Generation of electromotive force in igneous rocks subjected to non-uniform loading

When one end of an air-dry igneous rock block was uniaxially loaded in laboratory, there appeared an electromotive force that made electric currents flow from the stressed volume to the unstressed volume. Quartz-free rocks such as gabbro also generated this force, stronger than quartz-bearing rocks such as granite. This indicates that the piezoelectric effect of quartz and the electrokinetic effect of pore water do not make a large contribution toward generating the electromotive force. We focus on peroxy bond that is one of the abundant lattice defects in igneous rock-forming minerals. When mechanical loading deforms the lattice structure around this defect and breaks its bond, its energy levels change and act like an accepter. As an electron is trapped at this defect from a neighbor O^2- site, a positive hole is activated there. They attempt to diffuse toward the unstressed volume through the valence band and are simultaneously affected by the attractive electric force with the electrons trapped in peroxy bonds. This leads to a polarization in the stressed volume and the generation of electromotive force between the stressed and unstressed volumes. Similar electromotive force may be generated in the Earth's crust where inhomogeneous stress/strain is changing.     

Effects of tributyltin at concentrations below ambient levels in seawater on Caprella danilevskii (Crustacea: Amphipoda: Caprellidae)

Hatched juveniles of Caprella danilevskii (Crustacea: Amphipoda) were exposed to one of two concentrations of tributyltin (TBT) (1.1 and 10.7 ng TBTL(-1)) for 49 d at 20 degrees C. These concentrations are near or below ambient levels in seawater. In both treatments and control, the survival rate was 100% at maturation, and >85% at the end of the experiments. Females reached maturation at 20 (median) to 21.5d at instar VII, and repeated spawning 4-5 times during the experiment. The total number of juveniles per female decreased significantly from 39.5 in the control to 24.5 and 17.5 in 1.1 ng L(-1) and 10.7 ng L(-1) treatments, respectively. An earlier study reported that as the TBT concentration in seawater increased from a 0-10 ng L(-1) regime to a 10-20 ng L(-1) regime, the number of stations where Caprella spp. could be collected decreased along the coast of the Seto Inland Sea, of Japan. Thus, the present study indicates the possibility that the extremely low concentration of TBT measured in Japanese waters after 2000 lead to a reduction in reproductive success of Caprella spp.     

Response of Equatorial Pacific Mean Temperature Field to Intraseasonal Wind Forcing

The effects of intra-seasonal wind forcing on the mean field of the tropical Pacific Ocean has been studied using an ocean general circulation model (GCM). Idealized intra-seasonal zonal wind forcing with zero mean, which propagates eastward, induces net eastward jets at the equator that shift the warm water pool to the east. The mean temperature of the upper 200 m of the ocean increases off the equator and decreases at the equator. The change is independent of the propagation speed of the intra-seasonal wind forcing. The magnitude of the change depends on the amplitude and the period of the forcing, and the ocean structure, while the spatial pattern is independent of these parameters. A simple shallow water model is used to explain these changes. It is found that the term responsible for the enhanced eastward Equatorial jet is the Reynolds stress term, which arises from a phase shift of the zonal current due to friction. The resultant convergence of eastward momentum on the equator and geostrophic adjustment of the interface to the change of zonal current brings about the thermal redistribution of the upper ocean seen in the GCM.     

Equatorward Spreading of a Passive Tracer with Application to North Pacific Interdecadal Temperature Variations

A simulation is conducted with a realistic ocean general circulation model to investigate the three dimensional spreading of a passive tracer prescribed at the sea surface with the same distribution as the interdecadal sea surface temperature (SST) anomalies observed in the North Pacific. The tracers reaching the equator have the same sign as the major oval-shaped SST anomaly pattern in the central North Pacific but with a magnitude reduced less than 10% of the mid-latitude SST anomaly. The mixing both with the water containing SST anomalies of an opposite sign off the west coast of North America, and with the Southern Hemisphere thermocline water both contribute to the reduced equatorial amplitude. On the way to the equator in the southwestern part of the subtropical gyre, the subducted water is replenished by tracers leaking from the recirculation region to the north. The simulated passive tracer field in the subsurface layers agrees with the observed interdecadal temperature anomalies, suggesting the relevance of the processes studied here to the thermocline variability in the real North Pacific.     

Biomagnification profiles of polycyclic aromatic hydrocarbons, alkylphenols and polychlorinated biphenyls in Tokyo Bay elucidated by δC and δN isotope ratios as guides to trophic web structure

Biomagnification profiles of polycyclic aromatic hydrocarbons (PAHs), alkylphenols, and polychlorinated biphenyls (PCBs) from the innermost part of Tokyo Bay, Japan were analyzed using stable carbon (δ¹³C) and nitrogen (δ¹⁵N) isotope ratios as guides to trophic web structure. δ¹⁵N analysis indicated that all species of mollusks tested were primary consumers, while decapods and fish were secondary consumers. Higher concentrations of PCBs occurred in decapods and fish than in mollusks. In contrast, concentrations of PAHs and alkylphenols were lower in decapods and fish than in mollusks. Unlike PCBs, whose concentrations largely increased with increasing δ¹⁵N (i.e. increasing trophic level), all PAHs and alkylphenols analyzed followed a reverse trend. Molecular weights of PAHs are lower than those of PCBs, therefore low membrane permeability caused by large molecular size is an unlikely factor in the “biodilution” of PAHs. Organisms at higher trophic levels may rapidly metabolize PAHs or they may assimilate less of them.     

Sumisu volcano,Izu-Bonin arc,Japan: site of a silicic caldera-forming eruption from a small open-ocean island

Sumisu volcano was the site of an eruption during 30–60 ka that introduced ∼48–50 km³ of rhyolite tephra into the open-ocean environment at the front of the Izu-Bonin arc. The resulting caldera is 8 × 10 km in diameter, has steep inner walls 550–780 m high, and a floor averaging 900 m below sea level. In the course of five research cruises to the Sumisu area, a manned submersible, two ROVs, a Deep-Tow camera sled, and dredge samples were used to study the caldera and surrounding areas. These studies were augmented by newly acquired single-channel seismic profiles and multi-beam seafloor swath-mapping. Caldera-wall traverses show that pre-caldera eruptions built a complex of overlapping dacitic and basaltic edifices, that eventually grew above sea level to form an island about 200 m high. The caldera-forming eruption began on the island and probably produced a large eruption column. We interpret that prodigious rates of tephra fallback overwhelmed the Sumisu area, forming huge rafts of floating pumice, choking the nearby water column with hyperconcentrations of slowly settling tephra, and generating pyroclastic gravity currents of water-saturated pumice that traveled downslope along the sea floor. Thick, compositionally similar pumice deposits encountered in ODP Leg 126 cores 70 km to the south could have been deposited by these gravity currents. The caldera-rim, presently at ocean depths of 100–400 m, is mantled by an extensive layer of coarse dense lithic clasts, but syn-caldera pumice deposits are only thin and locally preserved. The paucity of syn-caldera pumice could be due to the combined effects of proximal non-deposition and later erosion by strong ocean currents. Post-caldera edifice instability resulted in the collapse of a 15° sector of the eastern caldera rim and the formation of bathymetrically conspicuous wavy slump structures that disturb much of the volcano’s surface.     

Out‐of‐plane stability assessment of buckling‐restrained braces including connections with chevron configuration

One of the key limit states of buckling‐restrained braces (BRBs) is global flexural buckling including the effects of the connections. The authors have previously proposed a unified explicit equation set for controlling the out‐of‐plane stability of BRBs based on bending‐moment transfer capacity at the restrainer ends. The proposed equation set is capable of estimating BRB stability for various connection stiffnesses, including initial out‐of‐plane drift effects. However, it is only valid for symmetrical end conditions, limiting application to the single diagonal configuration. In the chevron configuration, the out‐of‐plane stiffness in the two ends differs because of the rotation of the attached beam. In this study, the equation set is extended to BRBs with asymmetric end conditions, such as the chevron configuration. Cyclic loading tests of the chevron configuration with initial out‐of‐plane drifts are conducted, and the results are compared with the proposed equation set, which is formulated as a function of the normalized stiffness of the attached beam. © 2016 The Authors. Earthquake Engineering & Structural Dynamics published by John Wiley & Sons Ltd. © 2016 The Authors. Earthquake Engineering & Structural Dynamics published by John Wiley & Sons Ltd.     

Deep-sea submersible survey in the Suruga, Sagami and Japan Trenches: preliminary results of the 1985 Kaiko cruise, Leg 2

Nine submersible dives were made in three trenches off central Japan, between 2990 and 5900 m of water depth. Our observations confirm the interpretation that Daiichi-Kashima Seamount is a Cretaceous guyot formed on the Pacific plate that has traveled into the Japan Trench. We also confirmed the previous interpretation of a large normal fault that splits the seamount in two halves, the lower one being now subducting beneath the Japan margin. Compressional deformation was identified within the lower part of the inner slope in front of the seamount. The pattern of deformation that affects Quaternary sediments is in agreement with the present kinematics of the convergence between the Pacific plate and Japan. Deep-water (5700 m) clam colonies are associated with advection of fluids, driven by the subduction-related overpressures. In the northern slope of the Boso Canyon, along the Sagami Trough system (Philippine Sea plate-Japan boundary), the deformation affecting a thick upper Miocene to lower Pliocene sequence indicates two directions of shortening: a N175°E direction which is consistent with the present relative motion along the Sagami Trough (N285–N300°E) and a N30°E direction which could be related to a more northerly direction of convergence that occured during the early Quaternary and earlier.     

Elastic properties of the olivine and spinel polymorphs of Mg2GeO4, and evaluation of elastic analogues

The single-crystal elastic moduli of the olivine and spinel phases of Mg₂GeO₄ have been measured using Brillouin scattering spectra. The moduli for the olivine phase are: C₁₁ = 3.12, C₂₂ = 1.87, C₃₃ = 2.17, C₆₆ = 0.71, C₂₃ = 0.66, C₃₁ = 0.65 and C₁₂ = 0.60. The moduli for the spinel phase are: C₁₁ = 3.00, C₄₄ = 1.26 and C₁₂ = 1.18.These data are analyzed to define the best type of elastic analogue for magnesium orthosilicates. The character of the many-bodied, non-central force associated with the divalent cation is found to significantly influence the relative magnitudes of the elastic moduli. Since the nature of the many-bodied, non-central force is quite different for alkaline earth cations than for transition metal cations, we conclude that materials which contain one of these cation types is not a good analogue for materials with the other type. Magnesium orthogermanate, however, is a good analogue of magnesium orthosilicate. On the other hand, the high elastic anisotropy of the spinel phase of the germanate suggests that the germanium tetrahedron is less rigid under shear than the corresponding silicon tetrahedron. The success of the magnesium orthogermanate to model the magnesium orthosilicate is probably a result of the mechanical isolation of the tetrahedra, thus requiring the conclusions of this study to be further tested before applying them to other silicate systems.