The impact of different cooling strategies on urban air temperatures: the cases of Campinas,Brazil and Mendoza,Argentina

This paper describes different ways of reducing urban air temperature and their results in two cities: Campinas, Brazil—a warm temperate climate with a dry winter and hot summer (Cwa), and Mendoza, Argentina—a desert climate with cold steppe (BWk). A high-resolution microclimate modeling system—ENVI-met 3.1—was used to evaluate the thermal performance of an urban canyon in each city. A total of 18 scenarios were simulated including changes in the surface albedo, vegetation percentage, and the H/W aspect ratio of the urban canyons. These results revealed the same trend in behavior for each of the combinations of strategies evaluated in both cities. Nevertheless, these strategies produce a greater temperature reduction in the warm temperate climate (Cwa). Increasing the vegetation percentage reduces air temperatures and mean radiant temperatures in all scenarios. In addition, there is a greater decrease of urban temperature with the vegetation increase when the H/W aspect ratio is lower. Also, applying low albedo on vertical surfaces and high albedo on horizontal surfaces is successful in reducing air temperatures without raising the mean radiant temperature. The best combination of strategies—60 % of vegetation, low albedos on walls and high albedos on pavements and roofs, and 1.5 H/W—could reduce air temperatures up to 6.4 °C in Campinas and 3.5 °C in Mendoza.     

A large sedimentary basin in the Terra Sirenum region of the southern highlands of Mars

Different lines of evidence point to hydrological cycling in the martian past. The extent, duration, and magnitude of this cycling remains unclear, as well as the magnitude of aqueous processes on the surface. Here, we provide geomorphic and mineralogic evidence of a large inter-crater sedimentary basin located in the Terra Sirenum region, which was once covered by a body of liquid water with an areal extent of at least 30,000 km² and a depth of approximately 200 m. The topographic basin, which is modified by a number of large impact craters, is partly controlled by ancient impact and tectonic structures. As a result of evaporation of the large body of water, salt flats formed in the lowest topographic reaches of the basin. Hydrated phyllosilicates occur in close proximity to the salt flats and in the ejecta and rim materials of small impact craters with stratigraphic relations that suggest that they underlie the evaporite deposits. Crater statistics place the maximum age of aqueous activity during the Late Noachian epoch. The relatively pristine mineral deposits in the basin have a high potential to yield information of the geochemistry and water activity during the ancient Noachian Period when conditions were seemingly more conducive to life.     

Removal of Pyridine from Aqueous Solution by Adsorption on an Activated Carbon Cloth

Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed.     

Earth-Affecting Solar Causes Observatory (EASCO): A potential International Living with a Star Mission from Sun–Earth L5

This paper describes the scientific rationale for an L5 mission and a partial list of key scientific instruments the mission should carry. The L5 vantage point provides an unprecedented view of the solar disturbances and their solar sources that can greatly advance the science behind space weather. A coronagraph and a heliospheric imager at L5 will be able to view CMEs broadsided, so space speed of the Earth-directed CMEs can be measured accurately and their radial structure discerned. In addition, an inner coronal imager and a magnetograph from L5 can give advance information on active regions and coronal holes that will soon rotate on to the solar disk. Radio remote sensing at low frequencies can provide information on shock-driving CMEs, the most dangerous of all CMEs. Coordinated helioseismic measurements from the Sun–Earth line and L5 provide information on the physical conditions at the base of the convection zone, where solar magnetism originates. Finally, in situ measurements at L5 can provide information on the large-scale solar wind structures (corotating interaction regions (CIRs)) heading towards Earth that potentially result in adverse space weather.     

An overview of physical and ecological processes in the Rio de la Plata Estuary

The Rio de la Plata is a large-scale estuary located at 35°S on the Atlantic coast of South America. This system is one of the most important estuarine environments in the continent, being a highly productive area that sustains valuable artisanal and coastal fisheries in Uruguay and Argentina. The main goals of this paper are to summarize recent knowledge on this estuary, integrating physical, chemical and biological studies, and to explore the sources and ecological meaning of estuarine variability associated to the stratification/mixing alternateness in the estuary. We summarized unpublished data and information from several bibliographic sources. From study cases representing different stratification conditions, we draw a holistic view of physical patterns and ecological processes of the stratification/mixing alternateness. This estuary is characterized by strong vertical salinity stratification most of the time (the salt-wedge condition). The head of the estuary is characterized by a well-developed turbidity front. High turbidity constrains their photosynthesis. Immediately offshore the turbidity front, water becomes less turbid and phytoplankton peaks. As a consequence, trophic web in the estuary could be based on two sources of organic matter: phytoplankton and plant detritus. Dense plankton aggregations occur below the halocline and at the tip of the salt wedge. The mysid Neomysis americana, a key prey for juvenile fishes, occurs all along the turbidity front. A similar spatial pattern is shown by one of the most abundant benthic species, the clam Mactra isabelleana. These species could be taken advantage of the particulate organic matter and/or phytoplankton concentrated near the front. Nekton is represented by a rich fish community, with several fishes breeding inside the estuary. The most important species in terms of biomass is Micropogonias furnieri, the main target for the coastal fisheries of Argentina and Uruguay. Two processes have been identified as producing partially stratified conditions: persistent moderate winds (synoptic scale), or low freshwater runoff (interannual scale). Less frequently, total mixing of the salt wedge occurs after several hours of strong winds. The co-dominance of diatoms (which proliferate in highly turbulent environments) and red tides dinoflagellates and other bloom taxa (better adapted to stratified conditions), would indicate great variability in the turbulence strength, probably manifested as pulses. Microplankton and ichthyoplankton assemblages defined for the stratified condition are still recognized during the partially mixed condition, but in this case they occupy the entire water column: vertical structure of the plankton featuring the stratified condition become lost. Bottom fish assemblages, on the contrary, shows persistence under the different stratification conditions, though the dominant species of the groups show some variations. Summarizing, the Río de la Plata Estuary is a highly variable environment, strongly stratified most of the time but that can be mixed in some few hours by strong wind events that occur in an unpredictable manner, generating stratification/partially mixed (less frequently totally mixed) pulses all along the year. At larger temporal scales, the system is under the effects of river discharge variations associated to the ENSO cycle, but their ecological consequences are not fully studied.     

Fractionation of palladium and platinum in a Mesozoic diabase sheet, Gettysburg basin, Pennsyvania: implications for mineral exploration

The York Haven diabase sheet displays clear-cut evidence of fractionation of Pd and Pt during differentiation of a high-Ti (about 1.1%) quartz-normative tholeiitic magma (York Haven type). At York Haven the sheet is about 750 m thick. It is characterized by abundant cumulus MgO-rich orthopyroxene (bronzite), and is markedly depleted in incompatible elements relative to the chilled margins. In contrast, at Reesers Summit, 16 km to the northwest, the sheet is about 500 m thick and consists of evolved rocks that have contents of incompatible elements two to three times greater than in the enclosing chilled margins. These evolved rocks represent complementary fractions to the cumulate rocks at York Haven. Mineralogic, petrologic and geochemical variations suggest considerable lateral migration and fractionation of the initial magma.Chilled margins of both sections have essentially the same Pd and Pt contents (10 ppb each) and similar Pd to Pt ratios (1.2). During differentiation, the cumulate rocks at York Haven were enriched in Pt and depleted in Pd, whereas at Reesers Summit, the low-MgO diabase and ferrogabbro zone were enriched in Pd relative to Pt. Anomalously high contents of Pd (to 165 ppb), Au (to 54 ppb), and Te (to 26 ppb) were found in an iron- (to 18%) and chlorine- (to 0.44%) rich ferrogabbro at Reesers Summit, suggesting possible late or post-magmatic enrichment of precious metals. Field relations, geochemical and petrographic data provide guides for further exploration for Pd and Pt in differentiated high-Ti quartz-normative diabase sheets. Based on present information, the most favorable sites for economic deposits are late-stage differentiates enriched in Fe and Cl.     

Emission lines of Fe xv in spectra obtained with the Solar Extreme-Ultraviolet Research Telescope and Spectrograph

Recent R-matrix calculations of electron impact excitation rates in Mg-like Fe  xv are used to derive theoretical emission-line ratios involving transitions in the 243–418 Å  wavelength range. A comparison of these with a data set of solar active region, subflare and off-limb spectra, obtained during rocket flights by the Solar Extreme-Ultraviolet Research Telescope and Spectrograph (SERTS), reveals generally very good agreement between theory and observation, indicating that most of the Fe  xv emission lines may be employed with confidence as electron density diagnostics. In particular, the 312.55-Å  line of Fe  xv is not significantly blended with a Co  xvii transition in active region spectra, as suggested previously, although the latter does make a major contribution in the subflare observations. Most of the Fe  xv transitions which are blended have had the species responsible clearly identified, although there remain a few instances where this has not been possible. We briefly address the long-standing discrepancy between theory and experiment for the intensity ratio of the  3s^2 1S–3s3p ³P₁  intercombination line at 417.25 Å  to the  3s^2 1S–3s3p ¹P  resonance transition at 284.16 Å.     

Electron-Temperature Maps of the Low Solar Corona: ISCORE Results from the Total Solar Eclipse of 29 March 2006 in Libya

We conducted an experiment in conjunction with the total solar eclipse of 29 March 2006 in Libya that measured the coronal intensity through two filters centered at 3850 Å and 4100 Å with bandwidths of ≈?40 Å. The purpose of these measurements was to obtain the intensity ratio through these two filters to determine the electron temperature. The instrument, Imaging Spectrograph of Coronal Electrons (ISCORE), consisted of an eight inch, f/10 Schmidt Cassegrain telescope with a thermoelectrically-cooled CCD camera at the focal plane. Results show electron temperatures of 10⁵ K close to the limb to 3×10⁶ K at 1.3R _⊙. We describe this novel technique, and we compare our results to other relevant measurements. This technique could be easily implemented on a space-based platform using a coronagraph to produce global maps of the electron temperature of the solar corona.