U-Th systematics and Th ages of carbonate chimneys at the Lost City Hydrothermal Field

The Lost City Hydrothermal Field (LCHF) is a serpentinite-hosted vent field located 15 km west of the spreading axis of the Mid-Atlantic Ridge. In this study, uranium-thorium (U-Th) geochronological techniques have been used to examine the U-Th systematics of hydrothermal fluids and the ²³⁰Th ages of hydrothermally-precipitated carbonate chimneys at the LCHF. Fluid sample analyses indicate that endmember fluids likely contain only 0.0073 ng/g U or less compared to 3.28 ± 0.03 ng/g of U in ambient seawater. For fluid samples containing only 2-21% ambient seawater (1.1-11 mmol/kg Mg), Th concentration is 0.11-0.13 pg/g and surrounding seawater concentrations average 0.133 ± 0.016 pg/g. The ²³⁰Th/²³²Th atomic ratios of the vent fluids range from 1 (±10) × 10⁻⁶ to 11 (±5) × 10⁻⁶, are less than those of seawater, and indicate that the vent fluids may contribute a minor amount of non-radiogenic ²³⁰Th to the LCHF carbonate chimney deposits. Chimney ²³⁸U concentrations range from 1 to 10 μg/g and the average chimney corrected initial δ²³⁴U is 147.2 ± 0.8, which is not significantly different from the ambient seawater value of 146.5 ± 0.6. Carbonate ²³²Th concentrations range broadly from 0.0038 ± 0.0003 to 125 ± 16 ng/g and ²³⁰Th/²³²Th atomic ratios vary from near seawater values of 43 (±8) × 10⁻⁶ up to 530 (±25) × 10⁻³. Chimney ages, corrected for initial ²³⁰Th, range from 17 ± 6 yrs to 120 ± 13 kyrs. The youngest chimneys are at the intersection of two active, steeply-dipping normal faults that cut the Atlantis Massif; the oldest chimneys are located in the southwest portion of the field. Vent deposits on a steep, fault-bounded wall on the east side of the field are all <4 kyrs old, indicating that mass wasting in this region is relatively recent. Comparison of results to prior age-dating investigations of submarine hydrothermal systems shows that the LCHF is the most long-lived hydrothermal system known to date. It is likely that seismic activity and active faulting within the Atlantis Massif and the Atlantis Fracture Zone, coupled with volumetric expansion of the underlying serpentinized host rocks play major roles in sustaining hydrothermal activity at this site. The longevity of venting at the LCHF may have implications for ecological succession of microorganisms within serpentinite-hosted vent environments.     

Li, Be, B concentrations and δ7Li values in plagioclase phenocrysts of dacites from Nea Kameni (Santorini, Greece)

Li, Be, B and δ⁷Li SIMS analyses of plagioclase phenocrysts from the 1040–1941 Niki dacite lava (Nea Kameni, Santorini, Greece) exhibit varied processes. From their anorthite contents alone, the crystals may be segregated into four main types: type-N shows the normal decline in An during crystallisation (An_62–40); type-O has only oscillatory zoning accompanied by resorption surfaces (An_58–39); type-C is complex with high-An cores (subtype C1: An_64–58, subtype C2: An_88–73) and normal rims (An_55–42). Type-A plagioclase with high An content (An_92–82) is found within mafic enclaves. On the basis of their Li concentrations, type-O crystals may be subdivided into subtype O1 with flat Li concentration profiles and subtype O2 with decreasing Li concentration from core to rim. The concentrations of Be and B of all four types show a negative correlation with anorthite content (An), but Li concentration profiles differ amongst the different plagioclase types. Types N and O1, and the cores of type-C, are equilibrated in Li concentration. Types O2 and A, and the mantles of type-C display an initial enrichment in Li, probably from volatile influx into the melt. Consistent with the propensity towards equilibrium with the melt, these crystals display dramatic rim-ward declines in Li concentration. All analysed plagioclase crystals, except for the xenocrystic type-A, have nearly the same Li, Be and B concentrations at their rims. These coincide with the composition of plagioclase microlites in the groundmass, thereby affording estimates of plagioclase-melt partitioning for the light elements: K _Li = 0.19–0.28, K _Be = 0.24–0.38 and K _B = 0.007–0.009. δ⁷Li profiles in type-O2 and type-A phenocrysts manifest an unmistakable inverse relation to Li concentration, with variations of up to ~39 ‰, revealing preferential kinetic diffusion. This may have been driven by Li loss from the melt, most likely through degassing during decompression, perhaps in the course of magma ascent to subsequent eruption. Considering the rapid diffusion of Li in plagioclase, in situ phenocryst analyses may yield useful information about processes leading up to, or even causing, eruptions.     

The potential for photosynthesis in hydrothermal vents: a new avenue for life in the Universe?

We perform a quantitative assessment for the potential for photosynthesis in hydrothermal vents in the deep ocean. The photosynthetically active radiation in this case is from geothermal origin: the infrared thermal radiation emitted by hot water, at temperatures ranging from 473 up to 673 K. We find that at these temperatures the photosynthetic potential is rather low in these ecosystems for most known species. However, species which a very high efficiency in the use of light and which could use infrared photons till 1300 nm, could achieve good rates of photosynthesis in hydrothermal vents. These organisms might also thrive in deep hydrothermal vents in other planetary bodies, such as one of the more astrobiologically promising Jupiter satellites: Europa.     

Sulphur abundances in halo stars from multiplet 3 at 1045 nm

Sulphur is a volatile α ‐element which is not locked into dust grains in the interstellar medium (ISM). Hence, its abundance does not need to be corrected for dust depletion when comparing the ISM to the stellar atmospheres. The abundance of sulphur in the photosphere of metal‐poor stars is a matter of debate: according to some authors, [S/Fe] versus [Fe/H] forms a plateau at low metallicity, while, according to other studies, there is a large scatter or perhaps a bimodal distribution. In metal‐poor stars sulphur is detectable by its lines of multiplet 1 at 920 nm, but this range is heavily contaminated by telluric absorptions, and one line of the multiplet is blended by the hydrogen Paschen ζ line. We study the possibility of using multiplet 3 (at 1045 nm) for deriving the sulphur abundance because this range, now observable at the VLT with the infra‐red spectrograph CRIRES, is little contaminated by telluric absorption and not affected by blends at least in metal‐poor stars. We compare the abundances derived from multiplets 1 and 3, taking into account NLTE corrections and 3D effects. Here we present the results for a sample of four stars, although the scatter is less pronounced than in previous analysis, we cannot find a plateau in [S/Fe], and confirm the scatter of the sulphur abundance at low metallicity (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Surface pressure profiles, vortex structure and initialization for hurricane prediction. Part I: analysis of observed and synthetic structures

Without detailed reconnaissance, consistent representation of hurricane-like vortices in initial conditions for operational prediction and research simulations still remains elusive. It is thus often necessary, particularly for high-resolution intensity forecasting, to use synthetic tropical cyclone circulations to initialize forecast models. Variants on three commonly used surface pressure profiles are evaluated for possible use. Enhancements to the original profiles are proposed that allows definition of both the inner-core and outer circulation. The latter improvement creates a vortex more consistent with the estimated outer structure which sometimes appears to be crucial to the evolving intensity of the storm. It also allows smoother merging of the synthetic vortex with the environment. Comparisons of the profiles against (a) structure estimates, (b) each other, (c) structures obtained via conservation of angular momentum, and (d) observed vorticity structures, suggest that a new enhanced Fujita profile best represents real TC structures. Student-t tests indicate that improved fitting to the observations is statistically significant.     

Impact of the Equatorial Atlantic on the El Ni?o Southern Oscillation

Observations indicate that the Atlantic zonal mode influences El Ni?o Southern Oscillation (ENSO) in the Pacific, as already suggested in previous studies. Here we demonstrate for the first time using partial coupled experiments that the Atlantic zonal mode indeed influences ENSO. The partial coupling experiments are performed by forcing the coupled general circulation model (ECHAM5/MPI-OM) with observed sea surface temperature (SST) in the Tropical Atlantic, but with full air-sea coupling allowed in the Pacific and Indian Ocean. The ensemble mean of a five member simulation reproduces the observational results well. Analysis of observations, reanalysis, and coupled model simulations all indicate the following mechanism: SST anomalies associated with the Atlantic zonal mode affect the Walker Circulation, driving westward wind anomalies over the equatorial Pacific during boreal summer. The wind stress anomalies increase the east-west thermocline slope and enhance the SST gradient across the Pacific; the Bjerknes positive feedback acts to amplify these anomalies favouring the development of a La Ni?a-like anomalies. The same mechanisms act for the cold phase of Atlantic zonal mode, but with opposite sign. In contrast to previous studies, the model shows that the influence on ENSO exists before 1970. Furthermore, no significant influence of the Tropical Atlantic on the Indian Monsoon precipitation is found in observation or model.     

Stall markets in metropolitan Sydney

Stall markets on open air, suburban sites are an important new form of retailing in Sydney. The existing literature on petty commodity forms of production argues that stall markets are conserved in underdeveloped economies for a variety of reasons but the relevance of these ideas to the markets in many cities in advanced economies has not been considered. This paper identifies the basic types of stall markets in Sydney, establishes that these markets are not ephemeral and shows that they have characteristics and parameters which are similar to those of conventional shopping centres. Thus the way is open to compare stall markets with conventional retailing, to assess the role of stall markets in post‐industrial societies and to investigate the reasons for their recent appearance in Sydney.