Offshore experiments on styrene spillage in marine waters for risk assessment

Within the context of risk evaluation of chemical spillages into the marine environment, this paper reports on an offshore experiment to study the behaviour of styrene spilled into sea under natural conditions and discusses theoretical approaches. Floating structures were used to enclose the spillage and the gaseous cloud formation, and dissolution processes were in situ monitored. The identification of spill risks for man and marine environment through GESAMP's hazard profile is described for styrene: Styrene is rated as a chemical with a significant health hazard that will float but also evaporate. However, monitoring of the water column in the experiments showed that the concentration of styrene in water during the first hour represents 50% of the product spilled. For the potentially exposed public, the GESAMP hazard rating recommends the closure of beaches and evacuation. The risk assessment developed from experimental data confirms this safety advice.     

快速钻进冲洗液在地浸砂岩型铀矿的应用试验

针对地浸砂岩型铀矿塔木素工作区钻孔施工中发生的孔壁失稳、卡钻埋钻、钻速低等复杂问题,通过快速钻进冲洗液技术的试验应用,有效地防止泥岩地层水化膨胀;抑制岩屑分散,保持孔底清洁,有效地降低钻具摩擦和扭矩,降低了自然事故的发生率,提高了泥岩和砂岩的机械钻速,降低了钻探成本。     

可循环微泡沫及其应用

与普通泡沫相比,微泡沫的特殊结构使其具有优良的流动性能。微泡沫钻探具有普通泡沫钻探技术的优良特性:低密度、携岩能力强、节水、机械钻速高、保护岩心等。同时,微泡沫克服了普通泡沫的缺陷:需要空压机、发泡器和高压管线等设备和不能循环造成的浪费和环境污染,微泡沫钻井液可在现场利用常规搅拌设备配制和泥浆泵循环使用。可循环微泡沫钻井液将在深部找矿中发挥重要作用。介绍了微泡钻井液特性,并结合现场实践讨论了可循环微泡钻探技术在岩心钻探和油气勘探中的多重功效。     

包括前震和余震的不含时间的地震危险性概率分析

在不含时间的地震危险性概率分析中,每个震源都被视为在时间和空间上无关。因此,在时间和空间上都依赖主震的前震和余震都不被列入地震目录。然而,事实表明,这些地震能够产生破坏性地震动,应该被认为是构成地震危险性的一部分。本研究将主震及其相关地震作为时间不相关的群体,每个群体在时间和空间上都与其他任何群体无关,且都具有主震的复发时间。通过将震群中的地震视为事件的并,相关事件都会对地震动和危险性有贡献。根据美国地质调查局的高危险性场地判别方法,纳入相关事件使超过工程意义概率水平的地震动增加了约10％,但如果能够可靠地计算余震发生量的变化,这个增加量可能会高达20％。     

北吕宋岛菲律宾活动带蛇绿岩及其上覆浊积岩的放射虫研究新进展

The basement of the Philippine Mobile Belt (PMB) is mainly composed of ophiolites that are mostly overlain by Paleogene to Miocene turbidites in central Luzon. To clarify the geological development of the PMB with respect to the initial stage of the arc volcanism (eg. Yumul et al., 2003, 2008; Dimalanta and Yumul, 2003; Suzuki et al., 2011), radiolarian dating was examined in siliceous sediments associated with the ophiolites and turbidites. The samples were collected from sites identified with the Zambales and Montalban ophiolites, basic tuff phyllites in NW Din-galan, and their overlying formations.     

Evidence for polychlorinated biphenyls dechlorination in the sediments of Sado Estuary, Portugal

Sediment gravity cores and grab samples were collected in the Sado Estuary and in its coastal area. The cores were sliced on board and the percentage of weight loss on ignition was determined in the laboratory, and analysed for polychlorinated biphenyl (PCB) congeners. PCB contents were higher in samples from the North Channel of the estuary, nearby the industrial zone (max. 114 ng g-1 dry weight), while levels in the coastal area were lower than 4.9 ng g-1. The concentrations of the quantified congeners varied irregularly with sediment depth in the estuary, but showed two opposite distribution patterns in cores from the coastal area: the proportions of lower chlorinated congeners increased with depth, while congeners with higher number of chlorines decreased. This suggests a dechlorination of the most chlorinated congeners into less toxic compounds, under reductive conditions of the sediment. Though measurements were done in natural environment it appears that dechlorination was not entirely dependent on chlorine position in the phenyl rings.     

Bather density as a predominant factor for health effects related to recreational bathing: results from the Greek bathers cohort study

Our aim was to examine the health effects on bathers from exposure to recreational seawater on three beaches with different microbiology quality and bather density through a cohort study. An initial questionnaire and a 10 day follow up were used. Univariate and backward logistic regression analyses were used to asses the risk of developing symptoms or diseases among the bathers. In total, 3805 bathers were included in the study and 149 samples were collected from the three beaches. Despite all the beaches being characterized of high quality the levels of bacterial indicators differed among them. Health effects among bathers were not associated with bacterial indicators. A statistically significant increased risk for symptoms related to respiratory illness, gastroenteritis, medical consultation and use of medication was observed among bathers at the higher bather density beaches. Beach bather numbers should always be taken into account when considering a risk assessment approach.     

Spatial and temporal changes in microbial diversity of the Marmara Sea sediments

Spatial (10 different locations) and temporal (2 years) changes in characteristics of the Marmara Sea Sediments were monitored to determine interactions between the chemical and microbial diversity. The sediments were rich in terms of hydrocarbon, nitrate, Ni and microbial cell content. Denitrifying, sulfate reducing, fermentative and methanogenic organisms were co-abundant in 15 cm below the sea floor. The local variations in the sediments’ characteristics were more distinctive than the temporal ones. The sulfate and nitrate contents were the main drivers of the changes in the microbial community compositions. N and P were limited for microbial growth in the sediments, and their levels determined the total cell abundance and activity. Seasonal shifts in temperatures of the shallow sediments were also reflected in the active cell abundances. It was concluded that the Marmara Sea is a promising ecosystem for the further investigation of the ecologically important microbial processes.     

Distribution of heavy metals in soils of Port Harcourt and its environs,Niger Delta,Nigeria

Geochemical evaluation of the distribution of heavy metals in soils of Port Harcourt and its environs in the Niger Delta region is presented in respect of anthropogenic factor and index of geoaccumulation. Sixteen (16) soil samples were collected from two horizons (0-10 cm and 100 cm) from the various grids and analyzed. The geo-chemical analyses showed the vertical and horizontal distributions of heavy metals. The results showed the ranges of the metals determined as follows: Pb (6.86-2.49)×10-6, with an average of 4.63×10-6; Cd (0.05-0.00)×10-6, with an average of 0.02×10-6, As (0.01-0.00)×10-6, with an average of 0.00×10-6. Cu (15.36-10.80) ×10-6, with an average of 13.36×10-6, and V (1.36-0.20)×10-6, with an average of 0.94×10-6. Quantification of the degree of pollution was carried out using anthropogenic factor (AF) and index of geoaccumulation (Igeo). The Igeo values of 0.06, 0.02 and 0.00 for Pb, Cd and As, respectively indicate low-level contamination while Zn (1.14) and V (1.40) show me-dium-level contamination. The sources of contamination are attributed to urbanized anthropogenic activities. The majority of the samples analyzed show that the AF values are less than 1 with the exception of vanadium (V) whose AF values range from 2.73 to 13.60×10-6. Vanadium is more enriched than As, Cd, Pb, and Cu. The order of degrees of anthropogenic contamination and index of geoaccumulation in the soil is V >Zn >Pb >Cu >Cd >AS. Metals were retained near the top soil and their concentrations in the deepest horizons were lower and normal for uncontaminated soils. Metal concentrations in the top soil horizons were significantly related to distance from the industrial and hu-man activities.     

中国东海和韩国马山湾海域2株原甲藻的形态结构和分子序列比较

对采自我国东海温岭海域和韩国南部马山湾海域的2株原甲藻进行了藻种分离、纯化培养及rDNA ITS分子序列的PCR扩增与测序,并运用显微镜、扫描电镜、Jukes-Cantor距离矩阵及构建的系统发育树,比较研究了2株原甲藻的形态结构和分子序列.结果表明:温岭藻株(LAMB090508)和马山湾藻株(PDKS0206)具有...