Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

Influence of the total atmospheric optical depth and cloud cover on solar irradiance components

Broadband solar irradiance data obtained in the spectral range 400–940 nm at Kwangju, South Korea from 1999–2000 have been analyzed to investigate the effects of cloud cover and atmospheric optical depth on solar radiation components. Results from measurements indicate that the percentage of direct and diffuse horizontal components of solar irradiance depend largely on total optical depth (TOD) and cloud cover. During summer and spring, the percentages of diffuse solar irradiance relative to the global irradiance were 5.0% and 4.9% as compared to 2.2% and 3.0% during winter and autumn. The diffuse solar irradiance is higher than the direct in spring and summer by 24.2%, and 40.6%, respectively, which may largely be attributed to the attenuation (scattering) of radiation by heavy dust pollution and large cloud amount. In cloud-free conditions with cloud cover ≤2/10, the fraction of the direct and diffuse components were 66.0% and 34.0%, respectively, with a mean daily global irradiance value of 7.92±2.91 MJ m⁻² day⁻¹. However, under cloudy conditions (with cloud cover ≥8/10), the diffuse and direct fractions were 97.9% and 2.2% of the global component, respectively. The annual mean TOD under cloudless conditions (cloud cover≤2/10) yields 0.74±0.33 and increased to as much as 3.15±0.67 under cloudy conditions with cloud amount ≥8/10. An empirical formula is derived for estimating the diffuse and direct components of horizontal solar irradiance by considering the total atmospheric optical depth (TOD). Results from statistical models are shown for the estimation of solar irradiance components as a function of TOD with sufficient accuracy as indicated by low standard error for each solar zenith angle (SZA).     

Numerical Modeling of Ice Jams

A numerical model is proposed to describe the formation of ice jams under the effect of a release wave.     

Study of Heavy Metal Compound Transformations in Surface Waters

Results of studying Fe(III) hydrolysis and sorption of heavy metal compounds by organic matter of bottom sediments are discussed. The rate of Fe(III) hydrolysis is found to be largely determined by the concentration of dissolved organic substances. Values of kinetic parameters are obtained for heavy metal compounds sorption under static and dynamic conditions. Calculating the solubility of Fe, Cu, Cd, Zn, and Pb sulfides allowed the assessment of the amount of metals lost by bottom sediments due to the formation of metal complexes with dissolved organic substances contained in natural waters.     

Geographical and Ecological Characteristics of the Caspian Sea and Modern Tendencies in the Evolution of Its Ecosystem

The Caspian Sea is characterized in the geographic and ecological aspects, and the state of its ecosystem is estimated. The natural and anthropogenic processes that control the formation of the environmental conditions in the Caspian Sea and the distribution of principal commercial hydrobionts and their food items are analyzed. Data on modern tendencies in changes in the abiotic and biotic parameters of the ecosystem, their causes and mechanisms are summarized. Prospects of further changes related to the development of shelf fields of petroleum hydrocarbons are assessed.     

Nutrient Transport into the White Sea with River Runoff

Averaged data from long-term observations of concentrations of mineral-nutrient fractions along with fragmentary data and indirect estimates of organic-component concentrations in the tributaries of the sea (the Niva, the Onega, the Northern Dvina, the Mezen, and the Kem rivers) are analyzed. Monthly variations in the concentrations of the major nutrients in the river water flowing into the sea are characterized, and relationships between them in different seasons are determined. Annual nutrient transport into the White Sea by river water is assessed based on characteristics of river runoff and nutrient concentrations using a mathematical model. Wide variations are established in the ratios of organic and mineral fractions of nutrients delivered into the sea. The shares of mineral components in the total runoff of N_tot and P_tot into the sea are found to be equal to 18.1 and 18.8%, respectively.     

In-plane and anti-plane strong shaking of soil systems and structures

The concept of in-plane and anti-plane shaking is introduced with a rigid block on a plane surface with Coulomb friction. Using a hypoplastic constitutive relation to model the mechanical behaviour of the soil, numerical solutions for a rigid block on a thin dry or saturated soil layer are obtained. The coupled nature of dynamic problems involving granular materials is shown, i.e. the motion of the block changes the soil state—skeleton stresses and density—which in turn affects the block motion. Motions of the block as well as soil response can be more realistically calculated by the new model. The same constitutive equation is applied to the numerical simulation of the propagation of plane waves in homogeneous and layered level soil deposits induced by a wave coming from below. Experiments with a novel laminar shake box as well as real seismic records from well-documented sites during strong earthquakes are used to verify the adequacy of the hypoplasticity-based numerical model for the prediction of soil response during strong earthquakes. The response of a homogeneous earth dam subjected to in-plane and anti-plane shaking is investigated numerically. In-plane and anti-plane shaking is shown to cause nearly the same spreading of a sand dam under drained conditions, whereas under undrained conditions anti-plane shaking causes stronger spreading of the dam. The dynamic behaviour of a breakwater founded on rockfill and soft clay during the 1995 Kobe earthquake is back-calculated to show the good performance of the proposed numerical model also with a structure. Section 9 deals with buildings on mattresses of densified cohesionless soils or fine-grained soils with granular columns, slopes with ‘hidden’ dams and structures on piles traversing clayey slopes to show the suitability of hypoplasticity-based models for the earthquake-resistant design and safety assessment of geotechnical systems.     

Role of Wavelets in the Physical and Statistical Modelling of Complex Geological Processes

— Today, wavelets are recognized to have a wide range of useful properties that allow them to treat effectively multifacet problems, such as data compression, scale-localization analysis, feature extraction, statistics, numerical simulation, visualization, and communication. Second-generation wavelets represent a recent improvement of the wavelet algorithm, allowing for greater flexibility in the spatial domain and other computational advantages. We will show how these wavelets can be employed to extract large-scale coherent structures from (1) three-dimensional turbulent flows and (2) high Rayleigh number thermal convection. We will discuss the concept of modelling via decomposition into coherent and incoherent fields, taking into account the effect of the incoherent field via statistical modelling. We will discuss wavelet properties and how they can be utilized and integrated in handling large-scale problems in earthquake physics and other nonlinear phenomena in the geosciences.     

Hydro-thermal performance of multilayer capillary barriers in arid lands

In this study, a capillary barrier system was designed and tested for an arid land environment. To simulate arid land conditions of high temperature and sub-irrigation systems, the barrier was subjected to thermal and hydraulic gradients in opposite directions; to test the barrier system under these severe conditions, an experimental apparatus was designed and fabricated. The multilayer capillary barrier consisted of three layers made of silica sand, a mixture of sand and bentonite in equal portions, and a mixture of clay (25%) and aggregate (75%). Several one dimensional coupled heat and moisture tests were performed. Temperature variations along the thickness of the barrier were recorded as a function of time, and at the end of each test, the barrier was sliced into small sections, for the determination of volumetric water content as a function of distance from the heat source. The experimental results were discussed in view of the barrier's intended purpose of its ability to store moisture for long time durations. Coupled heat and moisture flow equations were developed and solved numerically via a finite difference method. Diffusivity parameters were calculated by using experimental results, a numerical model, and Powell's conjugate directions method of nonlinear optimization. The model was calibrated and the results were discussed. Good agreement between calculated and experimental results was obtained. This revised version was published online in July 2006 with corrections to the Cover Date.