Noble-metal mineralization in the Semenov-2 hydrothermal field (13°31′N), mid-atlantic ridge

The porous fine-grained to microcrystalline copper-zinc ore of the Semenov-2 hydrothermal field, a site in the Semenov hydrothermal cluster discovered in 2007 (13°31′N, MAR), is anomalously enriched in Au (22–188 ppm) and Ag (127–1787 ppm). Chalcopyrite, isocubanite, würtzite, and opal are major minerals; sphalerite, marcasite, pyrite, and covellite are auxiliary; and galena, pyrrhotite, native gold, silver telluride, barite, and aragonite are sporadic. Gold containing 0.31 to 23.07 wt % Ag occurs as up to 9-μm-sized subhedral, dendritelike, and elongated grains mostly hosted in opal and less frequently in sphalerite and in pores within isocubanite-chalcopyrite aggregate. An elongated grain (2 × 4 μm in size) of the Ag-Te phase was found in a pore. So far only basalts have been dredged from the Semenov-2 field, but anomalous gold and silver concentrations suggest the influence of ultramafic rocks; the latter were found 1.5 km westward, in the Semenov-1 hydrothermal field. Mineral assemblage and morphology of gold particles indicate its primary origin in contrast to the hydrothermal fields hosted in basalts, where gold is a product of remobilization. Zonal gold grains, found on oceanic floor for the first time, are characterized by low Ag content in the cores and high Ag content in the outer rims, reflecting variation in formation conditions.     

The Use of Geographically Weighted Regression for Spatial Prediction: An Evaluation of Models Using Simulated Data Sets

Increasingly, the geographically weighted regression (GWR) model is being used for spatial prediction rather than for inference. Our study compares GWR as a predictor to (a) its global counterpart of multiple linear regression (MLR); (b) traditional geostatistical models such as ordinary kriging (OK) and universal kriging (UK), with MLR as a mean component; and (c) hybrids, where kriging models are specified with GWR as a mean component. For this purpose, we test the performance of each model on data simulated with differing levels of spatial heterogeneity (with respect to data relationships in the mean process) and spatial autocorrelation (in the residual process). Our results demonstrate that kriging (in a UK form) should be the preferred predictor, reflecting its optimal statistical properties. However the GWR-kriging hybrids perform with merit and, as such, a predictor of this form may provide a worthy alternative to UK for particular (non-stationary relationship) situations when UK models cannot be reliably calibrated. GWR predictors tend to perform more poorly than their more complex GWR-kriging counterparts, but both GWR-based models are useful in that they provide extra information on the spatial processes generating the data that are being predicted.     

Geochemical specifics of massifs of the drusite complex in the central Belomorian Mobile Belt: II. Sm-Nd isotopic system of the rocks and the U-Pb isotopic system of zircons

First isotopic-geochemical data were obtained on basite-ultrabasite rocks from the southern Kovdor area that were previously provisionally ascribed to the drusite (coronite) complex based on the occurrence of drusite (coronite) textures. The mineral and whole-rock Sm-Nd isochron age determined for five rock samples from the Sorkajoki and Poioiva massifs and the massif of Elevation 403 m turned out to be close (within the error): 2485 ± 51, 2509 ± 93, and 2517 ± 75 Ma, respectively. The crystallization age was evaluated for the two massifs (Poiojovski and Mount Krutaya Vostochnaya) by the U-Pb system of zircons. Our samples contained both magmatic and xenogenic crustal zircons, whose age was estimated at 2700 Ma. The crystallization age of the massifs themselves (data on the magmatic zircons) is 2410 ± 10 Ma. The undepleted character of the mantle source (ɛNd = +0.9) and the much younger age of the massifs than that of other known manifestations of ultrabasic magmatism in the territory of Karelia and the Kola Peninsula (including the layered pluton classic drusite massifs) suggest that the central part of the Belomorian Mobile Belt hosts one more independent intrusive rock complex, which has never been recognized previously and which is different from typical drusites.     

Modelling shallow landslide susceptibility: a new approach in logistic regression by using favourability assessment

A new method for estimating shallow landslide susceptibility by combining Geographical Information System (GIS), nonparametric kernel density estimation and logistic regression is described. Specifically, a logistic regression is applied to predict the spatial distribution by estimating the probability of occurrence of a landslide in a 16 km² area. For this purpose, a GIS is employed to gather the relevant sample information connected with the landslides. The advantages of pre-processing the explanatory variables by nonparametric density estimation (for continuous variables) and a reclassification (for categorical/discrete ones) are discussed. The pre-processing leads to new explanatory variables, namely, some functions which measure the favourability of occurrence of a landslide. The resulting model correctly classifies 98.55% of the inventaried landslides and 89.80% of the landscape surface without instabilities. New data about recent shallow landslides were collected in order to validate the model, and 92.20% of them are also correctly classified. The results support the methodology and the extrapolation of the model to the whole study area (278 km²) in order to obtain susceptibility maps.     

Trace elements in organic- and iron-rich surficial fluids of the boreal zone: Assessing colloidal forms via dialysis and ultrafiltration

On-site size fractionation of about 40 major and trace elements (TE) was performed on waters from boreal small rivers and their estuaries in the Karelia region of North-West Russia around the “Vetreny Belt” mountain range and in Paanajärvi National Park (Northern Karelia). Samples were filtered in the field using a progressively decreasing pore size (5 μm, 2.5 (3) μm, 0.22 (0.45) μm, 100 kDa, 10 and 1 kDa) by means of frontal filtration and ultrafiltration (UF) techniques and employing in-situ dialysis with 10 and 1 kDa membranes followed by ICP-MS analysis. For most samples, dialysis yields a systematically higher (factor of 2-3) proportion of colloidal forms compared to UF. Nevertheless, dialysis is able to provide a fast and artefact-free in-situ separation of colloidal and dissolved components.Similar to previous studies in European subarctic zones, poor correlation of iron concentration with that of organic carbon (OC) in (ultra)filtrates and dialysates reflect the presence of two pools of colloids composed of organic-rich and Fe-rich particles. All major anions and silica are present as dissolved species (or solutes) passing through the 1-kDa membrane. Size-separation ultrafiltration experiments show the existence of larger or smaller pools of colloidal particles different for each of the considered elements.The effect of rock lithology (acidic versus basic) on the colloidal speciation of TE is seen solely in the increase of Fe and some accompanying TE concentrations in catchment areas dominated by basic rocks compared to granitic catchments. Neither the ultrafiltration pattern nor the relative proportions of colloidal versus truly dissolved TE are affected by the lithology of the underlying rocks: within ±10% uncertainty, the two colloidal (10 kDa-0.22 μm and 1-10 kDa) and the truly dissolved (<1 kDa) pools show no difference in percentage of TE distribution between two types of bedrock lithology. The same conclusion is held for organic- and Fe-rich waters. In contrast, landscape context analysis demonstrated slight dominance, for most TE affected by UF, of large-size colloids (10 kDa-0.22 μm) in rivers and streams and small-size colloids and truly dissolved fractions in swamp stagnant surface waters. This supports the existence of two pathways of colloids formation: during the plant litter degradation in wetland zones and at the redox front in river riparian zone.     

东昆仑三道湾流纹英安斑岩锆石U-Pb年龄及其地质意义

东昆仑格尔木河西三道湾流纹英安斑岩构成火山通道侵出相,侵入到纳赤台群哈拉巴依沟组碎屑岩系中,其形成时代对于造山带火山作用的研究和限定哈拉巴依沟组地层时代均具有重要的意义。采用激光烧蚀多接收器电感耦合等离子体质谱(LA-MC-ICP MS)方法,对三道湾流纹英安斑岩进行了锆石U-Pb定年,结果表明,流纹英安斑岩中25个岩浆锆石206Pb/238U加权平均年龄为425.9 ± 2.6 Ma,它被解释为流纹英安斑岩的结晶年龄,说明三道湾次火山岩所代表的火山通道为早古生代造山晚期牦牛山组火山岩形成时的火山喷发中心之一,而非晚侏罗世次火山岩。野外地质关系和次火山岩年龄可以限定哈拉巴依沟组形成于中志留世之前。      

On the elemental composition of suspended matter of the Severnaya Dvina River (White Sea region)

New data on the elemental composition of the Severnaya Dvina River, the largest one in the White Sea region, are presented. The elemental composition of the river water in May, the period of the snowmelt flood, is similar to the upper layer of the Earth’s continental crust due to the active erosion of the earth material in the catchment area. In August, the period of the summer low water, the impact of biogenic components increases and elevated concentrations of Cd, Sb, Mn, Zn, Pb, and Cu are observed. At other times, no significant pollution by heavy and rare-earth elements is registered.     

Detailed architecture of a compound incised valley system and correlation with forced regressive wedges: Example of Late Quaternary Têt and Agly rivers,western Gulf of Lions,Mediterranean Sea,France

Quaternary incised valley systems are usually characterized by the preservation of a single valley-fill attributed to the last post-glacial period. Moreover, there are very few cases of correlation between incised valley system developed on inner shelf and sedimentary units observed on the mid to outer shelf, mainly forced regressive wedges. The Roussillon shelf, in the western part of the Gulf of Lion, is a particular example of preserved Quaternary compound incised valley system also characterized by a direct correlation with the forced regressive lowstand wedges on the mid-outer shelf. High-resolution seismic data and a borehole, 60 m deep, located on the beach barrier permit an accurate study of the geometry and lithology of the system. Six imbricated and more or less preserved incised valleys and valley-fills are observed up to the inner to mid-shelf. The key surfaces associated to the incised valleys are correlated to the boundaries of the forced regressive wedges. They are assumed to be reworked surfaces. At the borehole location, only few thin layers, less than 1 m thick, of coarse grain and/or floating pebbles, are observed and should correspond to preserved fluvial lowstand deposits reworked under marine influence. The valley fills are mainly composed of estuarine muddy silts. From AMS ¹⁴C age dating it is inferred that the uppermost incised valley system is younger than 45 ky cal BP. Based on those observations, the six preserved incised valley systems are assumed to be controlled by the last six 4th order sea-level cycles — 100 ky — of the middle to late Quaternary. The paleo-topography of the underlying Plio-Quaternary deposits controls the compound incised valley system location. The deep topography of the Messinian Erosionnal Surface is a controlling factor at a lower degree. The partial preservation of the successive valley fill is attributed not only to the differential subsidence but also to the lateral migration of each incision and to the hydrodynamic regime.