The importance of changing oceanography in controlling late Quaternary carbonate sedimentation on a high-energy, tropical, oceanic ramp: north-western Australia

The North West Shelf is an ocean‐facing carbonate ramp that lies in a warm‐water setting adjacent to an arid hinterland of moderate to low relief. The sea floor is strongly affected by cyclonic storms, long‐period swells and large internal tides, resulting in preferentially accumulating coarse‐grained sediments. Circulation is dominated by the south‐flowing, low‐salinity Leeuwin Current, upwelling associated with the Indian Ocean Gyre, seaward‐flowing saline bottom waters generated by seasonal evaporation, and flashy fluvial discharge. Sediments are palimpsest, a variable mixture of relict, stranded and Holocene grains. Relict intraclasts, both skeletal and lithic, interpreted as having formed during sea‐level highstands of Marine Isotope Stages (MIS) 3 and 4, are now localized to the mid‐ramp. The most conspicuous stranded particles are ooids and peloids, which ¹⁴C dating shows formed at 15·4–12·7 Ka, in somewhat saline waters during initial stages of post‐Last Glacial Maximum (LGM) sea‐level rise. It appears that initiation of Leeuwin Current flow with its relatively less saline, but oceanic waters arrested ooid formation such that subsequent benthic Holocene sediment is principally biofragmental, with sedimentation localized to the inner ramp and a ridge of planktic foraminifera offshore. Inner‐ramp deposits are a mixture of heterozoan and photozoan elements. Depositional facies reflect episodic environmental perturbation by riverine‐derived sediments and nutrients, resulting in a mixed habitat of oligotrophic (coral reefs and large benthic foraminifera) and mesotrophic (macroalgae and bryozoans) indicators. Holocene mid‐ramp sediment is heterozoan in character, but sparse, most probably because of the periodic seaward flow of saline bottom waters generated by coastal evaporation. Holocene outer‐ramp sediment is mainly pelagic, veneering shallow‐water sediments of Marine Isotope Stage 2, including LGM deposits. Phosphate accumulations at ≈ 200 m water depth suggest periodic upwelling or Fe‐redox pumping, whereas enhanced near‐surface productivity, probably associated with the interaction between the Leeuwin Current and Indian Ocean surface water, results in a linear ridge of pelagic sediment at ≈ 140 m water depth. This ramp depositional system in an arid climate has important applications for the geological record: inner‐ramp sediments can contain important heterozoan elements, mid‐ramp sediments with bedforms created by internal tides can form in water depths exceeding 50 m, saline outflow can arrest or dramatically slow mid‐ramp sedimentation mimicking maximum flooding intervals, and outer‐ramp planktic productivity can generate locally important fine‐grained carbonate sediment bodies. Changing oceanography during sea‐level rise can profoundly affect sediment composition, sedimentation rate and packaging.     

U-Th systematics and Th ages of carbonate chimneys at the Lost City Hydrothermal Field

The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th systematics of hydrothermal fluids and the ²³⁰Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples containing only 2-21% ambient seawater (1.1-11 mmol/kg Mg), Th concentration is 0.11-0.13 pg/g and surrounding seawater concentrations average 0.133 ± 0.016 pg/g. The ²³⁰Th/²³²Th atomic ratios of the vent fluids range from 1 (±10) × 10⁻⁶ to 11 (±5) × 10⁻⁶, are less than those of seawater, and indicate that the vent fluids may contribute a minor amount of non-radiogenic ²³⁰Th to the LCHF carbonate chimney deposits. Chimney ²³⁸U concentrations range from 1 to 10 μg/g and the average chimney corrected initial δ²³⁴U is 147.2 ± 0.8, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate ²³²Th concentrations range broadly from 0.0038 ± 0.0003 to 125 ± 16 ng/g and ²³⁰Th/²³²Th atomic ratios vary from near seawater values of 43 (±8) × 10⁻⁶ up to 530 (±25) × 10⁻³. Chimney ages, corrected for initial ²³⁰Th, range from 17 ± 6 yrs to 120 ± 13 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.     

Uranium-series dating of pedogenic silica and carbonate, Crater Flat, Nevada

A ²³⁰Th-²³⁴U-²³⁸U dating study on pedogenic silica-carbonate clast rinds and matrix laminae from alluvium in Crater Flat, Nevada was conducted using small-sample thermal-ionization mass spectrometry (TIMS) analyses on a large suite of samples. Though the ²³²Th content of these soils is not particularly low (mostly 0.1-9 ppm), the high U content of the silica component (mostly 4-26 ppm) makes them particularly suitable for ²³⁰Th/U dating on single, 10 to 200 mg totally-digested samples using TIMS. We observed that (1) both micro- (within-rind) and macro-stratigraphic (mappable deposit) order of the ²³⁰Th/U ages were preserved in all cases; (2) back-calculated initial ²³⁴U/²³⁸U fall in a restricted range (typically 1.67±0.19), so that ²³⁴U/²³⁸U ages with errors of about 100 kyr (2σ) could be reliably determined for the oldest, 400 to 1000 ka rinds; and (3) though 13 of the samples were >350 ka, only three showed evidence for an open-system history, even though the sensitivity of such old samples to isotopic disruption is very high. An attempt to use leach-residue techniques to separate pedogenic from detrital U and Th failed, yielding corrupt ²³⁰Th/U ages. We conclude that ²³⁰Th/U ages determined from totally dissolved, multiple sub-mm size subsamples provide more reliable estimates of soil chronology than methods employing larger samples, chemical enhancement of ²³⁸U/²³²Th, or isochrons.     

Hydrogen incorporation in orthopyroxene: interaction of different trivalent cations

The incorporation of hydrogen into ferrosilite, Fe-bearing enstatite and orthopyroxene containing different trivalent cations (Cr³⁺ and Al³⁺, Cr³⁺ and Fe³⁺) was investigated experimentally at 25 kbar. Hydrogen concentration was determined by FTIR-spectroscopy on oriented crystal sections and by secondary ion mass spectroscopy, whereas Mößbauer spectroscopy and optical spectroscopy were used to characterise the valence state of Fe in orthopyroxene. Results suggest that hydrogen incorporation in ferrosilite is achieved by a similar mechanism as in pure enstatite. In Cr-bearing samples, however, hydrogen incorporation is reduced by the presence of other trivalent cations by an increased tendency to form Tschermaks substitutions, e.g. Si _T ⁴⁺ + Mg _M1 ²⁺ ? Al _T ³⁺ + Cr _M1 ³⁺ . Thus, hydrogen solubility in natural orthopyroxenes from the Earth’s mantle, containing significant amounts of Cr³⁺, Al³⁺, and Fe³⁺, may be much more limited than expected from their trivalent cation content, as a large fraction of the trivalent cations does not participate in H-incorporating reactions as 2 Mg _M1 ²⁺ ? M _M1 ³⁺ + V_M1 + H _i ⁺ .     

Remarkable Link between Projected Uncertainties of Arctic Sea-Ice Decline and Winter Eurasian Climate

We identify that the projected uncertainty of the pan-Arctic sea-ice concentration(SIC) is strongly coupled with the Eurasian circulation in the boreal winter(December–March; DJFM), based on a singular value decomposition(SVD) analysis of the forced response of 11 CMIP5 models. In the models showing a stronger sea-ice decline, the Polar cell becomes weaker and there is an anomalous increase in the sea level pressure(SLP) along 60°N, including the Urals–Siberia region and the Iceland low region. There is an accompanying weakening of both the midlatitude westerly winds and the Ferrell cell,where the SVD signals are also related to anomalous sea surface temperature warming in the midlatitude North Atlantic.In the Mediterranean region, the anomalous circulation response shows a decreasing SLP and increasing precipitation. The anomalous SLP responses over the Euro-Atlantic region project on to the negative North Atlantic Oscillation–like pattern.Altogether, pan-Arctic SIC decline could strongly impact the winter Eurasian climate, but we should be cautious about the causality of their linkage.     

安徽宣城矿集区长山铅锌多金属矿床成矿流体特征及成因

长山铅锌多金属矿床位于长江中下游成矿带宣城矿集区东北部,文章在对该矿床开展详细的地质调查和岩相学研究基础上,对代表性矿化蚀变矿物(石英、方解石)开展了流体包裹体测温、激光拉曼光谱和氢、氧、碳稳定同位素分析。长山铅锌多金属矿床矿化蚀变组合从早到晚可以分为矽卡岩-氧化物阶段、早硫化物阶段和晚硫化物阶段。矿物流体包裹体温度和盐度测算显示,长山矿床的成矿流体温度和盐度从矽卡岩-氧化物阶段(315～382℃,w(NaCl)_eq为14.04%～16.24%)→早硫化物阶段(220～347℃,w(NaCl)_eq为4.49%～15.86%)→晚硫化物阶段(163～306℃,w(NaCl)_eq为1.40%～11.10%)逐渐降低。石英和闪锌矿中包裹体的δD和δ¹⁸O值分别为-89.5‰～-67.8‰和-3.2‰～7.62‰,方解石中δ¹³C和δ¹⁸O值分别是-6.8‰～-1‰和10.6‰～17.1‰,同位素特征指示长山矿床的成矿流体为岩浆水与海相碳酸盐中富含有机质流体混合,...     

Extremely metal‐poor stars in SDSS fields

Some insight on the first generation of stars can be obtained from the chemical composition of their direct descendants, extremely metal‐poor stars (EMP), with metallicity less than or equal to 1/1000 of the solar metallicity. Such stars are exceedingly rare, the most successful surveys, for this purpose, have so far provided only about 100 stars with 1/1000 the solar metallicity and 4 stars with about 1/10000 of the solar metallicity. The Sloan Digital Sky Survey has the potential to provide a large number of candidates of extremely low metallicity. X‐shooter has the unique capability of performing the necessary follow‐up spectroscopy providing accurate metallicities and abundance ratios for several elements (Mg, Al, Ca, Ti, Cr, Sr,...) for EMP candidates. We here report on the results for the first two stars observed in the course of our Franco‐Italian X‐shooter GTO. The two stars were targeted to be of metallicity around –3.0, the analysis of the X‐shooter spectra showed them to be of metallicity around –2.0, but with a low α to iron ratio, which explains the underestimate of the metallicity from the SDSS spectra. The efficiency of X‐shooter allows an in situ study of the outer halo, for the two stars studied here we estimate distances of 3.9 and 9.1 kpc, these are likely the most distant dwarf stars studied in detail to date (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The Ksar Ghilane 002 shergottite—The 100th registered Martian meteorite fragment

We report on the discovery of a new shergottite from Tunisia, Ksar Ghilane (KG) 002. This single stone, weighing 538 g, is a coarse‐grained basaltic shergottite, mainly composed of maskelynitized plagioclase (approximately 52 vol%) and pyroxene (approximately 37 vol%). It also contains Fe‐rich olivine (approximately 4.5 vol%), large Ca‐phosphates, including both merrillites and Cl‐apatites (approximately 3.4 vol%), minor amounts of silica or SiO₂‐normative K‐rich glass, pyrrhotite, Ti‐magnetite, ilmenite, and accessory baddeleyite. The largest crystals of pyroxene and plagioclase reach sizes of approximately 4 to 5 mm. Pyroxenes (Fs_26–96En_5–50Wo_2–41). They typically range from cores of about Fs₂₉En₄₁Wo₃₀ to rims of about Fs₆₈En₁₄Wo₁₇. Maskelynite is Ab_41–49An_39–58Or_1–7 in composition, but some can be as anorthitic as An₉₃. Olivine (Fa_91–96) occurs mainly within symplectitic intergrowths, in paragenesis with ilmenite, or at neighboring areas of symplectites. KG 002 is heavily shocked (S5) as indicated by mosaic extinction of pyroxenes, maskelynitized plagioclase, the occurrence of localized shock melt glass pockets, and low radiogenic He concentration. Oxygen isotopes confirm that it is a normal member of the SNC suite. KG 002 is slightly depleted in LREE and shows a positive Eu anomaly, providing evidence for complex magma genesis and mantle processes on Mars. Noble gases with a composition thought to be characteristic for Martian interior is a dominant component. Measurements of ¹⁰Be, ²⁶Al, and ⁵³Mn and comparison with Monte Carlo calculations of production rates indicate that KG 002 has been exposed to cosmic rays most likely as a single meteoroid body of 35–65 cm radius. KG 002 strongly resembles Los Angeles and NWA 2800 basaltic shergottites in element composition, petrography, and mineral chemistry, suggesting a possible launch‐pairing. The similar CRE ages of KG 002 and Los Angeles may suggest an ejection event at approximately 3.0 Ma.     

Twentieth century Walker Circulation change: data analysis and model experiments

Recent studies indicate a weakening of the Walker Circulation during the twentieth century. Here, we present evidence from an atmospheric general circulation model (AGCM) forced by the history of observed sea surface temperature (SST) that the Walker Circulation may have intensified rather than weakened. Observed Equatorial Indo-Pacific Sector SST since 1870 exhibited a zonally asymmetric evolution: While the eastern part of the Equatorial Pacific showed only a weak warming, or even cooling in one SST dataset, the western part and the Equatorial Indian Ocean exhibited a rather strong warming. This has resulted in an increase of the SST gradient between the Maritime Continent and the eastern part of the Equatorial Pacific, one driving force of the Walker Circulation. The ensemble experiments with the AGCM, with and without time-varying external forcing, suggest that the enhancement of the SST gradient drove an anomalous atmospheric circulation, with an enhancement of both Walker and Hadley Circulation. Anomalously strong precipitation is simulated over the Indian Ocean and anomalously weak precipitation over the western Pacific, with corresponding changes in the surface wind pattern. Some sensitivity to the forcing SST, however, is noticed. The analysis of twentieth century integrations with global climate models driven with observed radiative forcing obtained from the Coupled Model Intercomparison Project (CMIP) database support the link between the SST gradient and Walker Circulation strength. Furthermore, control integrations with the CMIP models indicate the existence of strong internal variability on centennial timescales. The results suggest that a radiatively forced signal in the Walker Circulation during the twentieth century may have been too weak to be detectable.     

Der RÜckwärtseinschnitt auf der Kugel und die Funkortung bei weit entfernten Sendern

Zusammenfassung In der folgenden Arbeit wird vorausgesetzt, daß man die geographischen Koordinaten dreier SenderA, B, C kennt und eine stereographische Karte mit einem der Sender, z. B.C, als Kartenpol zur VerfÜgung hat. Die wahre N-Richtung braucht man nicht zu kennen. Vom unbekannten StandortS aus werden durch Funkpeilung die sphärischen WinkelC S A= undC S B= gemessen. Es wird gezeigt, wie man in der stereographischen Karte rein geometrisch und mathematisch streng die beiden zu und gehörigen (den Pothenotschen Kreisen der Ebene entsprechenden) Standkurven in ihrem ganzen Verlauf zeichnen kann. Einer der Schnittpunkte dieser beiden Kurven ist der gesuchte StandortS; seine geographischen Koordinaten werden der stereographischen Karte entnommen. Welcher der acht Schnittpunkte der richtige ist, ergibt sich aus dem gegißten Besteck. — Über die Ausgestaltung dieses Verfahrens zu einem Hilfsmittel der praktischen Navigation wird später gesprochen werden.

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Resection on the sphere and radio direction finding with the aid of long-distance wireless stations

Summary The following paper proceeds from the supposition that the co-ordinates of three wireless transmittersA,B, C are known and that a stereographic map is available having as pole the transmitterC, i. e. one of the three transmitters. The true northern direction needs not to be known. The spheric anglesC S A= andC S B= are measured by radio direction finding from the unknown positionS. It is explained how to plot — in a purely geometrical and rigorously mathematical way on a stereographic map — the entire path of the two radio position curves belonging to and and corresponding with the Pothenot circles on the plane. One of the eight points of intersection of the two radio position curves is the required fixS; its geographical co-ordinates are taken from the stereographic map; which of the intersection points is the right one will be found by the aid of the result of dead reckoning.In a later paper it will be explained how to develop this method to a practical aid in navigation.

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Le recoupement sur la sphère et la radiogoniométrie à l' aide d' émetteurs à grande portée

Résumé Le travail suivant part de la supposition que les coordonnées géographiques de trois émetteursA, B, C soient connues et que l'on dispose d'une carte stéréographique dont l'émetteurC, c.à.d. un des trois émetteurs, soit le pÔle. Il n'est pas nécessaire de connaÎtre le Nord vrai. On mesure les deux angles sphériquesC S A= etC S B= par radiogoniométrie à partir du point inconnuS. En se servant d'une méthode purement géométrique et rigoureusement mathématique on montre de quelle manière on peut porter sur la carte stéréographique tout le cours des deux »courbes de position« associées aux angles et et correspondant aux cercles de Pothenot en planimétrie. Un des huit points d'intersection de ces deux »courbes de position« est la position cherchéeS; on tire ses coordonnées géographiques de la carte stéréographique. Celui des huit points d'intersection qui se confond avec le point estimé indiquera la position correcte.L'extension de cette méthode à une aide de navigation sera l'objet d'un futur travail.