Oxygen and hydrogen isotope fractionation in serpentine-water and talc-water systems from 250 to 450 °C, 50 MPa

Oxygen and hydrogen isotope fractionation factors in the talc-water and serpentine-water systems have been determined by laboratory experiment from 250 to 450 °C at 50 MPa using the partial exchange technique. Talc was synthesized from brucite + quartz, resulting in nearly 100% exchange during reaction at 350 and 450 °C. For serpentine, D-H exchange was much more rapid than ¹⁸O-¹⁶O exchange when natural chrysotile fibers were employed in the initial charge. In experiments with lizardite as the starting charge, recrystallization to chrysotile enhanced the rate of ¹⁸O-¹⁶O exchange with the coexisting aqueous phase. Oxygen isotope fractionation factors in both the talc-water and serpentine-water systems decrease with increasing temperature and can be described from 250 to 450 °C by the relationships: 1000 ln  = 11.70 × 10⁶/T² − 25.49 × 10³/T + 12.48 and 1000 ln  = 3.49 × 10⁶/T² − 9.48 where T is temperature in Kelvin. Over the same temperature interval at 50 MPa, talc-water D-H fractionation is only weakly dependent on temperature, similar to brucite and chlorite, and can be described by the equation: 1000 ln = 10.88 × 10⁶/T² − 41.52 × 10³/T + 5.61 where T is temperature in Kelvin. Our D-H serpentine-water fractionation factors calibrated by experiment decrease with temperature and form a consistent trend with fractionation factors derived from lower temperature field calibrations. By regression of these data, we have refined and extended the D-H fractionation curve from 25 to 450 °C, 50 MPa as follows: 1000 ln  = 3.436 × 10⁶/T² − 34.736 × 10³/T + 21.67 where T is temperature in Kelvin. These new data should improve the application of D-H and ¹⁸O-¹⁶O isotopes to constrain the temperature and origin of hydrothermal fluids responsible for serpentine formation in a variety of geologic settings.     

Amplitudes of long-period PcP and the core-mantle boundary

The amplitudes of the core reflection PcP are sensitive to the wave velocities and densities in the neighborhood of the core-mantle boundary (CMB). We study the amplitude ratio of the long-period phases PcP and P from two South American deep-focus earthquakes with favorable fault-plane solution, depth and magnitude, as recorded by WWNSS and CSN stations in North America.Comparison is made with long-period PcP/P amplitude ratios, derived from theoretical seismograms for a variety of CMB models. Models from previous studies, which were mainly derived from short-period PcP observations and which are characterized by discrete layers above the CMB, are almost all inconsistent with the long-period data. The data also discriminate against low nonzero S velocities below the CMB. Simple first-order-discontinuity models of the CMB, for instance according to the Jeffreys-Bullen earth model or according to recent models based mainly on free oscillations, explain the data reasonably well.Model improvements are attempted by varying the P-velocity gradient above the CMB. The best amplitude fit is obtained for a rather strong decrease in P velocity with depth in this zone which, however, gives no acceptable traveltime fit for PcP. The scatter in body-wave amplitudes is considerable even for long-period waves and may prevent the correct assessment of that part of the amplitude variation of a phase with distance that is due to the variation of velocities and densities with depth alone.     

Evolution and observational signature of diffused antiworld

The existence of macroscopic regions with antibaryon excess in the baryon asymmetric Universe with general baryon excess is the possible consequence of practically all models of baryosynthesis. Diffusion of matter and antimatter to the border of antimatter domains defines the minimal scale of the antimatter domains surviving to the present time. A model of diffused antiworld is considered, in which the density within the surviving antimatter domains is too low to form gravitationally bound objects. The possibility to test this model by measurements of cosmic gamma ray fluxes is discussed. The expected gamma ray flux is found to be acceptable for modern cosmic gamma ray detectors and for those planned for the near future.     

Ecological-geochemical assessment of the state of the Volga source of water supply to Moscow

Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.     

Structural elements in southeastern Quebec,northwestern Appalachians,Canada

An attempt is made to correlate and separate in terms of style and time two contrasting sets of structural elements in the northwestern part of the Appalachian Uplands in the Province of Quebec, Canada. There is sufficient evidence to indicate that a fold system with north-south trending axes is superimposed on a fold system with east-west axes. It is suggested that the two sets of structures represent pulses of one long-continued deformation accompanied by corresponding early and late phases of metamorphism.

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Zusammenfassung Es wurde versucht, in den Appalachen des südöstlichen Teiles der Provinz Quebec, Kanada, zwei ungleichzeitige tektonische Systeme verschiedenen Baustils zu trennen. Die komplexen Kleinstrukturen zeigen, da\ Ost-West streichende Faltenachsen von einer jüngeren Nord-Süd-Faltung überprägt worden sind. Der Autor ist der Meinung, da\ die zwei tektonischen Systeme, die von einer frühen und späten Phase der Metamorphose begleitet werden, den zeitlich getrennten Verformungsstadien einer Orogenese entsprechen.

     

Multidimensional statistical technique for detection of low contrast geochemical anomalies

In this article we propose an advanced technique for detecting low contrast geochemical anomalies using a set of features. There are three principal elements in this technique: (1) a statistical measure of the contrast of the anomaly, denoted as τ; (2) selection of a background population; and (3) reduction of the dimensionality of the feature space. In the frame of the model, which describes the statistical distribution of geochemical background as a multidimensional normal distribution of logarithms of concentrations, the index, τ, is a powerful test statistic for the hypothesis of abnormality of an observation. Maps of τ anomalies can be rigorously interpreted on the basis of statistical inferences. Under all equal conditions this technique allows the detection of geochemical anomalies with at least the same contrast (if the chemical elements in a background population are correlated, then even the better) as using selective extractions of metals from soil or other techniques for data processing. The advantages of the proposed technique are demonstrated both theoretically and on examples of rare-metal and copper–nickel mineral deposits.