The effect of phytostabilization on Zn speciation in a dredged contaminated sediment using scanning electron microscopy, X-ray fluorescence, EXAFS spectroscopy, and principal components analysis

The maintenance of waterways generates large amounts of dredged sediments, which are deposited on adjacent land surfaces. These sediments are often rich in metal contaminants and present a risk to the local environment. Understanding how the metals are immobilized at the molecular level is critical for formulating effective metal containment strategies such as phytoremediation. In the present work, the mineralogical transformations of Zn-containing phases induced by two graminaceous plants (Agrostis tenuis and Festuca rubra) in a contaminated sediment ([Zn] = 4700 mg kg⁻¹, [P₂O₅] = 7000 mg kg⁻¹, pH = 7.8), untreated or amended with hydroxylapatite (AP) or Thomas basic slag (TS), were investigated after two yr of pot experiment by scanning electron microscopy coupled with energy-dispersive spectrometry (SEM-EDS), synchrotron-based X-ray microfluorescence (μ-SXRF), and powder and laterally resolved extended X-ray absorption fine structure (μ-EXAFS) spectroscopy. The number and nature of Zn species were evaluated by principal component (PCA) and least-squares fitting (LSF) analysis of the entire set of μ-EXAFS spectra, which included up to 32 individual spectra from regions of interest varying in chemical composition. Seven Zn species were identified at the micrometer scale: sphalerite, gahnite, franklinite, Zn-containing ferrihydrite and phosphate, (Zn-Al)-hydrotalcite, and Zn-substituted kerolite-like trioctahedral phyllosilicate. Bulk fractions of each species were quantified by LSF of the powder EXAFS spectra to linear combinations of the identified Zn species spectra.In the untreated and unvegetated sediment, Zn was distributed as ∼50% (mole ratio of total Zn) sphalerite, ∼40% Zn-ferrihydrite, and ∼10 to 20% (Zn-Al)-hydrotalcite plus Zn-phyllosilicate. In unvegetated but amended sediments (AP and TS), ZnS and Zn-ferrihydrite each decreased by 10 to 20% and were replaced by Zn-phosphate (∼30∼40%). In the presence of plants, ZnS was almost completely dissolved, and the released Zn bound to phosphate (∼40-60%) and to Zn phyllosilicate plus (Zn,Al)-hydrotalcite (∼20-40%). Neither the plant species nor the coaddition of mineral amendment affected the Zn speciation in the vegetated sediment. The sediment pore waters were supersaturated with respect to Zn-containing trioctahedral phyllosilicate, near saturation with respect to Zn-phosphate, and strongly undersaturated with respect to (Zn,Al)-hydrotalcite. Therefore, the formation of (Zn,Al)-hydrotalcite in slightly alkaline conditions ought to result from heterogeneous precipitation on mineral surface.     

The Plio-Pleistocene evolution of the Southern Middle Atlas Fault Zone (SMAFZ) front of Morocco

The South Middle Atlas front constitutes a northeast-trending shear zone, located north of the Neogene Missour basin and east of the Taza Guercif basin. This paper analyses the Southern Middle Atlas Fault Zone (SMAFZ) deformation since the Pliocene. The set of structures observed suggests that reverse and thrust faulting along the central part of the SMAFZ are combined with left-lateral slip along N–S striking faults of its south-western termination and right-lateral faulting along E–NE striking faults of the east–northeast termination. Thrusts and oblique thrust-related anticlines of the two lateral ramps partly accommodate north-west directed motion of the African plate. The Thrusts probably resulted from rejuvenation of Jurassic normal faults; they were active during the Upper Miocene–Pliocene and the Pleistocene. The geometries of positive inversion structures and buttressing effects are clearly dependent on the geometry and sedimentology of the original basin-controlling fault system and on the presence of a décollement level. Field mapping is integrated with Landsat imagery and a digital elevation model to investigate the morphotectonic evolution of the south-eastern range front of the Middle Atlas. Geomorphological features provide significant information on the processes that govern lateral propagation of active anticlines. Both suggest that the deformation front may have been active since Pliocene.     

JHomogenizer: a computational tool for upscaling permeability for flow in heterogeneous porous media

This paper presents an object-oriented programming approach for the design of numerical homogenization programs, called JHomogenizer. It currently includes five functional modules to compute effective permeability and simple codes for computing solutions for flow in porous media. Examples with graphical output are shown to illustrate some functionalities of the program. A series of numerical examples demonstrates the effectiveness of the methodology for two-phase flow in heterogeneous reservoirs. The software is freely available, and the open architecture of the program facilitates further development and can adapt to suit specific needs easily and quickly.     

Isothermal decompression of garnet metabasites from Laouni terrane in the LATEA,Central Hoggar,Algeria

We study the first occurrence of clinopyroxene-free garnet bearing metabasites encased in migmatitic gneisses and metapelites, in the area of Tin Begane belonging to the Laouni terrane in the Pan-African Trans-Saharan belt (Hoggar, Algeria). They present two successive parageneses after a primary assemblage characterized by the presence of high titanium amphiboles equilibrated with coarse-grained garnet, plagioclase, biotite, quartz, and rutile. The two retrograde parageneses show decompression textures with the developing of coronas- and worm-like symplectites consisting of orthopyroxene + plagioclase ± amphibole for the secondary paragenesis and plagioclase + amphibole for the late stage paragenesis. These garnet metabasites do not show high pressure paragenesese compared to those previously studied from the Laouni terrane and which are known to present at least one high pressure paragenesis involving primary pyroxenes. We investigate the exhumation of these metabasites by combining detailed petrographic and thermobarometric studies in order to constrain the P-T conditions for each metamorphic stage. The results suggest an isothermal decompression from peak granulitic conditions (850 ± 50 ^° C and 0.85 ± 0.15 GPa) down to transitional granulitic conditions (830 ±50 ^° C and 0.5 ±0.1 GPa) followed by a cooling episode to the amphibolite-greenschist facies transition at 480 ± 80 ^° C and 0.4– 0.5 GPa. These conditions are consistent with a tectonic exhumation process most likely provoked by a lithospheric thinning accompanied by a magmatic episode and partial melting of the lower continental crust.     

Modeling compositional compressible two-phase flow in porous media by the concept of the global pressure

We derive a new formulation for the compositional compressible two-phase flow in porous media. We consider a liquid–gas system with two components: water and hydrogen. The formulation considers gravity, capillary effects, and diffusivity of each component. The main feature of this formulation is the introduction of the global pressure variable that partially decouples the system equations. To formulate the final system, and in order to avoid primary unknowns changing between one-phase and two-phase zones, a second persistent variable is introduced: the total hydrogen mass density. The derived system is written in terms of the global pressure and the total hydrogen mass density. The system is capable of modeling the flows in both one and two-phase zones with no changes of the primary unknowns. The mathematical structure is well defined: the system consists of two nonlinear parabolic equations, the global pressure equation, and the total hydrogen mass density equation. The derived formulation is fully equivalent to the original one. Numerical simulations show ability of this new formulation to model efficiently the phase appearance and disappearance.     

Hydrogeological and mixing process of waters in deep aquifers in arid regions: south east Tunisia

This study addresses the hydrogeochemistry of thermal and cold waters from south east Tunisia. Temperature intervals are 38.5–68 °C and 22–27.8 °C for thermal water and cold water, respectively. Three distinct hydrogeological systems supply water either for irrigation or for drinking; they are: (1) the Continental Intercalaire geothermal aquifer (CI), (2) the Turonian aquifer and (3) the Senonian aquifer. A synthetic study including hydrochemical, hydrogeological and geothermal approaches have been applied in order to evaluate the inter-aquifers water transfer in south east of Tunisia. By using silica geothermometers and saturation indices for different solid phases, estimated thermal reservoir temperature varies between 52 and 87 °C and between 75 and 110 °C, respectively. Based on chemical and thermal data, mixing, which occurs between the ascending deep geothermal water and shallow cold water, is about 57 % cold water.     

Undrained Monotonic Response and Instability of Medium-Dense Sandy Soil

A series of undrained monotonic triaxial compression tests were performed on natural, medium-dense (relative density (RD) = 50%) Chlef sand containing 0.5% of non-plastic fines, under different confining pressures of 50 kPa, 100 kPa, and 200 kPa. This article focuses on distinctive states of the monotonic undrained response of sands, namely the critical state, the phase transformation state, the quasi-steady state, and the state of undrained instability (onset of flow liquefaction). Specimens were prepared using dry funnel pluviation and wet deposition to investigate the effect of the initial sand fabric on these states. The present data suggest that the initial fabric of the sand appears to have a significant effect on the undrained behavior in the early stages of shearing, with its influence vanishing at large strains. Wet deposition specimens demonstrate considerably larger undrained instability state strength than their dry funnel pluviation counterparts, and a unique critical state locus is reached by both dry funnel pluviation and wet deposition.