Adakite-like signature of Late Miocene intrusions at the Los Pelambres giant porphyry copper deposit in the Andes of central Chile: metallogenic implications

Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and La_N/Yb_N (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb     

Stable isotope (C,O, S) systematics of the mercury mineralization at Idrija,Slovenia: constraints on fluid source and alteration processes

The world-class Idrija mercury deposit (western Slovenia) is hosted by highly deformed Permocarboniferous to Middle Triassic sedimentary rocks within a complex tectonic structure at the transition between the External Dinarides and the Southern Alps. Concordant and discordant mineralization formed concomitant with Middle Triassic bimodal volcanism in an aborted rift. A multiple isotopic (C, O, S) investigation of host rocks and ore minerals was performed to put constraints on the source and composition of the fluid, and the hydrothermal alteration. The distributions of the ¹³C and ¹⁸O values of host and gangue carbonates are indicative of a fracture-controlled hydrothermal system, with locally high fluid-rock ratios. Quantitative modeling of the ¹³C and ¹⁸O covariation for host carbonates during temperature dependent fluid-rock interaction, and concomitant precipitation of void-filling dolomites points to a slightly acidic hydrothermal fluid (¹³C–4 and ¹⁸O+10), which most likely evolved during isotopic exchange with carbonates under low fluid/rock ratios. The ³⁴S values of hydrothermal and sedimentary sulfur minerals were used to re-evaluate the previously proposed magmatic and evaporitic sulfur sources for the mineralization, and to assess the importance of other possible sulfur sources such as the contemporaneous seawater sulfate, sedimentary pyrite, and organic sulfur compounds. The ³⁴S values of the sulfides show a large variation at deposit down to hand-specimen scale. They range for cinnabar and pyrite from –19.1 to +22.8, and from –22.4 to +59.6, respectively, suggesting mixing of sulfur from different sources. The peak of ³⁴S values of cinnabar and pyrite close to 0 is compatible with ore sulfur derived dominantly from a magmatic fluid and/or from hydrothermal leaching of basement rocks. The similar stratigraphic trends of the ³⁴S values of both cinnabar and pyrite suggest a minor contribution of sedimentary sulfur (pyrite and organic sulfur) to the ore formation. Some of the positive ³⁴S values are probably derived from thermochemical reduction of evaporitic and contemporaneous seawater sulfates.Editorial handling: P. Lattanzi     

Thermal modeling of Carboniferous to Triassic sediments of the Karawanken Range (Southern Alps) as a tool for paleogeographic reconstructions in the Alpine–Dinaridic–Pannonian realm

Vitrinite reflectance was measured in Late Carboniferous to Triassic shales, siltstones and marls of the Karawanken Range. Thermal models of the central South-Karawanken Range were calibrated on the basis of these data. They suggest an eroded overburden of more than 3,200 m of Jurassic to Cretaceous sediments and a heat flow in the range of 42 to 60 mW m^?2 during the time of maximum subsidence. Because the reconstructed thermal history of the South-Karawanken Range is very similar to the thermal history of the Generoso basin (western Southern Alps), these data provide strong evidence for a deep basinal position of the Southern Karawanken Range during Jurassic to Cretaceous times. A vitrinite reflectance anomaly at the northern margin of the South-Karawanken Range is explained by advective heat transport during the Oligocene. The heat source for the anomalies at the western margin of the Seeberg Rise and in the area between the Periadriatic Lineament and the Donat Fault Zone is unknown. Vitrinite reflectance in Late Triassic sediments indicates the South-Karawanken Range and the South-Zala Unit of the Pannonian basement as exotic blocks in the Sava Composite Unit. This is explained by Miocene displacement of structural units, which were derived from different paleogeographical segments of the Permo-Mesozoic western Tethyan margin.     

GIS-based spatial and temporal prediction system development for regional land subsidence hazard mitigation

An integrated GIS-based approach for establishing a spatial and temporal prediction system for groundwater flow and land subsidence is proposed and applied to a subsidence-progressed Japanese coastal plain. Various kinds of fundamental data relating to groundwater flow and land subsidence are digitized and entered into a GIS database. A surface water hydrological cycle simulation is performed using a GIS spatial data operation for the entire plain, and the spatial and temporal groundwater infiltration quantity is hereby obtained. Through the data transformation from the GIS database to a groundwater flow code (MODFLOW), a 3D groundwater flow model is established and unsteady groundwater flow simulation for the past 21 years is conducted with results which compare satisfactorily with observed results. Finally, a Visual Basic code is developed for land subsidence calculations considering aquifer and aquitard deformation. Future land subsidence in the plain is predicted assuming different water pumping scenarios, and the results provide important information for land subsidence mitigation decision-making.     

Geochemistry of the Upper Neoproterozoic and Lower Cambrian siliciclastic rocks and U-Pb dating on detrital zircons in the Central Iberian Zone,Spain

Sandstones and shales from the Upper Neoproterozoic (UN) succession in the Central Iberian Zone (CIZ) show parallel REE patterns and relatively restricted and similar ranges and average values of some element ratios such as Al₂O₃/TiO₂, Ti/Nb, Eu/Eu*, (La/Yb)n, (Gd/Yb)n and Th/U. This remarkable geochemical homogeneity for related medium- and fine-grained rocks is unusual, and strongly suggests a recycled source area. However, the Lower Cambrian (LC) equivalent rocks are, in general terms, geochemically less mature, more heterogeneous and more fractionated. Their average REE patterns are practically coincident, probably as a consequence of REE redistribution related to the reworking of sediments during a stage of sea level fall in Lower Cambrian times. Ti and Zr abundances, chemical index of alteration (CIA) values and element ratios such as Al₂O₃/TiO₂, K/Rb, Ti/Nb and Rb/Zr can be used for discriminating purposes between the UN and LC siliciclastic rocks. Detrital zircons from a UN and a LC sandstone display morphological differences. However, U-Pb data are discordant and cannot be interpreted in a straightforward manner. Nevertheless, age data are compatible with a model in which the continent of Gondwana would have supplied zircons, showing a bimodal age distribution, in variable proportions to the respective sandstone units.     

Phytoplankton Interannual Variability at Cassino Beach, Southern Brazil (1992–2007), with Emphasis on the Surf Zone Diatom Asterionellopsis glacialis

A long-term study (monthly sampling, 1992 to 2007) was conducted in the surf zone of Cassino Beach, Southern Brazil, in order to detect possible natural and/or anthropogenic disturbances. Surface water temperature (6–29°C) was the only parameter with predictable seasonal variation; salinity (14–38) was inversely related to rainfall (3.1–485.2 mm month⁻¹) and low values followed extreme precipitation periods in 1997/1998 and 2002/2003 (El Ni?o years). Asterionellopsis glacialis and chlorophyll a presented high concentrations and peak frequency until 1998, when an intense mud deposition occurred with concomitant extreme rainfall. It affected the surf zone and beach, changing the hydrology and dissolved inorganic nutrient availability. Six phytoplankton species groups were recognized with distinct responses to this mud deposition. We conclude that large-scale climatic changes, like El Ni?o Southern Oscillation, in conjunction with human activities significantly altered the phytoplankton ecology of the highly dynamic Cassino Beach surf zone.     

Early warning of rainfall-induced shallow landslides and debris flows in the USA

The state of knowledge and resources available to issue alerts of precipitation-induced landslides vary across the USA. Federal and state agencies currently issue warnings of the potential for shallow, rapidly moving landslides and debris flows in a few areas along the Pacific coast and for areas affected by Atlantic hurricanes. However, these agencies generally lack resources needed to provide continuous support or to expand services to other areas. Precipitation thresholds that form the basis of landslide warning systems now exist for a few areas of the USA, but the threshold rainfall amounts and durations vary over three orders of magnitude nationwide and over an order of magnitude across small geographic areas such as a county. Antecedent moisture conditions also have a significant effect, particularly in areas that have distinct wet and dry seasons. Early warnings of shallow landslides that include specific information about affected areas, probability of landslide occurrence, and expected timing are technically feasible as illustrated by a case study from the Seattle, WA area. The four-level warning scheme (Null, Outlook, Watch, Warning) defined for Seattle is based on observed or predicted exceedance of a cumulative precipitation threshold and a rainfall intensity–duration threshold combined with real-time monitoring of soil moisture. Based on analysis of historical data, threshold performance varies according to precipitation characteristics, and threshold exceedance corresponds to a given probability of landslide occurrence. Experience in Seattle during December 2004 and January 2005 illustrates some of the challenges of providing landslide early warning on the USA West Coast.     

A particle conveyor belt process in the Columbia River estuary: Evidence from chlorophyll<Emphasis Type="Italic">a</Emphasis> and particulate organic carbon

Using both the photosynthetically active chlorophylla (chla) content of the organic carbon fraction of suspended particulate matter (chla/POC) and the percentage of photosynthetically, active chla in fluorometrically measured chla plus pheophytina (% chla), we determined that under specified hydrodynamic conditions, neap-spring tidal differentiation in particle dynamics could be observed in the Columbia River estuary. During summer time neap tides, when river discharge was moderate, bottom chla/POC remained relatively unchanged from riverine chla/POC over the full 0–30 psu salinity range, suggesting a benign trapping environment. During summertime spring tides, bottom chla/POC decreased at mid range salinities indicating resuspension of chla-poor POC during flood-ebb transitions. Bottom % chla during neap tides tended to average higher than that during spring tides, suggesting that neap particles were more recently hydrodynamically trapped than those on the spring tides. Such differentiation supported the possibility of operation of a particle conveyor belt process, a process in which low-amplitude neap tides favor selective particle trapping in estuarine turbidity maxima (ETM)., while high-amplitude spring tides favor particle resuspension from the ETM. Untrapped river-derived particles at the surface would continue through the estuary to the coastal ocean on the neap tide; during spring tide some particles eroded from the ETM would combine with unsettled riverine particles in transit toward the ocean. Because in tensified biogeochemical activity is associated with ETM, these neap-spring differences may be critical to maintenance and renewal of populations and processes in the estuary. Very high river discharge (15, 000 m³ s⁻¹) tended to overwhelm neap-spring differences, and significant oceanic input during very low river discharge (5,000 m³ s⁻¹) tended to do the same in the estuarine channel most exposed to ocean input. During heavy springtime phytoplankton blooms, development of a thick bottom fluff layer rich in chla also appeared to negate neapspring differentiation because spring tides apparently acted to resuspend the same rich bottom material that was laid down during neap tides. When photosynthetic assimilation numbers [μgC (μgchl,a)⁻¹h⁻¹] were measured across, the full salinity range, no neap-spring differences and no river discharge effects occurred, indicating that within our suite of measurements the compositional distinction of suspended particulate material was mainly a function of chla/POC, and to a lesser extent % chla. Even though these measurements suggest the existence of a conveyor belt process, proof of actual operation of this phenomenon requires scalar flux measurements of chla properties in and out of the ETM on both neap and spring tides.     

Interannual and long-term variation in the nearshore fish community of the mesohaline Hudson River estuary

The detection of long-term shifts in species composition and spatial structuring of aquatic communities may be obscured by high levels of interannual variation. Estuarine fish communities are likely to exhibit high levels of variation owing to the influence of riverine forcing and the importance of anadromous and transient species, whose abundances may not be locally controlled. We describe patterns of interannual variation and long-term shifts in the nearshore fish community of the mesohaline Hudson River estuary based on 21 yr of beach seine sampling conducted annually between late August and mid November. Of the 60 species encountered, the most abundant were Atlantic silversides (Menidia menidia), striped bass (Morone saxatilis), white perch (Morone americana), American shad (Alosa sapidissima), and blueback herring (Alosa aestivalis). Relationships between annual community composition and seasonal flow and temperature regimes were examined with canonical correspondence analysis. Annual variation was most closely correlated with river flows in the 3-mo period preceding fish sampling, indicating a persistent effect of environmental conditions on community structure. Despite significant interannual variation in composition, longer-term trends in community structure were observed. These included declines in catch rates of freshwater and estuarine species and a dramatic increase in the catch of Atlantic silversides, an annual marine species. Associated with these changes were declines in community diversity and increased compositional variation. These results indicate that analyses of temporal changes in community structure need to account for the multiple time scales under which forcing factors and community composition vary.     

The effects of two benthic chamber stirring systems on the diffusive boundary layer,oxygen flux,and passive flow through model macrofauna burrows

Diffusive boundary layers (DBL), sediment oxygen flux, and natural passive flow through model macrofauna burrows were compared in two benthic chambers: one with a conventional rotational stirrer and the other with a two-dimensional flow diffuser system. Oxygen microprobe profiles showed that at similar velocities the mean diffusive boundary layer (DBL) thickness induced by a conventional rotor stirrer (453±118 μm) was not significantly different to that produced by the diffuser system (403±53 μm). The rotor produced twice as much DBL spatial variability (coefficient of variation 27%) as the diffuser (CV 11%). Variability between the rotor system’s DBL transect replicates was also two times greater (average CV of 22%) compared to the diffuser (CV 14%). At equivalent stirring speeds over experimental sediments, mean O₂ consumption rates were also not significantly different between the two systems. The diffuser induced consistently greater (16–37%) passive Bernoullian flow through model macrofauna borrows irrespective of the position of inhalant-exhalent openings. The rotor stimulated anomalous burrow flow regimes over a greater area of the chamber floor (36%) compared to the diffuser (23%). Depending on vent orientation the rotor was shown to reverse (exhalent to inhalant) burrow flow regimes in the central 9% of the chamber floor. This artifact of radial pressure and velocity differentials may have severe implications for tube dwelling infauna that rely on unidirectional flow. The diffuser system more closely mimicked natural two-dimensional water flow over the sediment surface and structures therein and is likely to give more representative results when measuring benthic processes within incubation devices.