Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration, North Jordan

The concentrations of fluorine in groundwater of North Jordan range from 0.009 to 0.055 mg/l. Other chemical parameters, e.g. pH, EC, TDS, Cl, TH, HCO₃, PO₄, SO₄, NO₃, NH₄, K, Ca, Mg, and NO₃ have been studied and showed higher concentrations in HCO₃⁻ and NO₃⁻ of 307 and 51 mg/l, respectively. Thermodynamic considerations show that almost all the analyzed samples are undersaturated with respect to calcite and fluorite. This undersaturation is probably due to their low availability in the locations. Fluoride concentration shows a positive relation to pH and HCO₃, whereas Cl, Mg, Ca, and Na initially increase and then decrease with increasing fluoride in the water. Saturation indexes of fluorite and calcite are estimated. The chemistry of the groundwater is controlled by the fluorite and calcite solubility. The topography of the area has exerted control on the aerial extent of fluoride concentration.     

The negative effect of environmental geological conditions of some geo-archaeological sites of North Coast and Alexandria

Three geo-archaeological sites at the North Coast and Alexandria, namely, the Alexandria wall (El Shalalat Park site), Abu Soir temple, and Marina excavations, were investigated to determine the negative impact of a salty environmental condition. The monuments suffer from rock decay of different rates. The geo-archaeological sites were built mainly from oolitic limestone blocks (i.e., the Alexandria wall at the El Shalalat Park site and Abu Soir temple) or excavated on them (i.e., Marina excavations). Field inspection and a lab analysis were carried out to understand the weathering mechanism. Salt weathering criteria such as disintegration, pitting, scaling, exfoliation, and honeycomb are observed on the Alexandria wall and upper parts of the Abu Soir temple, while dangerous cracks are detected on the Marina excavation tombs. The petrographic study of the oolitic limestone samples shows that they consist mainly of oolities and drusy sparite as a cement (oolitic grainstone). Some oolities have quartz grains as nuclei. Hydrochemical analysis shows that the total dissolved salts of extracted solutions of the North Coast quarry samples range from 539 to 686 ppm and dramatically increase (i.e., ten times) for extracted solutions from monument samples, ranging from 5395 to 6880 ppm. The dominant cation is sodium while the dominant anion is chlorine. Acid insoluble residue analysis shows that the carbonate content ranges from 89.2% to 96.4% for fresh samples from quarries and from 9.2% to 94.8% for weathered monument samples. The weight loss of the quarry oolitic limestone samples range from 30.7% to 32.7% and its physical and mechanical properties become worse after being subjected to 15 cycles of a durability simulation soundness test (using a sodium sulphate solution). Our main recommendations are to use suitable grouting for binding the cracks, high durability reconstruction rocks, and suitable cleaning methods to remove salts from the monuments.     

TOXICITY OF TWO HERBICIDES 2,4 -D DIMETHYLAMINE AND BENSULFURON METHYL TO RICE FIELD CHIRONOMUS KIIENSIS (TOKUNAGA) ( DIPTERA: CHIRONOMIDAE)

1 INTRODUCTIONRice field is a unique man -made wetland envi-ronment where many varieties of aquatic insects oc-curred ( Ali, Ahmad, 1988; Yamazaki,et al,2001a; Che Salmah, Abu Hassan, 2002). Duringrice cultivation in Malaysia, herbicides are used in-tensi…     

Estimation of frequency dependent coda wave attenuation structure at the vicinity of Cairo Metropolitan Area

Estimation of seismic wave attenuation in the shallow crust in terms of coda wave Q structure previously investigated in the vicinity of Cairo Metropolitan Area was improved using seismograms of local earthquakes recorded by the Egyptian National Seismic Network. The seismic wave attenuation was measured from the time decay of coda wave amplitudes on narrow bandpass filtered seismograms based on the single scattering theory. The frequency bands of interest are from 1.5 to 18 Hz. In general, the values obtained for various events recorded at El-Fayoum and Wadi Hagul stations are very similar for all frequency bands. A regional attenuation law Q _c = 85.66 f ^0.79 was obtained.     

孟加拉国农业利用强度增加、土地利用/覆盖变化和土地退化

在实地采访、地块土地利用/覆盖调查和1 260个土样的收集和实验室分析等野外工作的基础上,对比分析了1984—1985年和2003—2004年265个家户的人口、农业系统、土地利用和土壤质量数据,研究了孟加拉国6个村庄农业诱导强度增强对土地和土壤质量的影响。1984—2004年家户和土质数据的百分比变化用来构建诱导强度增强模型和土地退化模型中的统计变量和土地退化指标。结果表明：研究区种植强度和土地生产力的增加主要是由于低压泵灌溉的普及,化肥和杀虫剂的使用以及水稻、蔬菜和虾生产的多元化高产。诱导强度增强模型可以解释研究区81%的种植强度增量和73%的土地生产力增量。人口压力和市场驱动也诱发了农业利用强度的增加;环境约束起到了一定制约作用;低压泵灌溉等应对干旱的技术也对农业增产有一定贡献。然而动力耕作机、低压泵灌溉和化学物质的持续利用再加上除草性水稻、蔬菜和虾的频繁耕作和养殖已经导致土壤结构、质地和化学属性的退化,生产力也有所降低。利用强度越大的土地退化现象越严重,生产力下降得也更多。土地的不断退化将有可能会引发孟加拉国的马尔萨斯危机。     

Intraspecific morphometric diversity of barramundi (Lates calcariferBloch, 1790) in the waters of southern Bangladesh

A total of 160 barramundi's(Lates calcarifer Bloch,1790)sampled from four rivers(Tentulia,Balaswar,Bakkhali,and Andarmanik)along the southern coastal region of Bangladesh were investigated in terms of morphometric characters to reveal the intraspecific variation.Twenty-five morphometric measurements were extracted using the conventional method and subjected to multivariate analyses(i.e.,principal component analysis(PCA),discriminate function analysis(DFA),cluster analysis(CA))to distinguish individuals from different rivers.The result demonstrated that twenty-two out of 2 5 measurements was statistically significant(Univariate ANOVA)among all four populations.PCA analy sis of morphometric characters resulted in two principal components,PC I and PCII which accounted for 79.25%and 4.28%of the total data variance.PC I-PC Ⅱ plot explained 83.5 3%of total variance differentiated the population of L.calcarifer into two groups.Discriminate analysis correctly classified about 88.1%of the examined fish into the four areas.The UPGMA dendrogram showed that Bakkhali populations were the most morphologically different populations in comparison to other populations,while Andarmanik and Balaswar populations were very close to each other.The strong morphometric variation between Bakkhali and Tentulia,Andarmanik and Balaswar was observed in the present study,suggested the evidence of the separate stock population of barramundi in these locations,which might require distinct stock management strategies for resource sustainability in the waters of southern Bangladesh.However,if these findings are supported by further molecular markers and geometric morphometry,this would be a strong indication of different stocks of this population in the four rivers of southern Bangladesh.     

Near-surface foundation level assessment from seismic measurements: a case study of north Jeddah City,Saudi Arabia

In this study, a comprehensive assessment on the generation mechanism, distribution characteristics, and extension rules of structure cracks was conducted by in situ monitoring and field investigation in the Chengchao Iron Mine. Structure cracks are affected by many factors, e.g., surface deformation, structure strength, occurrence position, and machine vibration. They initially occur in a structure when the strength of the structure is not enough to resist the inner strain as surface deformation increases. In contrast, increases in width and length of structure crack exert stress release in the structure and thus decrease structure deformation surrounding the crack. A great ground crack may adversely aggravate structure cracking and release the stress of surrounding rock masses. In addition, micro cracks in rock masses provide favorable conditions for the generation and extension of cracks, resulting that cracks occur in shaft walls more easily and extend towards the deeper. The initial distribution of cracks is generally consistent with such micro cracks. Subsequently, cracks in deep rock masses will extend along the strike of the mined-out area as surface deformation increases. Sensibilities to cracking of structures are changed by their different strain resistances and become stronger from bolt-shotcrete shaft, bolt-shotcrete tunnel, and brick-concrete building to brick wall. Based on distribution characteristics of cracks and wave velocity in rock masses, the overlaying strata affected by underground mining can be divided into four zones: broken zone, broken transition zone, crack generation zone, and micro deformation zone.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part I: Isotopic (C,O) study of the Khushaym Matruk natural analogue (central Jordan)

The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ¹³C-values down to −31.4‰/PDB show the contribution of CO₂ derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO₂ in the near field.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: Organic matter evolution,magnetic susceptibility and metals (Ti,Cr, Fe) at the Khushaym Matruk natural analogue (Central Jordan)

Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval T_max values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.     

Simulation of vortex-induced vibrations of a cylinder using ANSYS CFX

In this paper, vortex-induced vibrations of a cylinder are simulated by use of ANSYS CFX simulation code. The cylinder is treated as a rigid body and transverse displacements are obtained by use of a one degree of freedom spring damper system. 2-D as well as 3-D analysis is performed using air as the fluid. Reynolds number is varied from 40 to 16000 approx., covering the laminar and turbulent regimes of flow. The experimental results of （Khalak and Williamson, 1997） and other researchers are used for validation purposes. The results obtained are comparable.