New palaeogeographic and lake-level reconstructions of Lake Tanganyika: implications for tectonic, climatic and biological evolution in a rift lake

Palaeogeographic and lake-level reconstructions provide powerful tools for evaluating competing scenarios of biotic, climatic and geological evolution within a lake basin. Here we present new reconstructions for the northern Lake Tanganyika subbasins, based on reflection seismic, core and outcrop data. Reflection seismic radiocarbon method (RSRM) age estimates provide a chronological model for these reconstructions, against which yet to be obtained age dates based on core samples can be compared. A complex history of hydrological connections and changes in shoreline configuration in northern Lake Tanganyika has resulted from a combination of volcanic doming, border fault evolution and climatically induced lake-level fluctuations. The stratigraphic expression of lake-level highstands and lowstands in Lake Tanganyika is predictable and cyclic (referred to here as Capart Cycles), but in a pattern that differs profoundly from the classic Van Houten cycles of some Newark Supergroup rift basins. This difference results from the extraordinary topographic relief of the Western Rift lakes, coupled with the rapidity of large-scale lake-level fluctuations. Major unconformity surfaces associated with Lake Tanganyika lowstands may have corresponded with high-latitude glacial maxima throughout much of the mid- to late Pleistocene.
Rocky shorelines along the eastern side of the present-day Ubwari Peninsula (Zaire) appear to have had a much more continuous existence as littoral rock habitats than similar areas along the north-western coastline of the lake (adjacent to the Uvira Border Fault System), which in turn are older than the rocky shorelines of the north-east coast of Burundi. This model of palaeogeographic history will be of great help to biologists trying to clarify the evolution of endemic invertebrates and fish in the northern basin of Lake Tanganyika.
     

Seismic anisotropy within the uppermost mantle of southern Germany

This paper presents an updated interpretation of seismic anisotropy within the uppermost mantle of southern Germany. The dense network of reversed and crossing refraction profiles in this area made it possible to observe almost 900 traveltimes of the P_n phase that could be effectively used in a time-term analysis to determine horizontal velocity distribution immediately below the Moho. For 12 crossing profiles, amplitude ratios of the P_n phase compared to the dominant crustal phase were utilized to resolve azimuthally dependent velocity gradients with depth. A P -wave anisotropy of 3–4 per cent in a horizontal plane immediately below the Moho at a depth of 30 km, increasing to 11 per cent at a depth of 40 km, was determined. For the axis of the highest velocity of about 8.03 km s⁻¹ at a depth of 30 km a direction of N31°F was obtained. The azimuthal dependence of the observed P_n amplitude is explained by an azimuth-dependent sub-Moho velocity gradient decreasing from 0.06 s⁻¹ in the fast direction to 0 s⁻¹ in the slow direction of horizontal P -wave velocity. From the seismic results in this study a petrological model suggesting a change of modal composition and percentage of oriented olivine with depth was derived.     

Mineral inclusions in diamonds from the Sputnik kimberlite pipe, Yakutia

The Sputnik kimberlite pipe is a small “satellite” of the larger Mir pipe in central Yakutia (Sakha), Russia. Study of 38 large diamonds (0.7-4.9 carats) showed that nine contain inclusions of the eclogitic paragenesis, while the remainder contain inclusions of the peridotitic paragenesis, or of uncertain paragenesis. The peridotitic inclusion suite comprises olivine, enstatite, Cr-diopside, chromite, Cr-pyrope garnet (both lherzolitic and harzburgitic), ilmenite, Ni-rich sulfide and a Ti-Cr-Fe-Mg-Sr-K phase of the lindsleyite-mathiasite (LIMA) series. The eclogitic inclusion suite comprises omphacite, garnet, Ni-poor sulfide, phlogopite and rutile. Peridotitic ilmenite inclusions have high Mg, Cr and Ni contents and high Nb/Zr ratios; they may be related to metasomatic ilmenites known from peridotite xenoliths in kimberlite. Eclogitic phlogopite is intergrown with omphacite, coexists with garnet, and has an unusually high TiO₂ content. Comparison with inclusions in diamonds from Mir shows general similarities, but differences in details of trace-element patterns. Large compositional variations among inclusions of one phase (olivine, garnet, chromite) within single diamonds indicate that the chemical environment of diamond crystallisation changed rapidly relative to diamond growth rates in many cases. P-T conditions of formation were calculated from multiphase inclusions and from trace element geothermobarometry of single inclusions. The geotherm at the time of diamond formation was near a 35 mW/m² conductive model; that is indistinguishable from the Paleozoic geotherm derived by studies of xenoliths and concentrate minerals from Mir. A range of Ni temperatures between garnet inclusions in single diamonds from both Mir and Sputnik suggests that many of the diamonds grew during thermal events affecting a relatively narrow depth range of the lithosphere, within the diamond stability field. The minor differences between inclusions in Mir and Sputnik may reflect lateral heterogeneity in the upper mantle.     

Late Cretaceous rift-related upwelling and melting of the Trindade starting mantle plume head beneath western Brazil

High mantle potential temperatures and local extension, associated with the Late-Cretaceous impact of the Trindade mantle plume, produced substantial widespread and voluminous magmatism around the northern half of the Paraná sedimentary basin. Our previous studies have shown that, above the central and eastern portions of the postulated impact zone where lithosphere extension is minimal, heat conducted by the plume caused large-scale melting of the more fusible parts of the subcontinental lithospheric mantle beneath the margin of the São Francisco craton and the surrounding Brasilía mobile belt. Here we combine geochemical data and field evidence from the Poxoreu Igneous Province, western Brazil to show how more intense lithospheric extension above the western margin of the postulated impact zone permitted greater upwelling and melting of the Trindade plume than further east. Laser ⁴⁰Ar/³⁹Ar age determinations indicate that rift-related basaltic magmas of the Poxoreu Igneous Province were emplaced at ? 84 Ma. Our detailed geochemical study of the mafic magmas shows that the parental melts underwent polybaric crystal fractionation within the crust prior to final emplacement. Furthermore, some magmas (quartz-normative) appear to have assimilated upper crust whereas others (nepheline- and hypersthene-normative) appear to have been unaffected by open-system crustal magma chamber processes. Incompatible trace element ratios (e.g. chondrite-normalised La/Nb?=?1) and isotopic ratios (⁸⁷Sr/⁸⁶Sr?=?0.704 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51274) of the Hy-normative basalts resemble those of oceanic islands (OIB). We therefore propose that these “OIB-like” magmas were predominantly derived from convecting-mantle-source melts (i.e. Trindade mantle plume). Inverse modelling of rare-earth element (REE) abundances suggests that the initial melts were predominantly generated within the depth range of ?80–100 km, in mantle with a potential temperature of ?1500 °C.     

On the Problem of Differential Payment for the Use of Different-Quality Surface Waters in Ukraine

The evolution of views and practical decisions regarding the problem of collecting payment for the use of surface waters with regard to their quality in the former USSR and present-day Ukraine is discussed. A simple and feasible method is proposed for differentitation of regional (basin) rates of payment for the use of surface water in Ukraine with allowance made for its quality assessed based on a system of environmental classifications.     

Long term atmospheric deposition as the source of nitrate and other salts in the Atacama Desert, Chile: New evidence from mass-independent oxygen isotopic compositions

Isotopic analysis of nitrate and sulfate minerals from the nitrate ore fields of the Atacama Desert in northern Chile has shown anomalous ¹⁷O enrichments in both minerals. Δ¹⁷O values of 14-21 ‰ in nitrate and 0.4 to 4 ‰ in sulfate are the most positive found in terrestrial minerals to date. Modeling of atmospheric processes indicates that the Δ¹⁷O signatures are the result of photochemical reactions in the troposphere and stratosphere. We conclude that the bulk of the nitrate, sulfate and other soluble salts in some parts of the Atacama Desert must be the result of atmospheric deposition of particles produced by gas to particle conversion, with minor but varying amounts from sea spray and local terrestrial sources. Flux calculations indicate that the major salt deposits could have accumulated from atmospheric deposition in a period of 200,000 to 2.0 M years during hyper-arid conditions similar to those currently found in the Atacama Desert. Correlations between Δ¹⁷O and δ¹⁸O in nitrate salts from the Atacama Desert and Mojave Desert, California, indicate varying fractions of microbial and photochemical end-member sources. The photochemical nitrate isotope signature is well preserved in the driest surficial environments that are almost lifeless, whereas the microbial nitrate isotope signature becomes dominant rapidly with increasing moisture, biologic activity, and nitrogen cycling. These isotopic signatures have important implications for paleoclimate, astrobiology, and N cycling studies.