The influence of delayed drainage on data from pumping tests in unconfined aquifers

Equations are derived for the flow to a pumped well in an aquifer having uniform anisotropy and overlain by a low-permeability aquitard. The water-table is assumed to be located in the aquitard. Drainage from the capillary zone above the water-table is taken into account.The differential equation for the flow in the aquifer is identical with that derived in a previous paper. The formation constants may therefore be evaluated by using type curves as described in that paper.A well-known pumping test is reanalysed, using the equations in the present paper. It is shown that the time-drawdown curves can be explained only by the existence of a low-permeability stratum in the vicinity of the water-table. In this example the slow draining of the unsaturated zone above the water-table seems to be a significant factor in determining the shape of the time-drawdown curves.     

Chlorophyll-deficient propagules of Avicennia marina and apparent longer term deterioration of mangrove fitness in oil-polluted sediments

A correlation between petroleum hydrocarbon concentrations in sediments and chlorophyll-deficient mutations in mangroves may occur also in Australian mangroves. Earlier reports of such mutations in the Caribbean area were evident in viviparous propagules of the common mangrove genera, Rhizophora, borne on otherwise normal trees. These mutant propagules were termed albinos' since they lacked chlorophyll and normal green coloration, leaving them white, yellow or red. The mutation was considered lethal since newly established albino seedlings appeared unable to survive more than a few months. Our preliminary investigation of mangroves in SE Queensland found a similar mutation in another common mangrove genus, Avicennia, and this was apparently also correlated with oil concentrations in sediments. Although, more evidence is required, an apparently similar relationship shows that whatever caused the mutations may act commonly across a diverse range of plant types in quite separate locations. How widespread might this mutation be in mangroves? How many genera and species are affected? Are all occurrences correlated with oil in sediments? Does oil cause the mutation? We discuss these important questions and the potentially serious implications to coastal management where high mutant densities may be indicative of longer term genetic deterioration of mangrove habitat in oil-polluted wetland environments.     

Major and Trace Element Analysis of Silicate Rocks by XRF and Laser Ablation ICP-MS Using Lithium Borate Fused Glasses: Matrix Effects, Instrument Response and Results for International Reference Materials

Major and trace element compositions of fifteen silicate rock reference materials have been determined by a combined XRF and laser ablation ICP‐MS (LA‐ICP‐MS) technique on glasses prepared by fusing the sample with a lithium borate flux (sample:flux = 1:3). Advantages of this technique include the ability to measure major and trace element abundances on a single sample using a quick and simple preparation that attacks resistant phases such as zircon without the need for acid dissolution. The method is suitable for a wide variety of bulk compositions including mafic, intermediate and silicic rocks. Abundance‐normalized mass response patterns (the ratio of signal intensity to element concentration) of the LA‐ICP‐MS analyses vary systematically with major element composition, demonstrating the presence of a matrix effect that cannot be compensated by normalisation to a single internal standard element. Increasing the sampling distance between the ICP‐MS cone and the torch reduces the magnitude of this effect, suggesting that a mechanism related to residence time of ablated particles in the plasma may be at least partially responsible for the observed variations in mass response patterns. When using a matrix‐matched calibration, agreement of the LA‐ICP‐MS results with published reference values or those obtained by solution ICP‐MS is 10% relative. Analytical precision based on replicate analyses is typically 5% RSD. Procedural detection limits that include contributions from gas background and flux are 0.01‐0.1 μg g‐¹ for the heavy mass trace elements (Rb‐U). Major element analyses by XRF show excellent agreement with results obtained using a conventional heavy element absorbing flux. High quality major and trace element data for silicate rocks can be achieved by a combined XRF and LA‐ICP‐MS analysis of Li₂B₄O₇/LiBO₂ fused glasses provided an appropriate matrix‐matched calibration is adopted.     

An Experimental Performance Evaluation of Spatio-Temporal Join Strategies

Many applications capture, or make use of, spatial data that changes over time. This requirement for effective and efficient spatio‐temporal data management has given rise to a range of research activities relating to spatio‐temporal data management. Such work has sought to understand, for example, the requirements of different categories of application, and the modelling facilities that are most effective for these applications. However, at present, there are few systems with fully integrated support for spatio‐temporal data, and thus developers must often construct custom solutions for their applications. Developers of both bespoke solutions and of generic spatio‐temporal platforms will often need to support the fusion of large spatio‐temporal data sets. Supporting such requests in a database setting involves the use of join operations with both spatial and temporal conditions – spatio‐temporal joins. However, there has been little work to date on spatio‐temporal join algorithms or their evaluation. This paper presents an evaluation of several approaches to the implementation of spatio‐temporal joins that build upon widely available indexing techniques. The evaluation explores how several algorithms perform for databases with different spatial and temporal characteristics, with a view to helping developers of generic infrastructures or custom solutions in the selection and development of appropriate spatio‐temporal join strategies.     

Paper 1. the mink methodology: background and baseline

A four step methodology has been developed for study of the regional impacts of climate change and the possible responses thereto. First the region's climate sensitive sectors and total economy are described (Task A, current baseline). Next a scenario of climate change is imposed on the current baseline (Task B, current baseline with climate change). A new baseline describing the climate sensitive sectors and total regional economy is projected for some time in the future (Task C, future baseline, year 2030) in the absence of climate change. Finally, the climate change scenario is reimposed on the future baseline (Task D, future baseline with climate change). Impacts of the climate change scenario on the current and future regional economies are determined by means of simulation models and other appropriate techniques. These techniques are also used to assess the impacts of an elevated CO₂ concentration (450 ppm) and of various forms of adjustments and adaptations. The region chosen for the first test of the methodology is composed of the four U.S. states of Missouri, Iowa, Nebraska and Kansas. The climate change scenario is the actual weather of the 1930s decade in the MINK region. ‘Current’ climate is the actual weather of the period 1951–1980.     

Conclusions,remaining issues,and next steps

The workshop focused on methodologies to assess the impacts of climate change on terrestrial and aquatic ecosystems and their socioeconomic consequences. It did not deal in any detail with the other components (i.e., models designed to estimate changes in atmospheric concentrations of greenhouse gases or in climatic factors) of an integrated assessment shown in Figure 2 of the introduction. This final chapter discusses some of the issues addressed during the San Diego workshop and highlights a few of the major findings of the papers. Issues discussed below include limitations of past modeling efforts and impediments to developing better models of the impacts of climate change on forest, grassland, and water resources; suggestions for future research both to develop better data and models and to employ existing data and modeling capabilities to improve the usefulness of climate impact assessments for policy purposes; and the need for developing a common assessment framework.The views expressed here are those of the authors and do not necessarily reflect those of their institutions or the other participants in the February 28 to March 3, 1993 workshop held in San Diego, California.     

Modeling surficial sand and gravel deposits

Mineral-deposit models are an integral part of quantitative mineral-resource assessment. As the focus of mineral-deposit modeling has moved from metals to industrial minerals, procedure has been modified and may be sufficient to model surficial sand and gravel deposits. Sand and gravel models are needed to assess resource-supply analyses for planning future development and renewal of infrastructure. Successful modeling of sand and gravel deposits must address (1) deposit volumes and geometries, (2) sizes of fragments within the deposits, (3) physical characteristics of the material, and (4) chemical composition and chemical reactivity of the material. Several models of sand and gravel volumes and geometries have been prepared and suggest the following: Sand and gravel deposits in alluvial fans have a median volume of 35 million m³. Deposits in all other geologic settings have a median volume of 5.4 million m³, a median area of 120 ha, and a median thickness of 4 m. The area of a sand and gravel deposit can be predicted from volume using a regression model (log [area (ha)] =1.47+0.79 log [volume (million m³)]). In similar fashion, the volume of a sand and gravel deposit can be predicted from area using the regression (log [volume (million m³)]=–1.45+1.07 log [area (ha)]). Classifying deposits by fragment size can be done using models of the percentage of sand, gravel, and silt within deposits. A classification scheme based on fragment size is sufficiently general to be applied anywhere.     

40Ar39Ar dating of glauconites: Measured 39Ar recoil loss from well-crystallized specimens

Nine glauconite samples with relatively high K concentrations and which appear to be well crystallized using normal X-ray diffraction techniques have been studied using the ${}^{40}\text{Ar}{}^{39}\text{Ar}$ method. The glauconite ${}^{40}\text{Ar}{}^{39}\text{Ar}$ apparent ages exceed their KAr, RbSr and, in most cases, stratigraphic ages by substantial amounts. ${}^{40}\text{Ar}{}^{39}\text{Ar}$ release spectra sometimes yield plateaus but these apparent ages have no geological significance. The results indicate that ³⁹Ar is lost by recoil from mineral grains during neutron irradiation, consistent with previously reported observations. The amount of ³⁹Ar loss was measured by isotope dilution for four samples and varied from 29% to 17%. In contrast, radiogenic ⁴⁰Ar is quantitatively retained during irradiation. The very fine blades which make up glauconite grains yield the mineral susceptible to large amounts of ³⁹Ar loss and unsuitable for ${}^{40}\text{Ar}{}^{39}\text{Ar}$ dating.     

Applications of Dual-Wall Reverse-Circulation Drilling in Ground Water Exploration and Monitoring

Dual-wall reverse-circulation drilling uses flush-threaded double-wall drill pipe and high-pressure air to provide continuous return of formation and water samples. Cuttings and formation waters are not contaminated with drilling additives or mixed with other borehole material. Up-hole velocity of about 70 ft/sec provides reliable logging of water, mineral or contaminant-bearing strata. Water samples representative of specific strata may be airlifted or bailed to the surface.
In the percussion hammer system, dual-wall drill pipe is advanced through chiefly unconsolidated material by the percussion action of an above-ground pile hammer. The borehole is drilled and temporarily cased in one pass. Wells or monitoring devices are installed as the drill pipe is hydraulically retracted during construction. A rotary head may be adapted as an option to allow dual-wall rotary drilling into consolidated or crystalline formations through a percussion hammer drill string temporarily left in place as a conductor.
The complex geology and variety of geoenvironmental problems in southern California has provided a testing ground for dual-wall drilling on hazardous material site investigations. Several case histories have demonstrated the capabilities and versatility of this method, including: (1) the installation of 4-inch and 6-inch diameter gasoline monitoring and recovery wells through gravels and cobbles at a filling station where hollow-stem auger drilling failed; (2) the confirmation of a dry borehole initially drilled by direct rotary at a landfill; and (3) multiple installations of monitoring devices through municipal refuse at a city of Los Angeles landfill.