. These observations are interpreted with respect to the position of the solar system relative to the neutral sheet in a quasi-longitudinal field configuration.Rotation measures calculated theoretically using a mathematical formulation of the quasi-longitudinal field model are adapted to experimental data. The resulting polarity of the global field structure is discussed in connection with the original dipole-like configuration the magnetic momentum vector of which is found to have been antiparallel to the angular momentum vector of the Galaxy. The relation between the field strength and the density of electrons is found to be consistent with earlier results.     

A surface complexation model for cadmium and lead adsorption onto diatom surface

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.     

Holocene record of productivity in the NW Iberian continental shelf

A multiproxy approach (textural characteristics, heavy metal concentrations and benthic foraminifera data) was adopted to study the OMEX core KSGX 40, collected at the Galicia Mud Deposit (NW Iberian outer continental shelf) and recording the last ca. 4.8 ka cal BP. Geochemical profiles of Fe, Mn, Zn, Co, Cr, Cu, Ni, Pb, Al and Ca show significant temporal variations. Benthic foraminifera productivity proxy suggests that the recorded muddy events were contemporaneous of a higher C_org flux to the marine benthic environment. The higher flux of organic matter, following a long-term intensification of the upwelling and coinciding with a finer sedimentation, led to depressed levels of oxygen beneath the water-sediments interface and to early diagenetic processes of several redox-sensitive elements.