Laboratory kinetics of C2H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.     

Small hypervelocity particles captured in aerogel collectors: Location,extraction, handling and storage

Abstract— It has now been about a decade since the first demonstrations that hypervelocity particles could be captured, partially intact, in aerogel collectors. But the initial promise of a bonanza of partially‐intact extraterrestrial particles, collected in space, has yet to materialize. One of the difficulties that investigators have encountered is that the location, extraction, handling and analysis of very small (10 μm and less) grains, which constitute the vast majority of the captured particles, is challenging and burdensome. Furthermore, current extraction techniques tend to be destructive over large areas of the collectors. Here we describe our efforts to alleviate some of these difficulties. We have learned how to rapidly and efficiently locate captured particles in aerogel collectors, using an automated microscopic scanning system originally developed for experimental nuclear astrophysics. We have learned how to precisely excavate small access tunnels and trenches using an automated micromanipulator and glass microneedles as tools. These excavations are only destructive to the collector in a very small area—this feature may be particularly important for excavations in the precious Stardust collectors. Using actuatable silicon microtweezers, we have learned how to extract and store “naked” particles—essentially free of aerogel—as small as 3 μm in size. We have also developed a technique for extracting particles, along with their terminal tracks, still embedded in small cubical aerogel blocks. We have developed a novel method for storing very small particles in etched nuclear tracks. We have applied these techniques to the extraction and storage of grains captured in aerogel collectors (Particle Impact Experiment, Orbital Debris Collector Experiment, Comet‐99) in low Earth orbit.     

The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv     

Pulsar Wind Nebulae in Egret Error Boxes

A remarkable number of pulsar wind nebulae (PWN) are coincident with EGRET γ-ray sources. X-ray and radio imaging studies of unidentified EGRET sources have resulted in the discovery of at least six new pulsar wind nebulae (PWN). Stationary PWN (SPWN) appear to be associated with steady EGRET sources with hard spectra, typical for γ-ray pulsars. Their toroidal morphologies can help determine the geometry of the pulsar which is useful for constraining models of pulsed γ-ray emission. Rapidly moving PWN (RPWN) with more cometary morphologies seem to be associated with variable EGRET sources in regions where the ambient medium is dense compared to what is typical for the ISM.     

Five WC9 stars discovered in the AAO/UKST Hα survey

We report the discovery of five massive Wolf–Rayet (WR) stars resulting from a programme of follow-up spectroscopy of candidate emission-line stars in the Anglo-Australian Observatory United Kingdom Schmidt Telescope (AAO/UKST) Southern Galactic Plane Hα survey. The 6195–6775 Å spectra of the stars are presented and discussed. A WC9 class is assigned to all five stars through comparison of their spectra with those of known late-type WC stars, bringing the known total number of Galactic WC9 stars to 44. Whilst three of the five WC9 stars exhibit near-infrared (NIR) excesses characteristic of hot dust emission (as seen in the great majority of known WC9 stars), we find that two of the stars show no discernible evidence of such excesses. This increases the number of known WC9 stars without NIR excesses to seven. Reddenings and distances for all five stars are estimated.     

Entry dynamics and acoustics/infrasonic/seismic analysis for the Neuschwanstein meteorite fall

Abstract— We have analyzed several types of data associated with the well‐documented fall of the Neuschwanstein meteorites on April 6, 2002 (a total of three meteorites have been recovered). This includes ground‐based photographic and radiometer data as well as infrasound and seismic data from this very significant bolide event (Spurný et al. 2002, 2003). We have also used these data to model the entry of Neuschwanstein, including the expected dynamics, energetics, panchromatic luminosity, and associated fragmentation effects. In addition, we have calculated the differential efficiency of acoustical waves for Neuschwanstein and used these values to compare against the efficiency calculated using available ground‐based infrasound data. This new numerical technique has allowed the source height to be determined independent of ray tracing solutions. We have also carried out theoretical ray tracing for a moving point source (not strictly a cylindrical line emission) and for an infinite speed line source. In addition, we have determined the ray turning heights as a function of the source height for both initially upward and downward propagating rays, independent of the explicit ray tracing (detailed propagation path) programs. These results all agree on the origins of the acoustic emission and explicit source heights for Neuschwanstein for the strongest infrasonic signals. Calculated source energies using more than four different independent approaches agree that Neuschwanstein was certainly <500 kg in initial mass, given the initial velocity of 20.95 km/s, resulting in an initial source energy ≤0.0157‐0.0276 kt TNT equivalent (4.185 times 10¹² J). Local source energies at the calculated infrasonic/seismic source altitudes are up to two orders of magnitude smaller than this initial source energy.     

The first and second order moments of the polarization profiles of hydrogen lines

The main properties of the first- and second-order moments of polarized hydrogen lines, forming in the presence of stationary electric and magnetic fields, are reviewed. The analytical results presented here apply directly to the case of optically-thin emission lines in the LTE regime. Some applications of such results to electric- and magnetic-field diagnostics in (solar) plasmas are then briefly considered.On leave from the Dipartimento di Astronomia e Scienza dello Spazio, Università di Firenze, Largo E. Fermi 5, I-50125 Firenze, Italy