Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Structure Function Analysis of Two-Scale Scalar Ramps. Part II: Ramp Characteristics and Surface Renewal Flux Estimation

Ramp features in the turbulent scalar field are associated with turbulent coherent structures, which dominate energy and mass fluxes in the atmospheric surface layer. Although finer scale ramp-like shapes embedded within larger scale ramp-like shapes can readily be perceived in turbulent scalar traces, their presence has largely been overlooked in the literature. We demonstrate the signature of more than one ramp scale in structure functions of the turbulent scalar field measured from above bare ground and two types of short plant canopies, using structure-function time lags ranging in scale from isotropic to larger than the characteristic coherent structures. Spectral analysis of structure functions was used to characterize different scales of turbulent structures. By expanding structure function analysis to include two ramp scales, we characterized the intermittency, duration, and surface renewal flux contribution of the smallest (i.e., Scale One) and the dominant (i.e., Scale Two) coherent structure scales. The frequencies of the coherent structure scales increase with mean wind shear, implying that both Scale One and Scale Two are shear-driven. The embedded Scale One turbulent structure scale is ineffectual in the surface-layer energy and mass transport process. The new method reported here for obtaining surface renewal-based scalar exchange works well over bare ground and short canopies under unstable conditions, effectively eliminating the α calibration for these conditions and forming the foundation for analysis over taller and more complex surfaces.     

Tellurides from Sunrise Dam gold deposit, Yilgarn Craton, Western Australia: a new occurrence of nagyágite

Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.     

Application of sodars in the study and monitoring of the environment

Summary Application of acoustic sounders (sodars) to study the atmospheric boundary layer (ABL) began in the early 1970s. During the last two decades the scope of sodars applications enlarged considerably. The proceedings of eleven symposia of the International Society for Remote Acoustic Sensing of the Atmosphere and Oceans (ISARS) are a unique collection of papers, where all directions of the sodar use since 1981 are presented. In this paper, a review of sodar applications to atmospheric research is presented based on materials published in these proceedings in the following fields: conditions of microwave and light propagation; regional climatology of the ABL; air pollution meteorology and weather forecast; mesoscale phenomena under stable and unstable stratification; micrometeorology; peculiarities of the ABL in remote and complex terrain.     

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Anaerobic Metabolism in Tidal Freshwater Wetlands: I. Plant Removal Effects on Iron Reduction and Methanogenesis

For energetic reasons, iron reduction suppresses methanogenesis in tidal freshwater wetlands; however, when iron reduction is limited by iron oxide availability, methanogenesis dominates anaerobic carbon mineralization. Plants can mediate this microbial competition by releasing oxygen into the rhizosphere and supplying oxidized iron for iron reducers. We utilized a plant removal experiment in two wetland sites to test the hypothesis that, in the absence of plants, rates of iron reduction would be diminished, allowing methanogenesis to dominate anaerobic metabolism. In both sites, methanogenesis was the primary anaerobic mineralization pathway, with iron reduction dominating only early and late in the growing season in the site with a less organic soil. These patterns were not influenced by the presence of plants, demonstrating that plants were not a key control of microbial metabolism. Instead, we suggest that site conditions, including soil chemistry, and temperature are important controls of the pathways of anaerobic metabolism.     

Use of remote sensing in lineament analysis for tectonic evolution and resource study of a part of Vindhyan Basin,Jhalawar area,India

Synoptivity and the exemplified fracture systems exhibited by the space borne imagery data has helped in solving many of the geological enigma in various parts of the world. The study conducted, using such remotly sensed data, in Jhalawar anticline, part of Proterozoic Cratonic Vindhyan Basin, Rajasthan, India, led to infer the history of tectonic evolution of peribasinal deformation which has been a matter of controversy for a century and more. In Landsat MSS data the Jhalawar region displays a panorama of lineaments and their analysis through azimuthal frequency diagrams, isofracture, lineament incidence and lineament intersection incidence density maps shows that the mean orientation of the lineaments fall in NW-SE and NE-SW and the shape of the various lineament density contours also show NE-SW and NW-SE orientations. In aerial photographs the area exhibits four sets of lineaments in NE-SW, NW-SE, N-S and E-W directions. Amongst these the former two sets are expressed as wide open master fracture systems with prolific vegetation fills along them and the latter two sets are characteristically observed as thin vegetation linears with frequent strike slip faulting along them. The further analysis of these fracture/lineament systems derived from multi-level remote sensing data shows that the Jhalawar anticline, which followed the pattern of flexural slip fold mechanism, was evolved by horizontally disposed σ1 (greatest principal stress) and 3σ (least principal stress) with the former oriented in NE-SW and the latter aligned in NW-SE directions with vertically disposed 2σ. The inference of such palaeostress environment of the Jhalawar region lead in the identification of a buried rigid basement high southwest of Jhalawar anticline, beneath the Deccan pile and loci of ground water, silica sand and probable igneous plug.     

Import of coastally-derived chlorophylla to South Slough, Oregon

Material transfer between estuaries and the nearshore zone has long been of interest, but information on the processes affecting Pacific Northwest estuaries has lagged behind other areas. The west coast of the U.S. is a region of seasonally variable upwelling that results in enhanced phytoplankton production in the nearshore zone. We examined estuarine-nearshore links over time by measuring physical oceanographic variables and chlorophylla concentration from an anchor station in South Slough, Oregon. Data was collected during 24-h cruises conducted at approximately weekly intervals during summer 1996 and spring 1997. The results demonstrate that the physical oceanography of this estuarine site was strongly influenced by the coastal ocean. Marine water reached the estuarine site on every sampled tide, and chlorophylla was clearly advected into the estuary with this ocean water. In contrast, phytoplankton concentrations were comparatively reduced in the estuarine water. There were, however, large fluctuations in the import of chlorophyll over the course of the summer. These variations likely reflect upwelling-generated phytoplankton production in the coastal ocean and subsequent cross-shelf transport to the estuary. Suspension feeding organisms in South Slough likely depend on the advection of this coastally-derived phytoplankton. The large allochthonous chlorophyll input measured for this system appears dissimilar from most estuaries studied to date. Previous investigations have focused on the outwelling and inwelling of materials in estuaries. We must now consider the influence of coastal upwelling and downwelling processes on estuarine material exchange.     

Geochemistry and geochronology of proterozoic tholeiite dykes of east antarctica: evidence for mantle metasomatism

Two episodes of tholeiite dyke emplacement have been identified in Archaean high-grade metamorphics of the Napier Complex in Enderby Land. Middle Proterozoic Amundsen dykes are typical continental tholeiites and most of the chemical variation in individual suites can be explained in terms of different degrees of partial melting and low-pressure crystal fractionation. Group I Amundsen tholeiites were derived from a relatively homogeneous source region 1,190±200 m.y. ago, whereas that of the group II Amundsen tholeiites was chemically and isotopically heterogeneous. Group II dykes have various degrees of enrichment in incompatible elements, and commonly show normalised trace element abundance patterns with negative Nb anomalies. These features imply variable metasomatism of the source region by a volatile-rich fluid phase (rather than a melt of any observed igneous composition) enriched in K, Rb, Ba, Th, and possibly La and Ce.Early Proterozoic (2,350±48 m.y.) tholeiites were emplaced at considerable depths in the crust during the waning stages of granulite-facies metamorphism and include a high-Mg suite of possible komatiitic affinity, ranging in composition from hypersthene-rich tholeiite (norite) to quartz-rich tholeiite. They tend to have higher ratios of highly to moderately incompatible elements (e.g., K/Zr, K/Ce), and larger Nb anomalies (i.e., higher K/Nb) compared with middle Proterozoic tholeiites, suggesting derivation from more enriched source regions. Isotopic data are not compatible with significant crustal contamination, but constrain source metasomatism to a time immediately before emplacement. Metasomatism of the source region of the much younger group I tholeiites may have been contemporaneous with that of the high-Mg suite.